Kimberly-clark Worldwide, Inc.

Wisconsin Alumni Research Foundation

Stephen Michael Lindsay

Michael Andrew Zawadzki

Donald Eugene Waldroup

Cathleen Mae Uttecht

Mike Thomas Goulet

Kenneth John Zwick

Jian Qin

Christopher Lee Satori

Thomas Gerard Shannon

Deborah Joy Calewarts

Brent Merrik Thompson

Richard Louis Underhill

Charles Wilson Colman

Francis P Abuto

Jenny L Day

Peiguang Zhou

Kaiyuan Yang

Bo Shi

Wing-Chak Ng

Carl Gerard Rippl

Joel Brostin

Jay W Warrick

Richmond R Cohen

Kenneth J Zwick

John Yin

James Benjamin Harvey

Yiming Weng

Keyur Desai

The present invention provides a wet-laid tissue product comprising regenerated cellulose fibers that can provide 25% or less of the total weight of the wet-laid tissue product. The regenerated cellulose fibers can have a denier of less than 0.9 and a fiber length of less than 6.0 mm. The wet-laid tissue product can provide improvements in softness at a given strength.

Soft and strong tissue product including regenerated cellulose fibers

A method for producing a foam-formed multilayered substrate that includes producing an aqueous-based foam including at least 3% by weight non-straight synthetic binder fibers, wherein the non-straight synthetic binder fibers have an average length greater than 2 mm; forming together a wet sheet layer from the aqueous-based foam and a cellulosic fiber layer, wherein the cellulosic fiber layer includes at least 60 percent by weight cellulosic fibers; and drying the combined layers to obtain the foam-formed multilayer substrate. A multilayered substrate includes a first layer including at least 60 percent by weight non-straight synthetic binder fibers having an average length greater than 2 mm; and a second layer including at least 60 percent by weight cellulosic fiber, wherein the first layer is in a facing relationship with the second layer, and wherein the multilayered substrate has a wet/dry tensile ratio of at least 60%.

Fibrous sheet with improved properties

A nonwoven substrate includes individual fibers each having a fiber surface and a fiber diameter, wherein a portion of the individual fibers include a micro-embossed pattern, and wherein the micro-embossed pattern includes pattern elements equal to or smaller than the fiber diameter. The pattern elements can be recessed into and/or extend out of the fiber surface, and the nonwoven substrate can include polypropylene or polyethylene. A disposable absorbent article includes a nonwoven substrate having individual fibers each having a fiber surface and a fiber diameter, wherein a portion of the individual fibers include a micro-embossed pattern, and wherein the micro-embossed pattern includes pattern elements equal to or smaller than the fiber diameter.

Micro- and nano-structured fiber-based substrates

Disclosed are processes for manufacturing cross-linked cellulosic fibers and tissue products comprising cross-linked cellulosic fibers, manufactured by reacting an oxidized polyol, in particular, an oxidized sugar having at least two aldehyde groups with a plurality of cellulosic fibers to yield treated fibers and heating the treated fibers at a temperature greater than about 140° C. to cure the treated fibers. In particular, said sugar is sucrose and the oxidising agent comprises hydrogen peroxide. The instant cross-linked fibers are manufactured without well-known cross-linking agents such as formaldehyde or polycarboxylic acids, and have good brightness and color and resist yellowing. Furthermore, the cross-linked cellulosic fibers are generally free from off odors and the instant cross-linked cellulosic fibers have enhanced properties, such as improved wet bulk, compared to uncross-linked fibers.

Cross-linked cellulosic fibers

The present disclosure relates to tissue products comprising crosslinked fibers. The tissue products generally have good formation, such as a Formation Index greater than about 20, strength, such as geometric mean tensile strengths greater than about 700 g/3″ and high bulk, such as sheet bulks greater than about 10 cc/g. Unlike many prior art crosslinked fibers, the crosslinked softwood pulps of the present invention, which are preferably prepared using a glyoxal based crosslinking reagent, are readily dispersible in water and have relatively low degrees of kink and curl. As such, the fibers are well suited for forming wet-laid tissue products and more particularly wet-laid tissue products having improved physical properties, such as improved bulk.

Tissue products comprising crosslinked fibers

The present invention provides mufti-layered tissue webs, and tissue product comprising the same, comprising long, high-coarseness wood pulp fibers selectively deposited in one or more outer layers of the multi-layered web. Surprisingly disposing long, high-coarseness wood pulp fibers in one or more outer layers, even in relatively modest amounts, may improve certain product properties, such as durability, without negatively affecting softness. In certain instances, both the softness and durability may be improved by selectively incorporating long, high-coarseness wood pulp fibers in one or more of the outer layers.

Layered tissue comprising long, high-coarseness wood pulp fibers

A substrate has an elastomeric film having surfaces and a nonwoven web having fibers, wherein a plurality of fibers is partially embedded in one surface of the film. In addition, a substrate has an elastomeric film and a nonwoven web having fibers, wherein a plurality of fibers is partially embedded in one surface of the film, and wherein the substrate is essentially free of adhesives and film-based microfibers. A method for making a film/nonwoven composite includes providing an elastomeric film traveling in a machine direction; providing a nonwoven web traveling in the machine direction in face-to-face contact with the film, wherein the nonwoven web includes fibers; and impinging the elastomeric film with hydro jets such that at least some of the fibers become embedded in the film.

Hydroembedded film-based composites

The present invention provides multi-layered tissue webs, and tissue product comprising the same, comprising long, high-coarseness wood pulp fibers selectively deposited in one or more outer layers of the multi-layered web. Surprisingly disposing long, high-coarseness wood pulp fibers in one or more outer layers, even in relatively modest amounts, may improve certain product properties, such as durability, without negatively affecting softness. In certain instances, both the softness and durability may be improved by selectively incorporating long, high-coarseness wood pulp fibers in one or more of the outer layers.

The present invention provides tissue webs and products that are manufactured by non-compressive dewatering and/or drying methods, such as through-air drying, where the webs and products comprise cross-linked fiber. The non-compressively dewatered tissue webs and products have improved sheet bulk and z-direction properties. For example, in one embodiment, the invention provides through-air dried tissue products having good sheet bulk and resiliency, such as a sheet bulk greater than about 15 cc/g and Compression Energy (E) greater than about 1.30 N/m. Surprisingly the foregoing products have sufficient strength to withstand use, such as a GMT greater than about 600 g/3&#x2033;, but are not overly stiff, generally having a Stiffness Index less than about 12.

Resilient high bulk tissue products

The disclosure provides tissue webs and products comprising cross-linked cellulosic fibers. In certain embodiments cross-linked cellulosic fibers are selectively disposed in one or more layers of a multi-layered tissue, wherein the tissue layer comprising cross-linked fibers is adjacent to a layer which is substantially free from cross-linked fiber. The cross-linked fibers may include hardwood kraft fibers reacted with a cross-linking agent selected from the group consisting of DMDHU, DMDHEU, DMU, DHEU, DMEU, and DMeDHEU. Tissue products and webs produced in this manner generally have improved sheet bulk, without losses in strength, compared to similar tissue products produced without cross-linked cellulosic fibers. As such the tissue products of the present invention generally have a basis weight from about 10 to about 50 gsm, a sheet bulk greater from about 8.0 to about 12.0 cc/g and geometric mean tensile from about 730 to about 1,500 g/3&#x2033;.

Soft, strong and bulky tissue

The present invention provides tissue webs and products that are manufactured by non-compressive dewatering and/or drying methods, such as through-air drying, where the webs and products comprise cross-linked fiber. The non-compressively dewatered tissue webs and products have improved sheet bulk and z-direction properties. For example, in one embodiment, the invention provides through-air dried tissue products having good sheet bulk and resiliency, such as a sheet bulk greater than about 12 cc/g and Compression Energy (E) greater than about 1.30 N/m. Surprisingly the foregoing products have sufficient strength to withstand use, such as a GMT greater than about 1,200 g/3&#x2033;, but are not overly stiff, generally having a Stiffness Index less than about 10.0.

Resilient high bulk towels

The present application relates to a cross-linked fiber and more specifically to fibers that have been subjected to cold caustic extraction (at less than 60&#xb0; C.) to reduce the hemicellulose content of the fibers by at least 50% and then cross-linked with a cross-linking agent that is curable at a modest temperature, such as less than 160&#xb0; C. The treated cross-linked fibers preferably have a hemicellulose content that is less than 5% by weight of the fiber. Preferable cross-linking agents are polyamide-epichlorohydrin (PAE) resins, polyamide-polyamine-epichlorohydrin (PPE) resins, and polydiallylamine-epichlorohydrin resins. The cross-linked fibers are readily dispersible in water even without fiberization and generally form webs and products having relatively few knits or knots. As such, the cross-linked fibers of the present invention are well suited for use in the manufacture of tissue webs and products, particularly wet-laid tissue webs and products.

High bulk tissue comprising cross-linked fibers

The present invention provides a modified cellulosic fiber having reduced hydrogen bonding capabilities. The modified fiber formed in accordance with the present invention may be useful in the production of tissue products having improved bulk and softness. More importantly, the modified fiber is adaptable to current tissue making processes and may be incorporated into a tissue product to improve bulk and softness without an unsatisfactory reduction in tensile.

Growing community of inventors

Appleton, WI, United States of America

Stephen Michael Lindsay