Sumitomo Chemical Company, Limited

Suketsugu Koumura

Hirohito Kenmochi

Kazuyoshi Hirabayashi

Yoshihisa Sueda

Yoshio Mori

Hisashige Terao

Takemi Tokieda

Nobuzi Nishimura

Seizo Konishi

Utazi Sawa

Masayuki Tsuji

Tadashi Yamamoto

A dye composition comprising at least one disazo dye of the formula (I) expressed in the form of a free acid, ##STR1## wherein each X.sub.1 and X.sub.2 is --SO.sub.2 CH.sub.2 CH.sub.2 OCOCH.sub.3, --SO.sub.2 CH.sub.2 CH.sub.2 OSO.sub.3 H or --SO.sub.2 CH.dbd.CH.sub.2, provided that at least one of X.sub.1 and X.sub.2 is --SO.sub.2 CH.sub.2 CH.sub.2 OCOCH.sub.3, and at least one disazo dye of the formula (II) expressed in the form of a free acid, ##STR2## Wherein each Y.sub.1 and Y.sub.2 is --SO.sub.2 CH.sub.2 CH.sub.2 OSO.sub.3 H, --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 OH, provided that one of Y.sub.1 and Y.sub.2 is --SO.sub.2 CH.sub.2 CH.sub.2 OSO.sub.3 H or --SO.sub.2 CH.dbd. CH.sub.2, is produced by diazotizing a mixture of 4-aminophenyl-.beta.-sulfatoethylsulfone and 4-aminophenyl-.beta.acetoxyethylsulfone in a weight ratio of 30 to 70: 70 to 30 with a nitrite, and coupling the resulting mixture of the diazonium salts with 1-amino-8-naphthol-3,6-disulfonic acid. The dye composition is suitable for dyeing natural or regenerated cellulosic fiber materials in black.

Disazo dye composition

A dye, which is suitable for dyeing cellulosic fiber materials, of the formula, ##STR1## wherein R and R' are each hydrogen, a C.sub.1 -C.sub.4 alkyl, or C.sub.1 -C.sub.4 hydroxyalkyl, m is an integer of 1 to 6, n and n' are each an integer of 2 to 4, and when m is 2 or more, n may be the same or different integer between 2 and 4, X is hydrogen or a group of the formula ##STR2## (wherein Q is a dye residue, R.sub.1 is hydrogen or a C.sub.1 -C.sub.4 alkyl and R.sub.2 is halogen); Y is hydrogen or a group of the formula ##STR3## (wherein Q' is a dye residue, and when m is 2 or more, Q's may be the same or different, R.sub.1 ' is hydrogen or a C.sub.1 -C.sub.4 alkyl and R.sub.2 ' is halogen); Z is hydrogen or a group of the formula ##STR4## (wherein Q' is a dye residue, R.sub.1 ' is hydrogen or a C.sub.1 -C.sub.4 alkyl and R.sub.2 ' is halogen, Q, Q' and Q' may independently be the same or different and X, Y and Z are not hydrogen at the same time).

Triazinyl-antraquinone dyes

A dye, which is suitable for dyeing cellulosic fiber materials, of the formula, ##STR1## wherein R and R' are each hydrogen, a C.sub.1 -C.sub.4 alkyl, or C.sub.1 -C.sub.4 hydroxyalkyl, m is an integer of 1 to 6, n and n' are each an integer of 2 to 4, and when m is 2 or more, n may be the same or different integer between 2 and 4, X is hydrogen or a group of the formula ##STR2## (wherein Q is a dye residue, R.sub.1 is hydrogen or a C.sub.1 -C.sub.4 alkyl and R.sub.2 is halogen); Y is hydrogen or a group of the formula ##STR3## 1 (wherein Q' is a dye residue, and when m is 2 or more, Q's may be the same or different, R.sub.1 ' is hydrogen or a C.sub.1 -C.sub.4 alkyl and R.sub.2 ' is halogen); Z is hydrogen or a group of the formula ##STR4## 5 (wherein Q' is a dye residue, R.sub.1 ' is hydrogen or a C.sub.1 -C.sub.4 alkyl and R.sub.2 ' is halogen, Q, Q' and Q' may independently be the same or different and X, Y and Z are not hydrogen at the same time).

Metallized triazine reactive dyes

A dye, which is suitable for dyeing cellulosic fiber materials, of the formula, ##STR1## wherein R and R' are each hydrogen, a C.sub.1 - C.sub.4 alkyl, or C.sub.1 - C.sub.4 hydroxyalkyl, m is an integer of 1 to 6, n and n' are each an integer of 2 to 4, and when m is 2 or more, n may be the same or different integer between 2 and 4, X is hydrogen or a group of the formula ##STR2## (wherein Q is a dye residue, R.sub.1 is hydrogen or a C.sub.1 - C.sub.4 alkyl and R.sub.2 is halogen); Y is hydrogen or a group of the formula ##STR3## (wherein Q' is a dye residue, and when m is 2 or more, Q's may be the same or different, R.sub.1 ' is hydrogen or a C.sub.1 - C.sub.4 alkyl and R.sub.2 ' is halogen); Z is hydrogen or a group of the formula ##STR4## (wherein Q' is a dye residue, R.sub.1 ' is hydrogen or a C.sub.1 - C.sub.4 alkyl and R.sub.2 ' is halogen, Q, Q' and Q' may independently be the same or different and X, Y and Z are not hydrogen at the same time).

Triazine reactive dyes

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Ibaragi, Japan

Suketsugu Koumura