Dow Corning Corporation

Cambridge Enterprise Limited

Steven Robson

William Alden Crossland

Igor Chorvath

Russell Keith King

Lauren Marie Tonge

Martin Grasmann

Terry Clapp

Jonathan Hannington

Anthony Bernard Davey

Yeong Joo Lee

Huan Xu

Pierre Maurice Chevalier

Duan Li Ou

Michael Dipino

David Shawl

Anne Dupont

Mikhael Pivnenko

Jonathan Paul Hannington

Robert Andrew Drake

David W Lawson

Anthony Bemard Davey

Mike Pivnenko

Terry Victor Clapp

Martin Grassman

Jr Jon Vierling Degroot

The present, invention relates to liquid crystal compositions having a smectic A structure for use in an optical device in which the composition is sandwiched between a pair of electrodes (-). In essence the composition includes a siloxane oligomer (component (a)) which may be seen to construct a layered SmA system of particular spacing and 'strength'. Within this structure a low molar mass nematic mesogen (component (c)) is provided that may be considered to be that of a 'plasticiser' which moderates the layer &#x201c;strength&#x201d;, while simultaneously providing tuneability to the properties of the composition, e.g. its refractive index or dielectric anisotropy. The addition of a side chain liquid crystal polysiloxane (component (d)) allows such systems to be further moderated since they can be considered as binding together the la&#x3e;&#xbe;rs, both within a given layer and between layers. An ionic dopant (component (b)) is also included in the composition that migrates through the composition when low frequency electric fields are applied to the composition by the electrodes, thereby disrupting the order to the composition. Order in the composition can be restored by applying a higher frequency field that does not allow the dopant time to migrate significantly. Chromophores may also be included in the formulation.

Liquid crystal formulations and structures for smectic A optical devices

A silicone resin, curable to a resin of low coefficient of thermal expansion, high glass transition temperature and high modulus, has the empirical formula(RSiO)(RSiO)(RSiO)(SiO)wherein each R is a hydrocarbon or substituted hydrocarbon group or a hydrogen atom; and a=0.02 to 0.8; b=0 to 0.4; and c+d=0.2 to 0.98, where a+b+c+d=1.0, characterized in that at least 2 mole % of the siloxane units in the resin are of the formula R'SiO, RR&#x2032;SiOor R&#x2032;SiO, wherein each R&#x2032; is an alkenyl group.

Silicone resins

Growing community of inventors

Vale of Glamorgan, United Kingdom

Steven Robson