Eastman-kodak Company

Stephen A Hershey

Robert E Dickerson

James C Bolthouse

Anthony Adin

J Ramon Vargas

Paul A Burns

Richard L Parton

Thomas L Penner

Franklin C Brayer

Patrick M Jeffries

Richard E Beal

Myra T Olm

George J Burgmaier

John D Mee

Elizabeth K Priebe

Charles H Weidner

Steven P Szatynski

Anthony D Gingello

David R Foster

Richard F Davis

Dorothy T Java

A radiographic material containing tabular silver halide grains also includes an amido compound as an antifoggant precursor that can slowly release an antifoggant over time. These compounds are present in reactive association with the silver halide in tabular silver halide emulsion layers, and are present in an amount of at least 0.5 mmol/mol of silver. The radiographic materials are protected from fog during storage particularly in high temperature environments.

Radiographic materials with antifoggant precursors

This invention relates to a silver halide photographic material comprising at least one silver halide emulsion comprising silver halide grains having associated therewith:

Silver halide material comprising low stain antenna dyes

A radiographic silver halide film useful for mammography comprises a support having a cubic grain silver halide emulsion on one side. The cubic grains are spectrally sensitized with a combination of first and second spectral sensitizing dyes that provides a combined maximum J-aggregate absorption of from about 540 to about 560 nm. The first spectral sensitizing dye is an anionic benzimidazole-benzoxazole carbocyanine and the second spectral sensitizing dye is an anionic oxycarbocyanine. The first and second spectral sensitizing dyes are present in a molar ratio of from about 0.25:1 to about 4:1.

Radiographic silver halide film for mammography with reduced dye stain

High bromide cubic grain emulsions

A blue-sensitive radiographic silver halide film comprises a silver halide emulsion layer comprising predominantly tabular silver halide grains that have an aspect ratio of at least 15, a grain thickness of at least 0.1 &mgr;m, and comprise at least 90 mol % bromide and up to 4 mol % iodide, based on total silver halide. Substantially all of the iodide is present in an internal localized portion of the tabular silver halide grains that excludes the surface of the grains. The tabular silver halide grains are dispersed in a hydrophilic polymeric vehicle mixture comprising at least 0.5% of oxidized gelatin, based on the total dry weight of the polymeric vehicle mixture in the emulsion layer. The tabular silver halide grains are spectrally sensitized using a combination of spectral sensitizing dyes to provide increased speed and reduced dye stain. The dyes have maximum J-aggregate absorptions on the tabular silver halide grains of from about 380 to about 500 nm, wherein the maximum J-aggregate absorption of one spectral sensitizing dye is from about 20 to about 50 nm lower in wavelength than the maximum J-aggregate absorption of the second spectral sensitizing dye.

Blue spectrally sensitized film for radiography, imaging assembly and method

Photographic material having enhanced light absorption and low dye stain

A photothermographic element comprises: (a) a support bearing on one surface thereof (b) a photosensitive emulsion layer (i) a binder; (ii) a light-insensitive organic silver salt, (iii) a reducing agent, and (iv) a photosensitive silver halide emulsion; (c) an antihalation dye incorporated in the emulsion layer, in a polymer layer under the photosensitive layer, in the support, or in a backside polymer layer; and (d) one or more tinting dyes such that the final color space of the film lies within the range defined by 220&deg;<h,<260&deg;, where h,is the psychometric hue angle, h,&equals;arctan(b*/a*), as defined in the CIELAB color system.

Photothermographic element having desired color

Portal localization radiographic elements and a process of confirming the targeting of a beam of X-radiation of from 4 to 25 MVp using the portal radiographic elements are disclosed. The X-radiation is directed at a subject containing features that are identifiable by differing levels of X-radiation absorption. After a first X-radiation exposure a shield containing a portal is placed between the subject and the source of X-radiation. X-radiation is directed at the subject through the portal. In each instance the X-radiation leaving the subject impinges on a metal screen, causing it to emit electrons, and the electrons impinge upon a fluorescent screen, causing it to emit light, creating during the first and second exposures first and second superimposed latent images in the radiographic element. A processor is employed to convert the latent images to viewable silver images from which intended targeting of the X-radiation passing through the portal in relation to the identifiable features of the subject is realized. The processor relies on attenuation of an infrared beam of a wavelength from 850 to 1100 nm by the radiographic element for activation, and at least one of the hydrophilic colloid layers of the radiographic element contains particles having an index of refraction in the wavelength range of from 850 to 1100 nm that differs from that of the hydrophilic colloid by at least 0.2 to create a specular density capable of attenuating the infrared beam and activating the processor.

Portal localization radiographic element and method of imaging

Portal radiographic elements and a process of confirming the targeting of a beam of X-radiation of from 4 to 25 MVp using the portal radiographic elements are disclosed. The X-radiation is directed at a shield containing a port to create a beam. The beam is directed at a selected anatomical feature of a patient over a period of at least 30 seconds. The portion of the beam that passes through the patient impinges on a metal screen, causing it to emit electrons, and the electrons impinge upon a fluorescent screen, causing it to emit light that exposes a portal verification radiographic element to create a latent image in light-sensitized silver halide grains. A processor is employed to convert the latent image to a viewable silver image from which intended targeting of the X-radiation beam can be verified. The processor relies on attenuation of an infrared beam of a wavelength from 850 to 1100 nm by the radiographic element for activation, and at least one of the hydrophilic colloid layers of the radiographic element contains desensitized silver halide grains to increase the specular density of the radiographic element in the wavelength range of infrared sensors that control the processor.

Portal verification radiographic element and method of imaging

The problem of sensing the presence of radiographic elements using infrared sensors that occurs when a radiographic element contains one or more very thin tabular grain emulsions a total silver coating coverage of less than 30 mg/dm.sup.2 is addressed by placing particles in one or more non-emulsion hydrophilic colloid layers. The particles are removable during rapid access processing, have a mean equivalent circular diameter of from 0.3 to 1.1 .mu.m, and have an index of refraction at the wavelength of the infrared radiation that differs from the index of refraction of the hydrophilic colloid by at least 0.2.

Infrared sensor detectable radiographic elements containing very thin

An element capable of forming a silver image is disclosed containing insufficient radiation-sensitive silver halide grains to render the element detectable by an infrared sensor. The element has been modified to increase infrared specular density by the inclusion of, in a hydrophilic colloid dispersing medium, particles (a) being removable from the element during a rapid access processing cycle, (b) having a mean size of from 0.3 to 1.1 .mu.m and at least 0.1 .mu.m larger than the mean grain size of the radiation-sensitive grains, and (c) having an index of refraction at the wavelength of the infrared radiation that differs from the index of refraction of the hydrophilic colloid by at least 0.2.

Infrared sensor detectable imaging elements

Radiographic films can be processed using conventional developing agents, either in the films or in solution. The films also include from about 0.02 to about 1 mg/dm.sup.2 of thialkylene bis(ammonium salt). The solution used for development is replenished at a low rate with a chemical base as the sole developer replenishing agent. The chemical base maintains developer composition pH at from about 9 to about 11 and enables processing of films without the use of conventional developer replenishing solutions or replenishment rates.

Processing radiographic films with low developer replenishment using an

A radiation-sensitive film for reproducing digitally stored medical diagnostic images through a series of laterally offset exposures by a controlled radiation source followed byprocessing in 90 seconds or less including development, fixing and drying is disclosed. The film exhibits an average contrast in the range of from 1.5 to 2.0, measured over a density above fog of from 0.25 to 2.0. An emulsion is provided in which silver bromochloride grains provided (a) containing at least 10 mole percent bromide, based on silver, (b) having a mean equivalent circular diameter of less than 0.40 .mu.m, (c) exhibiting an average aspect ratio of less than 1.3, and (d) coated at a silver coverage of less than 40 mg/dm.sup.2. Adsorbed to the surfaces of the silver bromochloride grains is at least one spectral sensitizing dye having an absorption half peak bandwidth in the spectral region of exposure by the controlled exposure source. The film also contains an infrared opacifying dye capable of reducing specular transmission through the film before, during and after processing to less than 50 percent, measured at a wavelength within the spectral region of from 850 to 1100 nm.

Films for reproducing digitally stored medical diagnostic images

Monocyclic and polycyclic azoles having the following formula modify the tone of a silver image formed from a fine grain radiation sensitive silver chlorobromide emulsion layer in which the silver chlorobromide grains have a mean equivalent circular diameter of less than 0.3 .mu.m. The azoles have the formula: ##STR1## wherein Z is --N.dbd. or --C(R.sup.5).dbd. where R.sup.5 is hydrogen, --NH.sub.2, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms;

Tone control of photographic silver images

Monocyclic and polycyclic azoles having the following formula enhance the covering power of a developed silver image formed from a radiographic element comprising a radiation sensitive tabular grain silver bromide, silver bromochloride or silver bromoiodide emulsion layer containing grains having a mean equivalent circular diameter of at least 0.3 .mu.m and a grain population wherein at least 50 percent of the total grain population projected area is accounted for by tabular grains having a tabularity of greater than 8, as determined by the relationship: ##EQU1## wherein T is tabularity; ECD is the mean effective circular diameter in .mu.m of the tabular grains; and t is the mean thickness in .mu.m of the tabular grains. The azoles have the formula: ##STR1## wherein Z is --N.dbd. or --C(R.sup.5).dbd. where R.sup.5 is hydrogen, --NH.sup.2, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms;

Growing community of inventors

Fairport, NY, United States of America

Stephen A Hershey