Sk Energy Co., Ltd.

Sk Innovation Co., Ltd.

Korea Research Institute of Chemical Technology

Sk Global Chemical Co., Ltd.

Sk Gc Americas Inc.

Sk Innovation., Ltd.

Sk Geo Centric Co., Ltd.

Suk Joon Kim

Sun Woong Choi

Deuk Soo Park

Yong Ki Park

Won Choon Choi

Hee Young Kim

Chul Wee Lee

Yong Seung Kim

Na Young Kang

Dae Hyun Choo

Seung Hoon Oh

Ji Min Kim

Hong Chan Kim

Bu Sub Song

Il Mo Yang

Tae Jin Kim

Ahn Seop Choi

Sang Yun Han

Jeong Ri Kim

Kwang An Ko

Byoung Cheon Jo

Doh Yeon Park

Tae-Jin Kim

Hai Jin Shin

Young Ki Park

Yong Zheng

Ju Eun Jung

Christopher Balhoff

Mark Jasek

Du Youn Ka

An ethylene-(meth)acrylic acid copolymer has a polydispersity index (PDI) in a range from 3.5 to 8.0, and has a melt flow index (MFI) measured at 190&#xb0; C. and 2.16 kg in a range from 350 g/10 min to 1800 g/10 min A water-dispersive composition includes the ethylene (meth)acrylic acid copolymer, a neutralizing agent and an aqueous medium.

Ethylene-(meth)acrylic acid copolymer and water-dispersive composition including the same

Disclosed are a molecular sieve catalyst and a preparation method thereof to produce light olefins from cracking naphtha catalytically in severe environments of high temperature and high moisture. In detail, the catalyst is prepared by spray-drying and calcining the mixed slurry, in which 0.01&#x2dc;5.0 wt % of MnOand 1&#x2dc;15 wt % of POare simultaneously imbedded in catalyst which consists of zeolite, clay and inorganic complex. According to the present invention, the method that manganese and phosphate are imbedded simultaneously in zeolite and inorganic complex is used to increases thermal-stability of obtained spherical catalyst, and increase olefin yield of cracking hydrocarbon such as naphtha by protecting acid-site of zeolite. To synthesize the required catalyst, the important procedures are mixing ratio and mixing sequence of Mn, P, zeolite, and inorganic complex.

Catalyst for catalytic cracking of hydrocarbon, which is used in production of light olefin and production method thereof

A method of preparing ZSM-5, including: providing a nanocrystalline ZSM-5 seed having a size of 70-150 nm; adding the nanocrystalline ZSM-5 seed to a stock solution including water glass as a silica source, an alumina source, a neutralizer and water to form a reaction mixture; and maintaining the reaction mixture at 150-200&#xb0; C. to crystallize the reaction mixture. The method is advantageous in that ZSM-5 having small and uniform crystal sizes and including no impurities can be synthesized in a short period of time.

Method of preparing ZSM-5 zeolite using nanocrystalline ZSM-5 seeds

Disclosed is a catalytic cracking process for the production of light olefins from a hydrocarbon feedstock using fast fluidization, which is a preferred process for more efficiently increasing the production of light olefin hydrocarbons. According to this invention, a fast fluidization regime is applied to a fluidized bed catalytic cracking process of producing light olefins using zeolite, such that a volume fraction and distribution of the catalyst sufficient to induce the catalytic cracking reaction can be provided, thus effectively enhancing the production of light olefin hydrocarbons, in particular, ethylene and propylene, at high selectivity.

Catalytic cracking process using fast fluidization for the production of light olefins from hydrocarbon feedstock

Disclosed is a process for increasing production of light olefinic hydrocarbons from hydrocarbon feedstock by catalytic cracking. In the process, an effective separation process structure and recycle method of light olefins are used not only to increase the productivity and efficiency of an overall process, thus effectively increasing the production of light olefins, but also to simplify the overall process.

Process for increasing production of light olefins from hydrocarbon feedstock in catalytic cracking

Disclosed is a process for producing light olefins from hydrocarbon feedstock. The process is characterized in that a porous molecular sieve catalyst consisting of a product obtained by evaporating water from a raw material mixture comprising a molecular sieve with a framework of Si&#x2014;OH&#x2014;Al&#x2014; groups, a water-insoluble metal salt, and a phosphate compound, is used to produce light olefins, particularly ethylene and propylene, from hydrocarbon, while maintaining excellent selectivity to light olefins. According to the process, by the use of a specific catalyst with hydrothermal stability, light olefins can be selectively produced in high yield with high selectivity from hydrocarbon feedstock, particularly full-range naphtha. In particular, the process can maintain higher cracking activity than the reaction temperature required in the prior thermal cracking process for the production of light olefins, and thus, can produce light olefins with high selectivity and conversion from hydrocarbon feedstock.

Process for production of light olefins from hydrocarbon feedstock

A porous solid acid catalyst for producing light olefins is prepared through pillaring and a solid state reaction of a raw material mixture. The catalyst is made of a porous material having a crystalline structure that is different from that of the raw material mixture. The catalyst exhibits excellent catalytic activity (i.e., conversion and selectivity) in the production of light olefins from hydrocarbon feeds such as full range naphthas.

Solid acid catalyst for producing light olefins and process using the same

Disclosed are a hydrothermally stable porous molecular sieve catalyst and a preparation method thereof. The catalyst consists of a product obtained by the evaporation of water from a raw material mixture comprising a molecular sieve having a framework of Si&#x2014;OH&#x2014;Al&#x2014;, a water-insoluble metal salt and a phosphate compound. The catalyst maintains its physical and chemical stabilities even in an atmosphere of high temperature and humidity. Accordingly, the catalyst shows excellent catalytic activity even when it is used in a severe process environment of high temperature and humidity in heterogeneous catalytic reactions, such as various oxidation/reduction reactions, including catalytic cracking reactions, isomerization reactions, alkylation reactions and esterification reactions.

Hydrothermally stable microporous molecular sieve catalyst and preparation method thereof

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Daejeon, South Korea

Suk Joon Kim