Baker Hughes, a Ge Compnay, LLC

Baker Hughes Holdings LLC

Baker Hughes Corporation

Sumit Bhaduri

Terry D Monroe

Qi Qu

Naima Bestaoui-Spurr

Hoang Van Le

Kimberly Spurlock Lant

James B Crews

Brian Benedict Beall

Frances H DeBenedictis

D V Satyanarayana Gupta

Shannon E Bryant

Paul S Carman

Harold Gene Hudson

Dv Satyanarayana Gupta

Ahmed S Zakaria

Frances H Debenedictis

Francis H DeBenedictis

Brian B Beall

Freeman Hill

Terry Monroe

Oil-soluble well treatment agents may be slowly released into a well or a subterranean formation by use of an aqueous fluid of (i) an oil-in-water dispersion having the oil-soluble well treatment agent as a dispersed phase and (ii) a second component having an oil-soluble or water-soluble primer coated onto a portion of its surface. The amount of the oil-soluble well treatment agent in the oil-in-water dispersion is from 20 to 50 weight percent and the average particle size of the oil-soluble well treatment agent in the dispersion may be from 0.005 to 2 micrometers. The oil-in-water dispersion may further contain a water-soluble well treatment agent.

Method of introducing oil-soluble well treatment agent into a well or subterranean formation

The disclosure relates to an aqueous acidizing fluid. In addition to an acid, the fluid contains an organophosphorus surfactant and/or an acid retarder. The organophosphorus surfactant may be an amino phosphonate or a phosphino carboxylate. The acid retarder comprises the combination of urea or a urea derivative and a bifunctional organic compound. Suitable bifunctional organic compounds contain at least one quaternary ammonium or phosphonium and at least one alcohol as well as salts of nitrogen containing heterocyclic rings.

Aqueous delayed acid system for well stimulation

A system for slowly releasing an oil-soluble well treatment agent into a well or a subterranean formation includes a composite of the oil-soluble well treatment agent associated with a second component. The amount of the oil-soluble well treatment agent in the composite is from 20 to 35 weight percent and the average particle size of the oil-soluble well treatment agent in the composite is less than or equal to 1 micrometer. The composite may further contain a water-soluble well treatment agent.

Delivery system for oil-soluble well treatment agents and methods of using the same

A method of treating a well or a subterranean formation with an aqueous treatment fluid containing one or more oil-soluble, water-insoluble well treatment agents. The fluid includes an aqueous dispersion containing the well treatment agent in an amount from 25 to 60 weight percent. The volume average particle diameter of the oil-soluble well treatment agent in the fluid may be less than or equal to 2.5 microns. The fluid may further contain a water-soluble well treatment agent.

Treatment methods using aqueous fluids containing oil-soluble treatment agents

Fouling caused by contaminants onto a metallic tubular, flow conduit or vessel in an underground reservoir or extending from or to an underground reservoir may be inhibited by applying onto the surface of the metallic tubular, flow conduit or vessel a treatment agent comprising a hydrophobic tail and an anchor. The anchor attaches the treatment agent onto the surface of the metallic tubular, flow conduit or vessel.

Method of inhibiting deposition of contaminants onto a metallic surface with a surface modifying treatment agent

A well treatment fluid contains a surface modifying treatment agent having an anchor and a hydrophobic tail. The surface modifying treatment agent is an organophosphorus acid derivative. After the well treatment fluid is pumped into a well penetrating the subterranean formation, the anchor binds to the surface of the formation. The subterranean formation is a siliceous formation or a metal oxide-containing subterranean formation. The anchor bonds to a Si atom when the formation is a siliceous formation and to the metal of the metal oxide when the formation is a metal oxide-containing formation. After being bound to the surface of the formation, frictional drag within the well is reduced. This allows for faster recovery of formation fluids. The bonding of the surface modifying treatment agent onto the formation may further be enhanced by first pre-treating the formation with a non-aqueous fluid. By increasing the number of sites for the surface modifying treatment agent to bind onto the surface of the subterranean formation, productivity is improved.

Method of using surface modifying treatment agents to treat subterranean formations

A composite having a solid particulate and a surface modifying treatment agent on the solid particulate wherein the surface modifying treatment agent has a hydrophobic tail and an anchor for adhering the hydrophobic tail onto the solid particulate. The anchor is an organophosphorus acid derivative. The composite may be used as a proppant in a hydraulic fracturing operation as well as a sand control particulate in a gravel packing operation. The presence of the surface modifying treatment agent on the surface of the solid particulate reduces the generation of fines and dust as well as the migration of sand during a hydraulic fracturing operation or a sand control operation. The presence of the surface modifying treatment agent on the surface of the solid particulate further enhances the crush resistance of the solid particulate.

Organophosphorus containing composites for use in well treatment operations

A well treatment fluid contains a surface modifying treatment agent having an anchor and a hydrophobic tail. The surface modifying treatment agent is an organophosphorus acid derivative. After the well treatment fluid is pumped into a well penetrating the subterranean formation, the anchor binds to the surface of the formation. The subterranean formation is a siliceous formation or a metal oxide-containing subterranean formation. The anchor bonds to a Si atom when the formation is a siliceous formation and to the metal of the metal oxide when the formation is a metal oxide-containing formation. After being bound to the surface of the formation, frictional drag within the well is reduced. This allows for faster recovery of formation fluids. The bonding of the surface modifying treatment agent onto the formation may further be enhanced by first pre-treating the formation with an aqueous fluid. By increasing the number of sites for the surface modifying treatment agent to bind onto the surface of the subterranean formation, productivity is improved.

Method of pumping aqueous fluid containing surface modifying treatment agent into a well

A downhole treatment composition comprises a rare earth-containing compound comprising one or more of the following: scandium; yttrium; lanthanum; cerium; praseodymium; neodymium; promethium; samarium; lutetium; europium; gadolinium; terbium; dysprosium; holmium; erbium; thulium; or ytterbium, wherein the downhole treatment composition is a cement slurry, a drilling fluid, or a spacer fluid. Also disclosed are methods of cementing a wellbore, methods of displacing a first fluid, and methods of drilling a wellbore in a subterranean formation using the cement slurry, the spacer fluid, or the drilling fluid.

Rare earth-containing compounds to enhance performance of downhole treatment compositions

Method of inhibiting fouling on a metallic surface using a surface modifying treatment agent

A method of improving the flow of a proppant pack or gravel pack comprises: introducing into a subterranean formation or a well a plurality of ceramic particles, the ceramic particles comprising about 0.1 wt. % to about 25 wt. % of a rare earth-containing compound, based on the total weight of the ceramic particles; and forming a proppant pack or gravel pack comprising the plurality of the ceramic particles; wherein the proppant pack or gravel pack improves fluid flow as compared with a reference proppant pack or gravel pack formed from otherwise identical ceramic particles except for being free of the rare earth-containing compound.

Rare earth materials to enhance properties of ceramic particles

Water and gas flow into a subterranean reservoir may be reduced by pumping into the reservoir a multi-aldehyde crosslinking agent and a low molecular weight polyacrylamide capable of crosslinking with the crosslinking agent. The reaction product forms a gel plug impermeable to water and gas.

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The Woodlands, TX, United States of America

Sumit Bhaduri