Alliedsignal Inc.

Allied Corporation

Uop Lcc

Stephen T Gonczy

Roger Y Leung

Gerald T Stranford

Ming S Shum

Joseph J Zupancic

Roy T Mitsche

John G Sikonia

Jon F Nebo

Randy J Lawson

George R Lester

Bruce I Rosen

Donald E Yuhas

Lawrence B Welsh

David P Groppi

Rober Y Leung

An improved fiber reinforced glass composite includes a carbon-coated refractory fiber in a matrix of a black glass ceramic having the empirical formula SiCxOy where x ranges from about 0.5 to about 2.0, preferably 0.9 to 1.6 and y ranges from about 0.5 to 3.0, preferably 0.7 to 1.8. Preferably the black glass ceramic is derived from cyclosiloxane monomers containing a vinyl group attached to silicon and/or a hydride-silicon group.

High flexural strength ceramic fiber reinforced silicon carboxide

An improved fiber reinforced glass composite includes refractory fiber in a matrix of a black glass ceramic having the empirical formula SiCxOy where x ranges from about 0.5 to about 2.0, preferably 0.9 to 1.6 and y ranges from about 0.5 to 3.0, preferably 0.7 to 1.8. Preferably the black glass ceramic is derived from cyclosiloxane monomers containing a vinyl group attached to silicon and/or a hydride-silicon group.

Method of preparing fiber reinforced glass composites

An improved fiber reinforced glass composite includes a carbon-coated refractory fiber in a matrix of a black glass ceramic having the empirical formula SiCxOy where x ranges from about 0.5 to about 2.0, preferably 0.9 to 1.6 and y ranges from about 0.5 to 3.0, preferably 0.7 to 1.8. Preferably the black glass ceramic is derived from cyclosiloxane monomers containing a vinyl group attached to silicon and/or a hydride-silicon group. Graceful failure can be obtained after exposure of the composites to temperatures up to 1300.degree. C.

Ceramic fiber reinforced silicon carboxide composite

Carbon-containing black glass compositions of matter having the empirical formula SiC.sub.x O.sub.y and derived from the polymer precursors having the residue ##STR1##

Carbon-containing black glass monoliths

An improved fiber reinforced glass composite includes a refractory fiber in a matrix of a nitrogen-containing black glass ceramic having the empirical formula SiN.sub.z C.sub.x O.sub.y where x ranges from greater than zero up to about 2.0, preferably 0.1 to 1.0, y ranges from 0.5 up to about 3.0, preferably 0.7 to 1.8, and z ranges from above zero up to about 1.5, preferably 0.2 to 1.0. Preferably the black glass ceramic is derived from cyclosiloxane monomers containing a vinyl group attached to silicon and/or a hydride-silicon group. The cyclosiloxane monomers are polymerized and then pyrolyzed in an ammonia-containing atmosphere to produce the nitrogen-containing black glass (silicon oxycarbonitride).

Silicon oxycarbonitride by pyrolysis of polycyclosiloxanes in ammonia

An improved fiber reinforced glass composite includes a boron nitride-coated refractory fiber in a matrix of a black glass ceramic having the empirical formula SiCxOy where x ranges from about 0.9 to 1.6 and y ranges from about 0.7 to 1.8. Preferably the black glass ceramic is derived from cyclosiloxane monomers containing a vinyl group attached to silicon and/or a hydride-silicon group. Graceful failure can be obtained after exposure of the composites to temperatures up to 600.degree.-700.degree. C. in air.

Reinforced silicon carboxide composite with boron nitride coated ceramic

A black glass having the empirical formula SiCxOy where x is greater than zero and up to about 2.0 and y is greater than zero and up to about 2.2 is produced from a cyclosiloxane polymer precursor by pyrolysis in the presence of oxygen by heating at a rate exceeding about 5.degree. C./min.

Fire resistant coating composition

A fiber reinforced glass composite capable of absorbing or transmitting microwave radiation includes refractory fiber in a matrix of a black glass ceramic having the empirical formula SiCxOy where x is greater than zero and up to about 2.0, and y is greater than zero and up to about 2.2. Preferably, the black glass ceramic is made by pyrolyzing precursor polymers derived from cyclosiloxane monomers containing a vinyl group attached to silicon and/or a hydride-silicon group in a controlled atmosphere, thereby adjusting the dielectric properties.

Ceramic Fiber reinforced silicon carboxide composite with adjustable

An improved protective layer for ceramic insulating bodies includes a composite having a refractory fiber in a matrix of a black glass ceramic having the empirical formula SiCxOy where x ranges from about 0.5 to about 2.0, preferably 0.9 to 1.6 and y ranges from about 0.5 to 3 0, preferably 0.7 to 1.8. The black glass ceramic is derived from cyclosiloxane monomers containing a vinyl group attached to silicon and/or a hydride-silicon group. The protective layer is formed by laying up plies of a prepreg on the insulating body following by pressing, curing and pyrolyzing said prepreg to form said protective layer.

Method for forming fiber-reinforced glass composite protective layers on

SiCxOy where x is greater than zero and up to about 2.0 and y is greater than zero and up to about 2.2 is produced from a cyclosiloxane polymer precursor by pyrolysis in the presence of oxygen by heating at a rate exceeding about 5.degree. C/min.

Black glass ceramic from rapid pyrolysis in oxygen-containing atmospheres

A protective layer for polymeric composite substrates comprises a fiber-reinforced glass composite having a refractory fiber in a matrix of a black glass ceramic having the empirical formula SiCxOy where x ranges from about 0.5 to about 2.0, preferably 0.9 to 1.6 and y ranges from about 0.5 to 3.0, preferably 0.7 to 1.8. The black glass ceramic is derived from cyclosiloxane monomers containing a vinyl group attached to silicon and/or a hydride-silicon group.

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Mt. Prospect, IL, United States of America

Stephen T Gonczy