Henkel Corporation

Cook Composites & Polymers Co.

Other

Cognis Corporation

Diamond Shamrock Chemicals Company

S. C. Johnson Commercial Markets, Inc.

Geo Specialty Chemicals, Inc.

Diamon Shamrock Chemical Co.

Stephen A Fischer

David I Devore

Reuben H Grinstein

Michael S Wiggins

Kartar S Arora

Chase J Boudreaux

Nancy S Clungeon

Patrick M McCurry, Jr

Michael J Incorvia

Reimar Heucher

Judith C Giordan

Allen D Urfer

John F Hessel

Charles B Allen

Sureshchandra G Desai

George A Smith

Steve Boucher

Bruce L Matta

Shruti Singhal

George Roth

Roger Lovald

Jose M Rodriguez

Grannis S Johnson

John J Miskel, Jr

Dinshaw F Bardoliwalla

Dwight D Heinrich

Paul D Whyzmuzis, Deceased

Brenda Taipale

Timothy C Vogel

Harry T Mills

Gary L Speenburgh

Paul D Whyzmuzis

Eric Nowicki

James V Patterson

James P Yosh, Jr

Barbara Balos

Maryellen Hereda

Jeffery L Anderson

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Thomas M Sisson

James R Heyward, Jr

Daniel A Teska

Jerome S Sajbel

Described is a process for making acrylic resins suitable as polymeric surfactants used in emulsion polymerization, as pigment grinding resins and for preparing dispersions used as overprint varnishes. The feedstock is styrene, &agr;-methyl styrene, acrylic acid and a polymerization initiator and is preferably free of solvent. This mix is passed through a continuous tube reactor run at a controlled range of pressure and relatively low residence time and temperature. Optimally, when the polymer/unreacted monomers blend exits the reactor and is devolatilized, the recovered monomers are used to make up part of the feedstock.

Solid acrylic resin using a continuous tube reactor

Novel polymeric compounds are disclosed which may be utilized alone, or after being further polymerized into an emulsion polymer, to form pigmented compositions that are useful in a variety of pigmented compositions, including inks. The inks produced have high bond strength, and are suitable for use in a large number of printing processes, most notably processes involving printing onto flexible substrates.

Pigmented compositions and articles of manufacture containing same

A method for formulating an aqueous dispersion of a polymer includes dissolving a polymer such as an acrylic polyol in a solvent to form a polymer solution. A surfactant is added to the polymer solution, and water is then added with mixing sufficient to dispersed the polymer in the water. The resulting aqueous dispersion can be mixed with a water dispersible polyisocyanate to produce coating materials which can be cured to form tough films and coatings.

Aqueous dispersions of polymers

A polymer useful as an inorganic pigment dispersant is provided. The polymer is derived from monomers consisting essentially of an ethylenically unsaturated aromatic monomer, an ethylenically unsaturated dicarboxylic acid monomer, and an ethylenically unsaturated monocarboxylic acid monomer. The total amount of said ethylenically unsaturated acid monomers is sufficient to permit said polymer to associate with an inorganic pigment in an aqueous medium in a manner which disperses said inorganic pigment in said aqueous medium to form a stable aqueous dispersion of said inorganic pigment, and the amount of said ethylenically unsaturated aromatic monomer is sufficient to reduce the water sensitivity of a dried coating of a latex paint comprised of said stable aqueous dispersion of said inorganic pigment. A process of preparing a polymer useful as an inorganic pigment dispersant and a method of preparing an inorganic pigment dispersion useful in the preparation of latex paints are also provided.

Methods of preparing inorganic pigment dispersions

An antistatic composition containing a crosslinked thermosetting resin formed by reacting, in the presence of a water-soluble solvent, (a) a polyaminoamide having unreacted primary and secondary amine groups and (b) a polychlorohydrin derivative.

Anti-static composition and process for making same

Described is a process for making acrylic resins suitable as polymeric surfactants used in emulsion polymerization, as pigment grinding resins and for preparing dispersions used as overprint varnishes. The feedstock is styrene, .alpha.-methyl styrene, acrylic acid and a polymerization initiator and is preferably free of solvent. This mix is passed through a continuous tube reactor run at a controlled range of pressure and relatively low residence time and temperature. Optimally, when the polymer/unreacted monomers blend exits the reactor and is devolatilized, the recovered monomers are used to make up part of the feedstock.

Bulk polymerization process for preparing solid acrylic resin

A process for providing a substrate with anti-static and lubricating properties by contacting the substrate with a water-soluble or water-dispersible polymer composition having hydrophobic and hydrophilic properties.

Anti-static lubricant composition and method of making same

An aqueous dispersion containing a polyamide and non-polyamide polymer is prepared by dissolving the polyamide in an organic solvent with a surfactant to form a polyamide solution. Water is then added to the polyamide solution to form an aqueous dispersion. The non-polyamide polymer can be added before or after the addition of water. The polyamide/non-polyamide dispersion can be used to produce an ink with better adhesion to plastic substrates and reduced blocking problems.

Aqueous polyamide dispersion composition

Latexes are thickened by compounds of the formula ##STR1## wherein R.sup.1 is an aliphatic, substituted aliphatic, aromatic, or substituted aromatic radical having a valence of from 2 to 8; each of B.sub.1 -B.sub.8 is independently an ester, amide, amine, ether, sulfide, disulfide, thiocarbamate, urea, thiourea, urethane, sulfate, phosphate, carbonyl, methylene, thioamide, carbonate, or imide linkage; each of X.sup.1 -X.sup.8 is independently --A.sub.1 --R.sup.2 --A.sub.2 -- or --A.sub.1 -- wherein each of A.sub.1 and A.sub.2 is independently an ester, amide, amine, ether, sulfide, disulfide, urethane, thiocarbamate, urea, thiourea, sulfate, phosphate, carbonyl, methylene, thioamide, carbonate, or imide linkage and R.sup.2 is a divalent aliphatic, substituted aliphatic, aromatic, or substituted aromatic radical with the proviso that only one of B.sub.1 -B.sub.8 is urethane and that when one of B.sub.1 -B.sub.8 is urethane, one of A.sub.1 and A.sub.2 is not urethane; each of d, g, j, m, p, s, v, y is independently 0 or 1, each of c, f, i, l, o, r, u, x is independently any integer or non-integer from 0 to about 200; each of J, K, L, M, N, P, Q, S is 0 or 1; each of e, h, k, n, q, t, w, z is independently any integer or non-integer from 0 to about 200; each of R.sup.3 -R.sup.10 is independently an aliphatic, substituted aliphatic, aromatic, or substituted aromatic radical having from 1 to about 50 carbon atoms; each of AG and AO is independently an ethyleneoxy, 1,2-propyleneoxy, 1,2-butyleneoxy unit or combinations thereof.

Polymeric thickeners for aqueous compositions

A process is provided for preparing a dispersion of a polyamide in water, said process comprising:

Aqueous dispersions of polyamides

A composition for thickening aqueous based personal care products is comprised of a cosolvent selected from the group consisting of a diol, the mono alkyl ether of a diol, a salt of a sulfated ethoxylated alcohol, a salt of a sulfated ethoxylated alkyl phenol, and a complex organic phosphate ester; water; a nonionic surfactant and, a complex ester.

Thickener for aqueous compositions

A polymer useful as an inorganic pigment dispersant is provided. The polymer is derived from monomers consisting essentially of an ethylenically unsaturated aromatic monomer, an ethylenically unsaturated acid monomer, and an ethylenically unsaturated amide monomer. The amount of said ethylenically unsaturated acid monomer is sufficient to permit said polymer to associate with an inorganic pigment in an aqueous medium in a manner which disperses said inorganic pigment in said aqueous medium to form a stable aqueous dispersion of said inorganic pigment, and the amount of said ethylenically unsaturated aromatic monomer is sufficient to reduce the water sensitivity of a dried coating of a latex paint comprised of said stable aqueous dispersion of said inorganic pigment. A process of preparing a polymer useful as an inorganic pigment dispersant and a method of preparing an inorganic pigment dispersion useful in the preparation of latex paints are also provided.

A composition and process for enhancing the aesthetic and tactile properties of an alkyl polyglycoside involving combining an alkyl polyglycoside having the general formula I:

Alkyl polyglycosides having improved aesthetic and tactile properties

Growing community of inventors

Yardley, PA, United States of America

Stephen A Fischer