E.i. Dupont De Nemours and Company

Stephen Claude De La Veaux

Charles David Musick

Narayanan Sankara Subramanian

Peter Jernakoff

Philipp Martin Niedenzu

Kevin J Leary

Eric Lee Brantley

Alan Roger Eaton

John Nicholas Birmingham

Yunghsing Samson Hsu

This invention relates to a supersonic center-feed nozzle system within the feed-inlet tube of a fluid-energy mill used for grinding particulate material such as titanium dioxide. Particularly, in the feed-inlet tube of the present invention, particulate material is introduced into the supersonic feed jet of primary grinding fluid in almost a perpendicular fashion, with the supersonic nozzle installed in the center of the particulate material core, imparting momentum to the particulate material. The momentum entrains the particulate into the main grinding chamber of the feed-inlet tube. In the main grinding chamber of the feed-inlet tube, a secondary stream of grinding fluid, introduced annularly, constricts the primary jet's divergent flow, enabling a higher turbulent mixing of the grinding fluids and the particulate material.

Center-feed nozzle in a contained cylindrical feed-inlet tube for improved fluid-energy mill grinding efficiency

One aspect of the invention is to provide a composition comprising a titanium dioxide particle having on the surface of said particle a substantially encapsulating layer comprising a pyrogenically-deposited metal oxide; said substantially encapsulating layer having on its surface at least one organic surface treatment material selected from an organo-silane, an organo-siloxane, a fluoro-silane, an organo-phosphonate, an organo-acid phosphate, an organo-pyrophosphate, an organo-polyphosphate, an organo-metaphosphate, an organo-phosphinate, an organo-sulfonic compound, a hydrocarbon-based carboxylic acid, an associated ester of a hydrocarbon-based carboxylic acid, a derivative of a hydrocarbon-based carboxylic acid, a hydrocarbon-based amide, a low molecular weight hydrocarbon wax, a low molecular weight polyolefin, a co-polymer of a low molecular weight polyolefin, a hydrocarbon-based polyol, a derivative of a hydrocarbon-based polyol, an alkanolamine, a derivative of an alkanolamine, an organic dispersing agent, or a mixture thereof. Another aspect of the invention is to provide processes for producing said composition.

Preparation of organic additive-treated, pyrogenic silica-encapsulated titanium dioxide particles

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Wilmington, DE, United States of America

Stephen Claude De La Veaux