General Electric Company

Stephen B Hamilton

Melvin D Beers

Warren R Lampe

Abe Berger

Terry G Selin

Novel organofunctional (ketoximino) silanes, such as acetoxyethyl tris(methylethylketoximine)silane, are provided which are useful as crosslinking agents chain-extending agents and chain-terminating agents in room temperature vulcanizable silicone elastomers. The room temperature vulcanizable compositions containing these novel organofunctional tris(ketoximino) silanes, which are stable free flowing fluids in the absence of moisture but cure to the rubbery, solid elastic state upon exposure to moisture, the method of making the same and the cured products thereof are also provided. The present room temperature vulcanizable compositions are particularly well suited for applications in conjunction with concrete (cement) substrates.

Novel organofunctional (ketoximino) silanes and room temperature,

There is provided by the present invention a twopart room temperature vulcanizable silicon rubber composition which is exceptionally stable to reversion and specifically to reversion of the cured composition caused by water comprising a silanol-stopped diorganopolysiloxane, filler, an alkyl silicate and a catalyst where the catalyst is a reaction product of an organic tin oxide compound with the hydrocarbon ester of an oxygen-containing acid having at least one oxygen atom in the acid radical attached to a replaceable acid hydrogen atom. The hydrocarbon ester can be either an inorganic acid or a carboxylic acid. The preferred catalyst in the present invention is the reaction product of dibutyl tin oxide and a phthalate ester.

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Schenectady, NY, United States of America

Stephen B Hamilton