Fuji Electric Co., Ltd.

Sumitaka Nogami

Michihiro Kitazawa

Yoichi Nakamura

Katsuhiro Sato

Nobuyoshi Mori

Hideki Kina

Kaneyuki Mantoku

Takashi Obinata

Yasushi Iguchi

Shinjiro Suzuki

Koichi Aizawa

Akira Takahashi

Yoshimasa Tomiuchi

Yukihisa Tamura

Hideki Komiyama

Kyoko Kitagawa

A laminate type organic electrophotographic photoconductor uses a thick undercoating layer as an intermediate layer for reducing the influence of a conductive substrate on a charge generation layer. An organosilicon coupling agent is bonded to the surfaces of small particles of titanium oxide, zirconium oxide, aluminum oxide or cerium oxide, at an Existence Ratio represented by the peak intensity ratio (Si2p/Me2p, Me=Ti, Zr or Al) or (Si2p/Ce3d) of from 0.15 to 0.6 of a bonding energy spectrum measured by X-ray photoelectron spectroscopy. The metal oxide small particles, the surfaces of which have been treated mechanochemically, are cleaned to reduce the ionic impurity concentration of the undercoating layer to below 1 ppm. The cleaned metal oxide small particles are dispersed into the polyamide copolymer binder resin for the undercoating layer. The undercoating layer produced in this manner results in a electrophotographic photoconductor whose electrical properties are constant despite environmental changes and repeated use. The electrophotographic photoconductor also resists residual potential rise after repeated use, and also resists image defect formation despite changes in environmental conditions and operating conditions.

Electrophotographic photoconductor and method of manufacturing same

An electrophotographic photoconductor includes a conductive substrate, an intermediate layer on the conductive substrate, and a photoconductive layer on the intermediate layer. The intermediate layer includes an n-type semiconductive organic pigment.

Electrophotographic photoconductor

In an electrophotographic photoconductor wherein an intermediate layer and a photosensitive layer are successively formed on a conductive substrate, a conductive boron polymer is used for forming the intermediate layer.

Electrophotographic photoconductor with conductive boron polymer

An inverted-lamination organic positive-photoconductor for electrophotography comprises a conductive substrate, a charge transport layer on the conductive substrate, a charge generation layer on the charge transport layer, a surface protection layer on the charge generation layer, with the surface protection layer containing a polyaniline compound which includes being doped with a protonic acid selected from a sulfonic acid, a carboxylic acid, an organophosphoric acid, or a potential compound, wherein the potential compound is a compound that reacts to form one of a sulfonic acid, a carboxylic acid, or an organophosphoric acid.

Inverted-lamination organic positive-photoconductor for

In order to provide a laminate type organic photoconductor for electrophotography excellent in abrasion resistance and having enhanced stability of characteristics and high productivity, a binder resin of a charge transport layer as an outermost layer of the laminate type photoconductor includes a specified copolymer polycarbonate resin containing at least one constitutional unit of those represented by a formula (1) and at least one constitutional unit of those represented by a formula(2).

Photoconductor for electrophotography

An electrophotographic photoconductor includes an electroconductive substrate and a photosensitive layer which is provided on the electroconductive substrate and which includes a charge generating agent, a hole charge transporting agent, and antioxidant composed of at least two antioxidant materials. In a second embodiment, the electrophotographic photoconductor includes an electroconductive substrate and a photosensitive layer which is provided on the electroconductive substrate and which includes a charge generating layer containing a charge generating agent and a charge transporting layer containing a hole charge transporting agent, and antioxidant composed of at least two antioxidant materials.

Electrophotographic photosensitive material

A photoconductor for electrophotography includes a conductive substrate; an undercoating layer formed on the conductive substrate; a charge generation layer formed on the undercoating layer; and a charge transport layer formed on the charge generation layer, wherein the undercoating layer comprises a coating film containing as the main constituent thereof an addition compound containing iodine added thereto, and wherein the charge generation layer comprises a P-type charge generation material containing iodine added thereto.

An electrophotographic photoreceptor has a conductive substrate and a photosensitive layer formed on the substrate. The photosensitive layer contains one compound which is selected from the group of the compounds represented by the formulae (I), (II), (III), (IV), and (V). Therefore, the electrophotographic photoreceptor shows stable characteristics, good durability, and long span of life in repeat use.

Electrophotographic photoreceptors with anti-oxidizing agents

An electrophotographic photoconductor include an conductive substrate; an undercoat layer provided on the conductive substrate; and a photosensitive layer having charge-generation and charge-transport functions provided on the undercoat layer. The undercoat layer includes a polyamide resin and methylhydrogenpolysiloxane-treated titanium dioxide and preferably styrene-maleic acid half-ester copolymer. The photoconductor can be produced by the steps of: dispersing a polyamide resin and methylhydrogenpolysiloxane-treated titanium dioxide and preferably styrene-maleic acid half-ester copolymer in a mixture solvent of an alcohol-type solvent and a halogenated hydrocarbon-type solvent, thereby preparing a coating liquid for an undercoat layer; applying the coating liquid onto a conductive substrate, thereby providing an undercoat layer on the substrate; and forming a photosensitive layer on the undercoat layer.

Electrophotographic photoconductor and process for producing the same

A photoconductor for electrophotography includes an electroconductive substrate; and a photosensitive layer provided on the electroconductive substrate and composed of an intermediate layer, a charge generation layer, and a charge transfer layer laminated in this order, wherein the intermediate layer is a doped layer and is composed of a cured layer of a copolycondensate between an amino resin and a phenolic resin hat has been subjected to doping with at least one dopant.

Photoconductor having a cured layer of an amino resin-phenol resin

An electrophotographic photoconductor having superior electrical properties and image quality which are not affected by the external environment is provided. The photoconductor includes an intermediate layer formed between a conductive substrate and a photosensitive layer. The intermediate layer is a hardened film containing as its main components melamine resin, aromatic carboxylic acid and/or aromatic carboxylic anhydride, and fixed iodine. Alternatively, the intermediate layer is composed of normal-butylated melamine resin, acid and/or an acid equivalent, and fixed iodine. The film thickness of the intermediate layer according to the present invention need not be as thin as in the prior art. An intermediate layer of such a thickness can cover various defects on the surface of the conductive substrate, and a uniform photosensitive layer with few film defects can be formed on the intermediate layer. In particular, even in the case of a photoconductor with a photosensitive layer composed of a charge-transfer layer laminated on a charge-generation layer, a thin-film, charge-generation layer can be easily formed without experiencing non-uniform film growth.

Photoconductor element of an electrophotographic device

An electrophotographic photoconductor has an intermediate layer formed between an electrically conductive substrate and photosensitive layer. The intermediate layer is made of a hardened film formed by hardening an amino resin with a catalyst comprising aromaticsulfonic acid, alicyclicsulfonic acid, a mixture thereof, or latent acid thereof to provide good image qualities without causing any troubles in the process of image formation.

A positively charged organic photosensitive body is provided, the photosensitive body being free from public hazards, and being highly sensitive and highly durable. The photosensitive body has a photosensitive layer of a laminated structure on a conductive substrate. The photosensitive layer has a charge transport layer (I) having hole mobility, a charge generation layer, and a charge transport layer (II) containing a curing product of a doped amino resin and having electron mobility. The charge transport layer (I), the charge generation layer, and the charge transport layer (II) are laminated in this order on the conductive substrate. Various suitable substances may be added to the charge transport layer (II), thereby enhancing its durability without deteriorating the photosensitive characteristics.

Photosensitive body for electrophotography

An organic photosensitive member for electrophotography is provided which comprises a photosensitive layer 3 formed on an electroconductive substrate 1 via an undercoating layer 2, the photosensitive layer 3 comprising a charge generating layer 4 and a charge transporting layer 5, wherein the undercoating layer 2 consists essentially of 12/6/66 copolymeric polyamide expressed by the general formula (I) ##STR1## and a styrene/maleic acid half ester copolymer. By providing such an undercoating layer, it becomes possible to obtain a photosensitive member having excellent electrophotographic characteristics, involving minimal changes in these characteristics during repeated use, and giving a high quality image stably.

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Kawasaki, Japan

Sumitaka Nogami