Schlumberger Technology Corporation

Exxonmobil Research and Engineering Company

Stephen C Leviness

Andrzej Mariusz Malek

Franklin D Lomax

David O Marler

Maxim Lyubovsky

Horacio Trevino

Weldon K Bell

Andrew L Kurkjian

John Allan Nighswander

Keith James Massie

Christopher P Heinrichs

Moinuddin Khan

Rama A Zakaria

Richard Shannon Todd

Processes for activating and/or regenerating Fischer-Tropsch and/or oxygenate synthesis catalysts include the transportation of a modular, portable catalyst activation and/or regeneration unit to Fischer-Tropsch and/or oxygenate production units. An alternative process for activating and/or regenerating Fischer-Tropsch and/or oxygenate synthesis catalysts includes activating and/or regenerating the catalyst in a production unit at a catalyst treatment facility. An alternative process for activating and/or regenerating Fischer-Tropsch and/or oxygenate synthesis catalysts includes activating and/or regenerating the catalyst in a synthesis reactor at a catalyst treatment facility.

Fischer-trospch and oxygenate synthesis catalyst activation/regeneration in a micro scale process

A production process includes combining a first feed stream and a second feed stream to produce, in a pre-reforming reactor, a first product stream comprising CHand HO; wherein the first feed stream contains a mixture of Hand at least one selected from the group consisting of hydrocarbons having two or more carbon atoms and alcohols having two or more carbon atoms, and the mixture has a hydrogen stoichiometric ratio (&#x3bb;) of at least 0.1, and the second feed stream contains steam; feeding the first product stream into a reforming reactor; and reacting the first product stream in the reforming reactor to produce a second product stream containing CO and H; and a catalyst for use in the process. Conversion of the second product stream to synthetic crude, methanol, higher alcohols, and/or DME may also be undertaken. Yet further conversion of a synthetic crude to lubricants, diesel and the like, and/or the alcohols/DME to gasoline, olefins, and/or other oxygenates may also be included.

Hydrogenating pre-reformer in synthesis gas production processes

A method of tracking production from an NG source that includes the steps of providing one or more micro-scale GTL units, feeding NG from the source to the micro-scale GTL units, operating the micro-scale GTL units and adjusting the number of micro-scale GTL units employed to track or match the production from the source is provided. In some aspects of the invention, the micro-scale GTL unit includes both syngas manufacture and liquid product synthesis. The liquid product synthesis step may produce methanol, mixed higher carbon number alcohols, dimethyl ether, Fischer-Tropsch liquids, and/or any combination of these products.

Tracking feedstock production with micro scale gas-to-liquid units

A mobile system for providing start-up electrical power to a micro scale liquid hydrocarbon and/or oxygenate synthesis plant is provided including a portable gas or liquid fueled electrical generator, a steam turbine, a plant generator mechanically coupled to the steam turbine, a plant power load; and means for synchronizing electrical power generated by the portable electrical generator with electrical power generated by the plant generator is provided. Also provided is a process for synchronizing electrical power generated by the portable electrical generator with electrical power generated by the plant generator.

Micro scale fischer-tropsch and oxygenate synthesis process startup unit

A process for enhancing the activity of a catalyst metal particulate for hydrogenation reactions comprising calcining the particulate in an oxidant-containing atmosphere to partially oxidize it thereby forming a porous layer of oxides thereon, treating with an solution capable of oxidizing the calcined metal particulate and comprising a compound of a hydrogenation catalyst metal to where said metal particulate has absorbed a volume of solution equal to at least about 10% of its calculated pore volume and activating it by treatment with a hydrogen-containing gas at elevated temperatures thereby forming a dispersed active metal catalyst. Preferably, the treated particulate is calcined a second time under the same conditions as the first before final activation with a hydrogen-containing gas. The metal particulate is preferably sized after each calcination and any agglomerates larger than 250 microns are comminuted to a desired size.

Fischer-Tropsch catalyst production

Dispersed Active Metal catalyst for hydrogenation reactions is produced by treating a substantially catalytically inactive metal particulate with a solution capable of oxidizing the metal particulate and comprising of at least one compound of a hydrogenation catalyst metal thereby forming a layer of at least one of hydroxides and oxides thereon. The metal particulate is activated by treatment with a hydrogen-containing gas at elevated temperatures to form a porous layer of Dispersed Active Metal catalyst. Preferably, the treated metal particulate is dried prior to activation, and also preferably calcined in an oxidant-containing atmosphere prior to activation. The treatment solution may advantageously contain a compound of at least one promoter metal for the added catalyst metal. The porosity of the layer provides enhanced catalyst activity as well as improved methane selectivity in the Fischer-Tropsch process.

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Tulsa, OK, United States of America

Stephen C Leviness