Lg Energy Solution, Ltd.

Lg Chem, Ltd

Ulsan National Institute of Science and Technology

Sung-Joong Kang

Jung-Pil Lee

Ji-Hoon Ryu

Jae-Hyun Lee

Eun-Bee Kim

Suk-Woo Lee

In-Sung Uhm

Hyea-Eun Han

Ho-Suk Shin

Seung-He Woo

Sung-Ju Cho

Yong-Hee Lee

Dong-Chan Lee

Guilong Jin

Ji-Young Kim

Min-Chul Jang

Hyo-Sik Kim

Byoung-Kuk Son

Ji-Hee Ahn

Dong-Hyeon Kang

Je-Young Kim

Hong-Kyu Park

Sang-Young Lee

Jung-Hun Choi

Ju-Ryoun Kim

Joo-Hong Jin

Ju-Myung Kim

Min-Kyu You

Dae-Jin Lee

Jeong-A Kim

The present disclosure relates to an electrode assembly for an all-solid-state battery with improved safety, and more particularly, to an electrode assembly of a new structure designed to prevent the damage of a solid electrolyte layer caused by a step formed in a negative electrode layer due to changes in thickness of the negative electrode layer, such as an increase or decrease in thickness at part of the negative electrode layer, during charging/discharging. The electrode assembly is characterized by comprising a protective layer having an opening, interposed between the negative electrode and the solid electrolyte layer.

All-solid-state battery using lithium metal for negative electrode

The solid electrolyte membrane according to the present disclosure interrupts migration of lithium ions by the formation of an ion conduction-interrupting layer in the electrolyte membrane through the phase separation of polymers under a high-temperature condition, including an increase in the internal temperature of a battery. Since a battery is prevented from thermal runaway and explosion through the formation of the 'ion conduction-interrupting layer' (also referred to as ‘interrupting layer’), it is possible to improve the heat resistance and safety of the battery.

Electrolyte membrane for all-solid state battery and all-solid state battery including the same

The solid electrolyte membrane according to the present disclosure forms an ion conduction-interrupting layer therein by polymer phase separation under a high temperature condition, such as an increase in internal temperature of a battery, and thus interrupts lithium ion transport. Therefore, it is possible to prevent thermal runaway and explosion of a battery by the formed ion conduction-interrupting layer (also referred to as interrupting layer), and thus to improve the heat resistance and safety of the battery.

Electrolyte membrane for all-solid-state battery and all-solid-state battery including the same

The present disclosure relates to a solid electrolyte membrane including a polymer electrolyte material and a porous polymer sheet which form a composite with each other in such a manner that the pores of the porous polymer sheet filled with the polymer electrolyte material, and a method for manufacturing the same. Since the porous polymer material and the solid electrolyte material form a composite with each other, it is possible to obtain a solid electrolyte membrane having excellent strength and a small thickness of 50 μm or less, and thus to improve the energy density of a battery.

Solid electrolyte membrane, method for manufacturing same, and all-solid-state battery comprising same

Provided is a solid electrolyte membrane for a solid-state battery, including at least two solid electrolyte layers and at least one volume-swelling layer, wherein the volume-swelling layer is disposed between the solid electrolyte layers. The solid electrolyte membrane includes (a) an ion conductive solid electrolyte material, and the volume-swelling layer includes (b) inorganic particles, wherein the inorganic particles form an alloy with lithium and include a metal, metal oxide or both. Thus, it is possible to provide a solid electrolyte membrane for a solid-state battery fundamentally prevented from a short-circuit by inhibiting growth of lithium dendrite.

Solid electrolyte membrane and solid-state battery comprising same

The present disclosure relates to an electrode for an all solid-state battery and a method for manufacturing the same. The electrode comprises an electrode active material layer, wherein the gaps between the electrode active material particles forming the electrode active material layer are filled with a mixture of a polymeric solid electrolyte and a conductive material. The method for manufacturing the electrode comprises a solvent annealing process, and the contact between the electrode active material particles and the conductive material is improved through the solvent annealing process, thereby improving ion conductivity of the electrode and capacity realization in the battery.

Method for manufacturing electrode comprising polymeric solid electrolyte and electrode obtained thereby

In a solid electrolyte membrane according to the present disclosure, an ion conduction blocking layer is formed in the electrolyte membrane by a polymer material having low ionic conductivity by phase separation of polymer under the high temperature condition such as an increase in the internal temperature of a battery, to block the movement of lithium ions. The formed ion conduction blocking layer (hereinafter referred to as blocking layer) prevents thermal runaway and consequential explosions of the battery, thereby improving the heat resistance safety of the battery.

Electrolyte membrane for all-solid-state battery, and all-solid-state battery comprising same

The present disclosure relates to an electrode for an all solid-state battery and a method for manufacturing the same. The electrode comprises an electrode active material layer, wherein the gaps between the electrode active material particles forming the electrode active material layer are filled with a mixture of a polymeric solid electrolyte, oxidation-/reduction-improving additive and a conductive material. The method for manufacturing the electrode comprises a solvent annealing process, and the dissociation degree and transportability of the oxidation-/reduction-improving additive are increased through the solvent annealing process, thereby improving the life characteristics of a battery.

The present disclosure relates to an electrode for an all solid-state battery and a manufacturing method thereof, and a mixture of a polymer-based solid electrolyte and a conductive material is filled between electrode active material particles that constitute an electrode active material layer, to increase the contact between the electrode active material particles and the conductive material through a solvent annealing process included in a manufacturing process, thereby improving ionic conductivity in the electrode and capacity in the electrode.

Method for manufacturing electrode comprising polymer-based solid electrolyte and electrode manufactured by the method

A solid electrolyte membrane for a solid-state battery and a battery comprising the same is provided. The battery may comprise lithium metal as a negative electrode active material. The solid electrolyte membrane comprises an inhibiting layer, which is preferably capable of inhibiting growth of lithium dendrite, because it includes an effective amount of a dendrite growth-inhibiting material, which is capable of ionizing lithium deposited in the form of metal. Thus, when lithium metal is used as a negative electrode for a solid-state battery comprising the solid electrolyte membrane, it is possible to delay and/or inhibit growth of lithium dendrite, and thus to effectively prevent an electrical short-circuit caused by dendrite growth.

Solid electrolyte membrane and solid-state battery comprising the same

A solid electrolyte membrane and method of preparing, including a plurality of polymer filaments arranged crossed as a 3-dimensional structure in the form of a net of nonwoven fabric-like shape, and a plurality of inorganic solid electrolytes inserted and uniformly distributed in the structure. By this structural feature, a large amount of solid electrolyte particles are uniformly distributed and filled in the electrolyte membrane, contact between the particles is good, and ionic conduction paths are sufficiently provided. Additionally, the durability of the solid electrolyte membrane is improved by the 3-dimensional structure, and the flexibility and strength increase. The nonwoven fabric composite solid electrolyte membrane has an effect in preventing inorganic solid electrolyte particle from being disconnected therefrom.

Method for manufacturing solid electrolyte membrane for all solid type battery and solid electrolyte membrane manufactured by the method

The present disclosure relates to an all solid-state battery cell and a method for manufacturing the same. The gaps between the electrode active material particles forming the electrode active material layer are filled with a mixture of a polymeric solid electrolyte with a conductive material, and an organic solid electrolyte membrane is interposed between the positive electrode and the negative electrode. The method comprises a solvent annealing process to improve the contact between the electrode active material particles and the conductive material and to improve the contact between the electrode active material layer and the organic solid electrolyte membrane, thereby providing an all solid-state battery cell with improved ion conductivity and capacity realization.

Method for manufacturing all solid-state battery comprising polymeric solid electrolyte and all solid-state battery obtained thereby

Disclosed are an electrode having a three-dimensional structure, the electrode including: a porous nonwoven web including a plurality of polymer fibers that form an interconnected porous network; an active material composite positioned among the polymer fibers and including active material particles and a first conductive material; and a second conductive material positioned on an outer surface of the active material composite, wherein the interconnected porous network is filled homogeneously with the active material composite and the second conductive material to form a super lattice structure, and an electrochemical device including the electrode having a three-dimensional structure.

Electrode having three dimensional structure and electrochemical device including the same

An electrode for a solid state battery is provided. The electrode active material layer of the electrode shows improved mechanical properties, such as elasticity or rigidity, of the electrode layer through the crosslinking of a binder resin. Thus, it is possible to inhibit or reduce the effect of swelling and/or shrinking of the electrode active material during charging/discharging. Therefore, the interfacial adhesion between the electrode active material layer and an electrolyte layer and the interfacial adhesion between the electrode active material layer and a current collector are maintained to a high level to provide a solid state battery having excellent cycle characteristics.

Electrode for solid state battery and method for manufacturing the same

Provided is a composite solid electrolyte membrane for an all-solid-state secondary battery, including: a phase transformation layer containing a plasticizer and a lithium salt; a porous polymer sheet layer; and a solid polymer electrolyte layer, wherein the phase transformation layer, the porous polymer sheet layer and the solid polymer electrolyte layer are stacked successively, and the phase transformation layer is disposed in such a manner that it faces a negative electrode when manufacturing an electrode assembly. An all-solid-state secondary battery including the composite solid electrolyte membrane is also provided. The composite solid electrolyte membrane for an all-solid-state secondary battery reduces the interfacial resistance with an electrode, increases ion conductivity, and improves the safety of a battery.

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Daejeon, South Korea

Sung-Joong Kang