Dow Global Technolgoies LLC

Rohm and Haas Company

Ddp Specialty Electronic Materials US, LLC

Steven Rosenberg

Abhishek Roy

Steven Douglas Jons

Ian A Tomlinson

Mou Paul

XiaoHua Qiu

Robert C Cieslinski

David D Hawn

Martin H Peery

Joseph D Koob

Tina L Arrowood

Chengli Zu

Mark Alan Rickard

Aman A Desai

Bruce B Gerhart

Ralph Craig Even

Alfred Karl Schultz

Chunming Zhang

Andrew M Savo

John David Finch

Lester Howard McIntosh, Iii

Matthew D Reichert

Robert Johnson

Decai Yu

Jon E Johnson

Huang Wu

Derek M Stevens

Yasushi Maeda

Anand S Badami

XiaoHua Sam Qiu

Lester H Mcintosh

A filtration assembly including: a hyperfiltration assembly including: a high pressure vessel including a feed port, concentrate port and permeate port, and a plurality of serially arranged spiral wound hyperfiltration membrane modules; a bioreactor assembly including: a low pressure vessel comprising a first and second port, and a plurality of spiral wound bioreactors located within the low pressure vessel with each bioreactor comprising a flat sheet having two opposing bio-growth surfaces and a feed spacer spirally wound about an axis; and a fluid flow pathway extending from a fluid feed source: into the first port of the low pressure vessel, through the bioreactors and out the second port of the low pressure vessel, and into the feed port of the high pressure vessel, through the membrane modules and out of the concentrate port and permeate port.

Filtration assembly including spiral wound bioreactors and membrane modules positioned in separate pressure vessels

A method for making a composite polyamide membrane comprising a porous support and a thin film polyamide layer, wherein the method includes: i) applying a polar solution comprising a polyfunctional amine monomer, and a non-polar solution comprising a polyfunctional acyl halide monomer to a surface of a porous support and interfacially polymerizing the monomers to form a thin film polyamide layer, wherein the non-polar solution further comprises at least 50 vol % of a Cto Caliphatic hydrocarbon and from 2 to 25 vol % of benzene or benzene substituted with one or more Cto Calkyl groups; and ii) applying an aqueous solution of nitrous acid to the thin film polyamide layer.

Composite polyamide membrane made via interfacial polymerization using a blend of non-polar solvents

A thin film composite polyamide membrane comprising a porous support and a thin film polyamide layer characterized by possessing: i) an azo (&#x2014;N&#x2550;N&#x2014;) content of from 0.40% to 1.00%, as measured by pyrolysis gas chromatography; and ii) a dissociated carboxylate content of at least 0.40 mol/kg as measured by RBS at pH 9.5.

Composite polyamide membrane having azo content and high acid content

Provided is a method of suspension polymerization comprising

Suspensions in aqueous media

A method for making a composite polyamide membrane including a porous support and a thin film polyamide layer including the steps of applying a polyfunctional amine monomer and a combination amine-reactive compounds to a surface of the porous support and reacting the constituents to form a thin film polyamide layer, wherein the amine-reactive compounds include: i) a polyfunctional amine-reactive monomer including two to three amine-reactive moieties selected from acyl halide, sulfonyl halide and anhydride, ii) a polyfunctional amine-reactive monomer including at least four amine-reactive moieties selected from acyl halide, sulfonyl halide and anhydride, and iii) an acid compound including at least on carboxylic acid moiety or salt thereof and at least one amine-reactive moiety selected from acyl halide and sulfonyl halide.

Membrane derived from polyfunctional amine and combination of different polyfunctional amine-reactive monomers

Provided is a suspension comprising liquid droplets dispersed in an aqueous medium, wherein said droplets comprise (a) one or more water-insoluble compounds, and (b) a vinyl polyelectrolyte (PED) having a polarity, and wherein said aqueous medium comprises a polyelectrolyte (PEW) having a polarity that is opposite to the polarity of said polyelectrolyte (PED). Also provided are a method of making such a suspension and a method using such a suspension in a process of suspension polymerization.

A method for making a composite polyamide membrane comprising a porous support and a thin film polyamide layer, wherein the method includes the steps of applying a polar solution comprising a polyfunctional amine monomer and a non-polar solution comprising a polyfunctional acyl halide monomer to a surface of a porous support and interfacially polymerizing the monomers to form a thin film polyamide layer. The method is characterized by including a substituted benzamide monomer within the non-polar solution.

Composite polyamide membrane made using substituted benzamide monomer

A method for making a composite polyamide membrane comprising a porous support and a thin film polyamide layer, wherein the method includes the step of applying a polyfunctional amine monomer and polyfunctional acyl halide monomer to a surface of the porous support and interfacially polymerizing the monomers to form a thin film polyamide layer, wherein the step of applying the polyfunctional acyl halide monomer to the porous support includes the step of combining the polyfunctional acyl halide monomer with a non-polar solvent at a concentration of at least 0.18 weight percent to form a coating solution which is applied to the surface of the porous support, and wherein the interfacial polymerization is conducted in the presence of a tri-hydrocarbyl phosphate compound which is provided in a molar ratio of at least 0.5:1 with the polyfunctional acyl halide monomer. Many additional embodiments are described including membranes made from the subject method and applications for such membranes.

Composite polyamide membrane

A thin film composite polyamide membrane having a porous support and a thin film polyamide layer comprising a reaction product of m-phenylene diamine (mPD) and trimesoyl chloride (TMC), characterized by the thin film polyamide layer having a critical strain value of less than 10%. In another embodiment, the thin film polyamide layer has a modulus of greater than 0.75 (GPa). In yet another embodiment, the thin film polyamide layer has an equilibrium swelling value of at least 45%. In another embodiment, the thin film polyamide layer has a thickness of at least 230 nm.

Composite polyamide membrane with improved structure

A thin film composite polyamide membrane comprising a porous support and a thin film polyamide layer characterized by possessing: i) an azo (&#x2014;N&#x2550;N&#x2014;) content of from 0.30% to 0.80%, as measured by pyrolysis gas chromatography; and ii) a dissociated carboxylate content of at least 0.18 mol/kg as measured by RBS at pH 9.5.

Composite polyamide membrane having high acid content and low azo content

A thin film composite membrane including a porous support and a thin film polyamide layer characterized by having a dissociated carboxylate content of at least 0.45 moles/kg at pH 9.5 and a method for making a composite polyamide applying a polar solution comprising a polyfunctional amine monomer and a non-polar solution comprising a polyfunctional amine-reactive monomer to a surface of the porous support and interfacially polymerizing the monomers to form a thin film polyamide layer, wherein the method is characterized by the non-polar solution comprising at least 0.025 wt % of an acid compound including at least one carboxylic acid moiety and at least one amine-reactive moiety selected from acyl halide and anhydride.

Composite polyamide membrane with increased carboxylic acid functionality

A thin film composite polyamide membrane comprising a porous support and a thin film polyamide layer characterized by possessing an azo (&#x2014;N&#x2550;N&#x2014;) content of from 0.75% to 0.95%, as measured by pyrolysis gas chromatography.

Composite polyamide membrane having preferred azo content

A method for making a composite polyamide membrane comprising the steps of applying a polyfunctional amine monomer and polyfunctional acyl halide monomer to a surface of the porous support and interfacially polymerizing the monomers to form a thin film polyamide layer, wherein the method is includes at least one of the following steps: i) conducting the interfacial polymerization in the presence of a monomer comprising at least one phosphorous-containing functional group or salt thereof and an at least one amine-reactive functional group; and/or ii) applying such a monomer to the thin film polyamide layer.

Composite polyamide membrane derived from monomer including amine-reactive and phosphorous-containing functional groups

A method for making a composite polyamide membrane comprising the step of applying polyfunctional amine and acid halide monomers to a surface of a porous support and interfacially polymerizing the monomers to form a thin film polyamide layer. The method further includes the step of conducting the interfacial polymerization in the presence of: a carboxylic acid monomer comprising an aliphatic or aromatic moiety substituted with single carboxylic acid functional group and at least one acyl halide functional group, and a tri-hydrocarbyl compound.

Composite polyamide membrane derived from carboxylic acid containing acyl halide monomer

A method for making a composite polyamide membrane including the steps of applying a polyfunctional amine monomer and polyfunctional acyl halide monomer to a surface of the porous support and interfacially polymerizing the monomers to form a thin film polyamide layer, wherein the method is includes at least one of the following steps: i) conducting the interfacial polymerization in the presence of a subject monomer comprising at least one carboxylic acid group linked to an aromatic moiety and wherein the aromatic moiety is further substituted with at least one of an acyl halide or anhydride functional group and ii) applying the subject monomer to the thin film polyamide layer. The invention includes many additional embodiments.

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Shorewood, MN, United States of America

Steven Rosenberg