Rhodia Chimie

Bluestar Silicones France Sas

Elkem Silicones France Sas

Bluestar Silicones France

Stefan Breunig

Christian Maliverney

Delphine Blanc

Jean-Marc Frances

Gerard Mignani

Michel Feder

Philippe Olier

Gérald Guichard

Jérôme Bordas

Jean-Pierre Delarche

Gèrard Mignani

A method is described for vulcanizing a green tire using an organopolysiloxane-based mold release agent lubricant composition. Also described, is an organopolysiloxane-based mold release agent lubricant composition.

Method for vulcanizing a green tire using an organopolysiloxane-based mold release agent lubricant composition

A method of lubricating an expandable rubber bladder is described for use during a vulcanization of a green tire within a metal press. The method can include applying compositions in the form of emulsions of silicone oils to the inner surface of the green tires and/or to the outer surface of the vulcanization bladders to facilitate the molding-demolding thereof during the manufacture of the tires.

Lubrication method

An article having antifouling properties and intended to be employed in aquatic uses, in particular marine uses. In particular there is provided an article having antifouling properties and intended to be employed in aquatic uses which comprises: a) a support, b) optionally, at least one primer coat on said support comprising at least one anticorrosive product, c) optionally, at least one intermediate primer coat promoting adhesion between the coats, d) at least one adhesion-promoting coat or tie coat, deposited on said primer coat or on said support when the primer coat is absent, and e) at least one antifouling coat or topcoat, deposited on said adhesion-promoting coat or tie coat.

Article having antifouling properties for aquatic and particularly sea use

An article having antifouling properties and intended to be employed in aquatic uses, in particular marine uses, which comprises: a) a support, b) optionally, at least one primer coat on said support comprising at least one anticorrosive product, c) optionally, at least one intermediate primer coat promoting adhesion between the coats, d) at least one adhesion-promoting coat or tie coat, deposited on said primer coat or on said support when the primer coat is absent, and e) at least one antifouling coat or topcoat, deposited on said adhesion-promoting coat or tie coat.

The invention relates to compositions in the form of silicone oil emulsions which are intended to be applied to curing bladders as a mold-release agent during tire production.

Siloxane-based composition which is intended for tire molding/stripping

Organosilicon compounds having at least one &#x2261;SiH unit per molecule are functionalized via heterogeneous catalysis into, for example, epoxidized POS by hydrosilylation between an ethylenically unsaturated epoxide such as VCMX and a hydrogenated POS of the MDD'M type with M=RSiO, D=R&#x2014;SiO, D&#x2032;=RH=SiO, in which R=alkyl, and wherein the viscosity of the final product is controlled, i.e., to limit the parasitic reactions of cationic polymerization by opening of heterocycles, resulting in partial or total gelling of the reaction mixture, said hydrosilylation characteristically being carried out in the presence of at least one inorganic non-nucleophilic base and, optionally, water.

Functionalization of silicones and anti-adhesive coatings made therefrom

The subject-matter of the invention is a process for the preparation of silicone oils which are weakly colored and low in turbidity by hydrosilylation of polyorganohydrosiloxanes with different or identical synthons comprising at least one hydrocarbon-comprising ring in which is included an oxygen atom, the said reaction being carried out in the presence of a heterogeneous catalytic composition comprising a metal chosen from the group consisting of cobalt, rhodium, ruthenium, platinum and nickel deposited on an inert support.

Method for preparing silicone oils by hydrosilylation with polyorganohydrogenosiloxanes and units containing at least one hydrocarbon ring including an oxygen atom, in the presence of a heterogeneous catalytic composition

The invention concerns a lubricating organo-functional silicone oil, whether or not in emulsion. The invention aims at improving oils and lubricating silicone emulsions, in terms of emulsion stability, transfer and flow of the oil in emulsion on metal surfaces, of stripping lubricating power, non-clogging of molds and paintability of molded metal articles when used for stripping. In order to achieve said aim, the inventive POS oil is functionalized with the lubricating organophilic radical W (C12-C20 alkyl) and with a radical bearing one or several adhering functions such as diacid, thiol, phosphonate, sulphonate hydroxy, hydroxyamine, amine, ether, amide and their combinations. The invention also concerns emulsions whether or not containing additives, based on said WY functionalized POS oils, the preparation of said oils and said emulsions and their uses when stripping metal articles molded in metal moulds.

Lubricating polyorganosiloxane oil, aqueous emulsion containing same, preparation and use thereof for stripping metals

The invention aims at improving such compositions by proposing a non-toxic diluent harmless to reactivity and by making these compositions translucent, free from metallic impurities and capable of constituting light-polymerisable varnish with good properties of ductility for leveling and surface coating. This aim is achieved by the invention which proposes a composition comprising an organic polymerisable matrix A, containing cyclo-aliphatic epoxide resins or not, acrylates, alkenyl-ethers or polyols, a silicon diluent B with viscosity less than 100 MPa's, a radical and/or cationic (onium salt) photoinitiator C, optionally a light-sensitising material D, a pigment E and another additive F; provided that when A is a cyclo-aliphatic epoxide resin, B has a metal concentration not more than 100 ppm. The invention also concerns the use of the silicon diluent B for preparing a composition crosslinkable by cationic and/or radical process, under UV radiation, in the presence of a photoinitiator (ink or varnish).

Composition (e. g. ink or varnish) which can undergo cationic and/or radical polymerization and/or crosslinking by irradiation, based on an organic matrix, a silicone diluent and a photoinitiator

The invention concerns a novel method for preparing stable silicone fluid containing &equiv;SiH groups. The preparation method is carried out from a first silicone fluid containing &equiv;SiH groups and monomers with both a functional group and a group capable of hydrosylilation; the mol ratio monomer &equiv;SiH of said fluid ranging from 0.0001 and 1. The fluids obtained by this novel method are used particularly for producing antiadhesive coatings.

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Villette de Vienne, France

Stefan Breunig