Union Carbide Corporation

Stephen C Winans

Robert W Beisner

Paul D Sherman, Jr

Dennis G Morrell

In a rhodium-catalyzed hydroformylation process employing olefin reactants having from 3 to 20 carbon atoms to produce products rich in normal aldehydes, the efficiency of the catalyst in producing such products is substantially uneffected and propionaldehyde is also produced by employing ethylene as a coreactant along with the olefin.

Hydroformylation of ethylene with higher olefins

This invention relates to the continuous production of alkane polyols by the reaction of hydrogen and CO in a homogeneous liquid phase mixture containing a rhodium carbonyl complex catalyst, the mole ratio of H.sub.2 /CO in the reactant gas being above about 0.1, wherein the improvement comprises periodically lowering the H.sub.2 /CO mole ratio in the reactant gas to about 0.1 or less and thereafter increasing the H.sub.2 /CO mole ratio to about its former value.

Rhodium catalyst regeneration by carbon monoxide treatment

This invention relates to the continuous production of alkane polyols by the reaction of hydrogen and oxides of carbon in a homogeneous liquid phase mixture containing a rhodium carbonyl complex catalyst wherein the improvement comprises periodically lowering the temperature of the liquid phase mixture and thereafter raising it to about its former value.

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South Charleston, WV, United States of America

Stephen C Winans