Amoco Corporation

Bp Amoco Corporation

Basf Se Corporation

Stephen Y Chen

John L Melquist

Weilong L Chiang

Boh C Tsai

George E Rotter

Cheryl A Pauer

Paul J Cahill

Lakshmi N Venkateshwaran

Compositions for scavenging oxygen are disclosed. These compositions comprise condensation copolymers comprising predominantly polyester segments and an oxygen scavenging amount of polyolefin oligomer segments. The polyester segments comprise segments derived from typical bottling and packaging polyesters such as PET and PEN. The copolymers are preferably formed by transesterification during reactive extrusion and typically comprise about 0.5 to about 12 wt % of polyolefin oligomer segments. The copolycondensates are capable of absorbing at least 0.4 cc of oxygen per gram of copolymer in the solid state at ambient temperatures and are typically used as layers in films, liners, cups, wraps, bottles, etc. Use of these oxygen scavenging compositions in bottles provides a clear and rigid bottle similar in appearance to unmodified polyester bottles. In a series of preferred embodiments, bottles fabricated with the oxygen scavenging copolycondensates of this invention are over 99.4 wt % polyester and suitable for recycle with other polyester bottles.

Oxygen scavenging condensation copolymers for bottles and packaging

Concentrates produced by melt processing a branching agent and a polyester carrier are disclosed. The concentrates are useful in melt processing polyesters. The concentrates contain sufficiently high concentrations of a branching agent to minimize the formation of crosslinked compounds in the concentrates. Process for using the concentrate also are disclosed.

Concentrate for use in the melt fabrication of polyester

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Wheaton, IL, United States of America

Stephen Y Chen