Samsung Electronics Co., Ltd.

Sung-Je Choi

Sang-in Lee

Young-wook Park

Han-jin Lim

Jae-Soon Lim

Yeong-kwan Kim

A method of forming a capacitor having a lower electrode, an upper electrode, and a dielectric layer of an integrated circuit device is provided. A metal compound is adsorbed on the lower electrode by using a gaseous metal compound. A physisorbed metal compound on the lower electrode is purged by using an inert gas. The metal compound adsorbed on the lower electrode is oxidized with an oxidation gas to form a metal oxide. A gaseous product formed by oxidizing the metal compound is purged. Above steps are repeated to form a diffusion barrier layer of the metal oxide. The dielectric layer is formed of TaOon the diffusion barrier layer. A heat treatment is performed for the dielectric layer comprised of TaOunder oxidation atmosphere. The steps are performed in a single atomic layer deposition chamber.

Method of forming a capacitor of an integrated circuit device

In a method of forming a thin film using an atomic layer deposition (ALD) method, a thin film is formed on a substrate in cycles. Each cycle includes injecting a first reactant including an atom that forms the thin film and a ligand into a reaction chamber that includes the substrate, purging the first reactant, injecting a second reactant into the reaction chamber, and purging the second reactant. The thin film is formed by a chemical reaction between the atom that forms the thin film and a second reactant whose binding energy with respect to the atom that forms the thin film is larger than the binding energy of the ligand with respect to the atom that forms the thin film and the generation of by-products is prevented. The generation of a hydroxide by-product in the thin film is suppressed by using a material that does not include a hydroxide as the second reactant, purging the second reactant, and reacting the second reactant with a third reactant that includes hydroxide. After purging the second reactant, the third reactant for removing impurities and improving the stoichiometry of the thin film is injected and purged. In this way, it is possible to obtain a thin film that does not include impurities and whose stoichiometry is excellent.

Method of forming thin film using atomic layer deposition method

A method for forming a dielectric layer of a semiconductor device is disclosed. A semiconductor wafer is loaded into a reaction chamber. A source gas mixture containing at least two mixed chemical reactants is introduced into the reaction chamber, thereby chemically adsorbing a portion of the source gas mixture onto a surface of the semiconductor wafer. The chamber is purged or pumped to remove physisorbed reactants therefrom. The source gas mixture chemically adsorbed on the surface of the semiconductor wafer is oxidized to form an atomic layer.

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Seoul, South Korea

Sung-Je Choi