E.i. Dupont De Nemours and Company

Stephen Mazur

T Joseph Dennes

Charles E Jackson

Pankaj Arora

Lewis E Manring

Glen Edward Simmonds

Eric P Holowka

Stephane Francois Bazzana

Gary W Foggin

Lakshmi Krishnamurthy

Gerald Donald Andrews

Steven C Freilich

Henry C Hadley, Jr

Joseph T Dennes

The present invention is directed to the preparation and use of aromatic polyimide nanowebs with amide-modified surfaces. Uses include as a filtration medium, and as a separator in batteries, particularly lithium-ion batteries. The invention is also directed to a method comprising the aromatic polyimide nanoweb with amide-modified surface. The invention is further directed to a multi-layer article comprising the aromatic polyimide nanoweb with amide-modified surface, and to an electrochemical cell comprising the multi-layer article.

Filtration method using polyimide nanoweb with amidized surface and apparatus therefor

This invention provides a multi-layer article comprising a first electrode material, a second electrode material, and a porous separator disposed between and in contact with the first and the second electrode materials, wherein the porous separator comprises a nanoweb consisting essentially of a plurality of nanofibers of a fully aromatic polyimide. Also provided is a method for preparing the multi-layer article, and an electrochemical cell employing the same. A multi-layer article comprising a polyimide nanoweb with enhanced properties is also provided.

Multi-layer article comprising polyimide nanoweb

A method for reducing the self discharge rate and the variability in the self discharge rate of an electrochemical cell wherein a porous separator is inserted between a cathode and an anode of the cell and the porous separator contains a nanoweb that comprises a plurality of nanofibers that may contain a fully aromatic polyimide and the fully aromatic polyimide has a degree of imidization of greater than 0.51 where degree of imidization is the ratio of the height of the imide C&#x2014;N absorbance at 1375 cmto the C&#x2014;H absorbance at 1500 cm.

Method for reducing self discharge in an electrochemical cell

The present invention is directed to the preparation and use of aromatic polyimide nanowebs with amide-modified surfaces. Uses include as a filtration medium, and as a separator in batteries, particularly lithium-ion batteries. The invention is also directed to a filtration apparatus comprising the aromatic polyimide nanoweb with amide-modified surface. The invention is further directed to a multi-layer article comprising the aromatic polyimide nanoweb with amide-modified surface, and to an electrochemical cell comprising the multi-layer article.

Polyimide nanoweb with amidized surface and method for preparing

Methods for oxidizing organic compounds coated or adsorbed on a topographically patterned solid surface are provided. The methods can be used to selectively remove the organic compounds from the non-recessed areas.

Topographically selective oxidation

This invention provides membrane-mediated electropolishing (MMEP) processes for polishing and/or planarizing metal work pieces using topographically patterned membranes. The processes can be used for both pure metals and alloys, and provide advantages over conventional electropolishing processes and known MMEP processes using smooth membranes. This invention also provides a cathode half-cell and an apparatus useful in membrane-mediated electropolishing processes. The invention also provides processes for electroengraving and electromachining topographic patterns, holes and/or grooves into the surface of a metal work piece.

Membrane-mediated electropolishing with topographically patterned membranes

This invention provides a membrane-mediated electropolishing apparatus for polishing and/or planarizing metal work-pieces. The work-piece is wetted with a low-conductivity fluid. The wetted work-piece is contacted with a first side of a charge-selective ion-conducting membrane, wherein the second side contacts a conductive electrolyte solution in electrical contact with a electrode. Current flow between the electrode and the work-piece electropolishes metal from the work-piece. This invention also provides a half-cell adapted for use in membrane-mediated electropolishing having a fully or partially enclosed volume, a conductive electrolyte which partially or essentially fills the enclosed volume, an electrode which is in contact with the electrolyte, and a charge-selective ion-conducting membrane which seals one surface of the enclosed volume, cavity or vessel in such a way that the internal surface of said membrane contacts the electrolyte solution or gel and the external surface is accessible to contact the work-piece.

Apparatus adapted for membrane-mediated electropolishing

This invention provides a membrane-mediated electropolishing process for polishing and/or planarizing metal work pieces. The work piece is wetted with a low-conductivity fluid. The wetted work piece is contacted with a first side of a charge-selective ion-conducting membrane, wherein the second side contacts a conductive electrolyte solution in electrical contact with a cathode. Current flow between the cathode and the work piece electropolishes metal from the work piece. This process can be used for both pure metals and alloys, and provides several significant advantages over conventional electropolishing processes. This invention also provides an apparatus useful in the membrane-mediated electropolishing process.

Membrane-mediated electropolishing

A thermoplastic solid surface material derived from a thermoplastic latex co-dispersion and downstream intermediates, including (a) aqueous thixotropic slips; (b) polymeric composite flakes; (c) composite powders; (d) composite pastes; and (e) preformed composite pieces

Solid surface materials derived from aqueous latex dispersions of thermoplastic polymers

Aqueous blends of colloidally dispersed polymers

This invention relates to counter-current diffusion methods for depositing metals as interlayers within films.

Metal interlayers in films by counter-current diffusion

Polyimide-electron donor charge transfer complexes, supported or unsupported, as photoconductive elements characterized by photoconductivities in excess of the sum of the individual photoconductivities of the polyimide and electron donor components.

Photoconductive polyimide-electron donor charge transfer complexes

A photosensitive cathode is used to vary in three dimensions, the position, shape and density of a metallic interlayer formed in a preformed polymer film using an electrochemical deposition process.

Growing community of inventors

Wilmington, DE, United States of America

Stephen Mazur