The British Petroleum Company, P.l.c.

Bp Chemicals Limited

Bp Chemicals Limited & British Petroleum Co. P.l.c.

Stephen R Tennison

John J McCarroll

Alan I Foster

Peter G James

John Trevor Clark

Richard W Joyner

Anthony M Lear

Derrick John Watson

Richard Henry Weatherhead

Nicholas P Wilkinson

Paul W Satchell

A moulded ion exchange resin structure suitable for use in reactive distillation is prepared by compressing particles of an ion exchange resin precursor having chemically reactive functional groups on their surfaces, into a preform having a predetermined shape, subsequently chemically bonding the particles together by reaction of the functional groups for example by acid-catalysed condensation and converting the precursor to an ion exchange resin, for example by sulphonation.

Process for preparing a molded ion exchange resin structure

A process for separating components of a liquid mixture comprising a more adsorbable component (A), for example C.sub.1 to C.sub.6 carboxylic acids, and a less adsorbable component (B), for example water, wherein the relative adsorbity of component (A), component (B) and a desorbent liquid (D) with respect to an adsorbent in an adsorption column is in the order D&gt;A&gt;B, which process comprises the steps in sequence of: (a) passing the liquid mixture through an adsorption column containing the adsorbent and selectively adsorbing component (A) while discharging a stream enriched in component (B); (b) rinsing the adsorbent in the adsorption column after step (a) with desorbent liquid (D) which is immiscible with component (B) whereby component (A) is displaced from adsorbent by desorbent (D) and withdrawing from the adsorption column a first liquid phase stream comprising a mixture of component (A) and component (B) and withdrawing from the adsorption column a second liquid phase stream comprising a mixture of desorbent (D) and component (A); and (c) thermally displacing desorbent (D) from the adsorbent in the adsorption column after step (b). Preferably, the desorbent (D) forms an azeotrope with component (B). Suitable adsorbents are highly micro-porous activated carbons.

Process for separating components of a liquid mixture

A method of producing a form-stable sintered porous shaped phenolic resin article with continuous open pore structure and high macroporosity, in which a phenolic resin mixture is partially cured to a solid which is then comminuted to give a comminuted resin. The comminuted resin is admixed with water, hexamethylene tetramine and a cellulose ether, and the resulting comminuted resin mixture is formed into a shaped article which is allowed to come to equilibrium with air having a relative humidity of less than 100% at a temperature below 100.degree. C. The shaped article is then sintered to produce a form-stable sintered porous product.

Phenolic resin and carbon products

Process for the production of porous shaped articles

Catalysts as prepared by impregnating a carbon support with a halogen-containing compound of Ru, reducing the Ru to metal with hydrogen, and then depositing an alkali metal and a barium compound. The catalysts may be used for ammonia production.

Catalysts and their use in ammonia production

Methanol is converted to synthesis gas over a catalyst comprising Pd, an alkali metal, alkaline earth metal or a lanthanide on a carbon having defined surface area characteristics.

Methanol conversion process

Methanol is produced by passing CO and H.sub.2 over a supported Pd catalyst containing an alkali metal alkaline earth metal, or lanthanide promoter and supported on a carbon support with defined surface area characteristics.

Catalytic process for the production of methanol

A process for the production of ammonia comprises passing hydrogen and nitrogen over a catalyst comprising a transition metal, e.g. ruthenium, and a modifying metal, e.g. an alkali metal, supported on a graphite-containing carbon support having specified surface area properties. At start-up the nitrogen is supplied in stoichiometric excess and thereafter in stoichiometric proportions.

Process for the production of ammonia

Catalyst for the synthesis of ammonia from hydrogen comprises (1) as support on graphite containing carbon having (a) a basal plane surface area of at least 100 m 2/G (b) a ratio of BET surface area to basal plane surface area of not more than 5:1 and (c) a ratio of basal plane surface area to edge surface area of at least 5:1 and (ii) as active component (a) 0.1 to 50% by weight of a transition metal and (b) 0.1 to 4 times by weight of (a) of a modifying metal or ion selected from the alkali or alkaline earth metals or ions. The modifying metal or ion is actively associated with the transition metal rather than the support.

Process for producing a catalyst comprising a graphite containing

A modified alumina catalyst support is prepared by mixing a Solution A containing alkali, a Solution B containing a salt of a modifying metal of Group 111A, other than aluminium, or V111 other than a platinum group metal, of the Periodic Table, and a Solution C containing a aluminium salt, to form a precipitate, ageing the precipitate, separating the precipitate from the supernatant liquor and calcining the precipitate. A platinum group metal may be added to the support and the resulting catalyst is suitable for catalyzing hydrocarbon conversation processes, particularly catalytic reforming.

Method for preparing a modified alumina catalyst support and a

Process for the synthesis of ammonia using catalysts supported on

Hydrogen transfer catalyst comprises (a) as support a graphite containing carbon having (1) a basal plane surface area of at least 100 m.sup.2 /g, (2) a ratio of BET surface area to basal plane surface area of not more than 5:1 and (3) a ratio of basal plane surface area to edge surface area of at least 5:1 and (b) as active component, 0.01 to 10% by weight, of the total weight of catalyst of a platinum group metal disposed thereon. The catalyst is particularly suitable for reforming.

Platinum group metal catalyst

Graphite-containing carbon is prepared by subjecting carbon to the steps of (1) an initial heat treatment in an inert atmosphere, (2) an oxidation stage and (3) a further heat treatment in an inert atmosphere.

Growing community of inventors

Weybridge, United Kingdom

Stephen R Tennison