Celgard Inc.

Stefan Reinartz

Kang Karen Xiao

Eric Robert White

Masaaki Okada

Changqing Wang Adams

Robert A Nark

Katharine R Chemelewski

Eric Joseph Penegar

Brian R Stepp

Xiaomin Zhang

Kristoffer K Stokes

Ronnie E Smith

Insik Jeon

Junqing Ma

Takahiko Kondo

Michael B Lane

Edward Kruger

Xiang Yu

C Glen Wensley

Daniel R Alexander

Allen M Donn

Yao Lu

Zhengming Zhang

Hisaki Ikebata

Described herein is a multilayer microporous film or membrane that may exhibit improved properties, including improved dielectric break down and strength, compared to prior monolayer or tri-layer microporous membranes of the same thickness. The preferred multilayer microporous membrane comprises microlayers and one or more lamination barriers. Also disclosed is a battery separator or battery comprising one or more of the multilayer microporous films or membranes. The inventive battery and battery separator is preferably safer and more robust than batteries and battery separators using prior monolayer and tri-layer microporous membranes. Also, described herein is a method for making the multilayer microporous separators, membranes or films described herein.

Microlayer membranes, improved battery separators, and related methods

A new or improved microporous monolayer, bilayer, trilayer, or multilayer membrane, separator membrane, separator, or coated separator is disclosed. The membrane is preferably made up of at least one resin or polymer and at least one additive. The additive may comprise at least one material that improves adhesion of the microporous membrane to a coating, including a polyaramid-containing coating and a PCS coating, or to a different material such as a metallic surface, including an electrode surface. Improvements in adhesion are based on comparisons to similar microporous membranes without the at least one additive. In some preferred embodiments, the at least one additive may comprise, consist of, or consist essentially of a functionalized polymer or the combination of a functionalized polymer and an elastomer. In some embodiments, the functional group of the functionalized polymer may be maleic anhydride (MAH). Also disclosed is a battery separator or coated separator comprising the new or improved microporous membrane. The battery separator may comprise the microporous membrane coated with a polyaramid-containing coating. Also disclosed is a new or improved separator, composite, battery, secondary lithium ion battery, and/or vehicle or device comprising the separator, composite, or battery.

Battery separators, coated battery separators, batteries, and related methods

A multilayer microporous membrane which includes microlayers and one or more lamination barriers is disclosed. Also disclosed is a battery separator or battery comprising one or more of the multilayer microporous films or membranes. Also, described herein is a method for making multilayer microporous separators, membranes or films.

Described herein is a multilayer microporous film or membrane that may exhibit improved properties, including improved dielectric break down and strength, compared to prior monolayer or tri-layer microporous membranes of the same thickness. The preferred multilayer microporous membrane comprises microlayers and one or more lamination interfaces or barriers. Also disclosed is a battery separator or battery comprising one or more of the multilayer microporous films or membranes. The inventive battery and battery separator is preferably safer and more robust than batteries and battery separators using prior monolayer and tri-layer microporous membranes. Also, described herein is a method for making the multilayer microporous separators, membranes or films described herein.

Microlayer membranes, battery separators, batteries, and related methods

A novel or improved base film for impregnation, impregnated base film, product incorporating the impregnated base film, and/or related methods as shown, claimed or described herein.

Base films for impregnation, improved impregnated products, and related methods

New and/or improved coatings, layers or treatments for porous substrates, including battery separators or separator membranes, and/or coated or treated porous substrates, including coated battery separators, and/or batteries or cells including such coatings or coated separators, and/or related methods including methods of manufacture and/or of use thereof are disclosed. Also, new or improved coatings for porous substrates, including battery separators, which comprise at least a matrix material or a polymeric binder, and heat-resistant particles with additional additives, materials or components, and/or to new or improved coated or treated porous substrates, including battery separators, where the coating comprises at least a matrix material or a polymeric binder, and heat-resistant particles with additional additives, materials or components are disclosed. Further, new or improved coatings for porous substrates, including battery separators, and new and/or improved coated porous substrates, including battery separators, new or improved coatings for porous substrates, including battery separators, which comprise at least (i) a matrix material or a polymeric binder, (ii) heat-resistant particles, and (iii) at least one component selected from the group consisting of a cross-linker, a low-temperature shutdown agent, an adhesion agent, and a thickener, and new and/or improved coated porous substrates, including battery separators, where the coating comprises at least (i) a matrix material or a polymeric binder, (ii) heat-resistant particles, and (iii) at least one component selected from the group consisting of a cross-linker, a low-temperature shutdown agent, an adhesion agent, a thickener, a friction-reducing agent, and a high-temperature shutdown agent are disclosed.

Coated separators, lithium batteries, and related methods

Described herein, are battery separators, comprising the following: a microporous polymeric film; and an optional coating layer on at least one side of the microporous polymeric film, wherein at least one of the microporous polymeric film and the optional coating comprises an additive. The additive is selected from the group consisting of a lubricating agent, a plasticizing agent, a nucleating agent, a shrinkage reducing agent, a surfactant, an SEI improving agent, a cathode protection agent, a flame retardant additive, LiPFsalt stabilizer, an overcharge protector, an aluminum corrosion inhibitor, a lithium deposition agent or improver, or a solvation enhancer, an aluminum corrosion inhibitor, a wetting agent, and a viscosity improver. Also, described herein are batteries, including lithium-ion batteries, comprising one or more of the described separators. Methods for making the battery separators are also described.

Additives for improved battery performance, improved additive-containing membranes, improved battery separators, improved batteries, and related methods

Coating compositions for porous substrates, and/or related methods including methods of manufacture and/or of use thereof are disclosed. Also, coating compositions for porous substrates, where the coating comprises at least a polymeric binder and heat-resistant particles with or without additional additives, materials or components are disclosed. Further, coating compositions for porous substrates which comprise at least (i) a polymeric binder, (ii) heat-resistant particles, and (iii) at least one component selected from the group consisting of a cross-linker, a low-temperature shutdown agent, an adhesion agent, and a thickener, and coated porous substrates, including battery separators, where the coating composition comprises at least (i) a polymeric binder, (ii) heat-resistant particles, and (iii) at least one component selected from the group consisting of a cross-linker, a low-temperature shutdown agent, an adhesion agent, a thickener, a friction-reducing agent, a high-temperature shutdown agent are disclosed.

Coatings, coated separators, batteries, and related methods

In accordance with at least certain embodiments, the present invention is directed to novel, improved, coated, or treated separator membranes, separators or membrane based separators for lithium batteries. The membranes or separators may include non-woven layers, improved surfactant treatments, or combinations thereof. The separators or membranes are useful for solvent electrolyte lithium batteries, especially rechargeable lithium ion batteries, and provide improved performance, wettability, cycling ability, and/or recharging efficiency.

Microporous battery separators including polyolefin layer and non-woven layer with alkylbenzene sulfonic acid lithium salt surfactant, lithium batteries utilizing the same, and methods of manufacture of the same

New and/or improved coatings for porous substrates, including battery separators or separator membranes, and/or coated porous substrates, including coated battery separators, and/or batteries or cells including such coatings or coated separators, and/or related methods including methods of manufacture and/or of use thereof are disclosed. Also, new or improved coatings for porous substrates, including battery separators, which comprise at least a polymeric binder and heat-resistant particles with or without additional additives, materials or components, and/or to new or improved coated porous substrates, including battery separators, where the coating comprises at least a polymeric binder and heat-resistant particles with or without additional additives, materials or components are disclosed. Further, new or improved coatings for porous substrates, including battery separators, and new and/or improved coated porous substrates, including battery separators, new or improved coatings for porous substrates, including battery separators, which comprise at least (i) a polymeric binder, (ii) heat-resistant particles, and (iii) at least one component selected from the group consisting of a cross-linker, a low-temperature shutdown agent, an adhesion agent, and a thickener, and new and/or improved coated porous substrates, including battery separators, where the coating comprises at least (i) a polymeric binder, (ii) heat-resistant particles, and (iii) at least one component selected from the group consisting of a cross-linker, a low-temperature shutdown agent, an adhesion agent, a thickener, a friction-reducing agent, a high-temperature shutdown agent are disclosed.

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Waxhaw, NC, United States of America

Stefan Reinartz