Centre National De La Recherche Scientifique

Bostik Sa

Total Research & Technology Feluy

Université De Rennes 1

Total Petrochemicals Research Feluy

Université De Rennes I

Sophie Guillaume

Abbas Razavi

Guillaume Michaud

Stephane Fouquay

Frederic Simon

Marion Helou

Jean-François Carpentier

Martine Slawinski

Olivier Miserque

Cyril Chauveau

Jean-françois Carpentier

Yann Sarazin

Abdou Khadri Diallo

Elise Vanbiervliet

William Guerin

Stéphane Fouquay

Frédéric Simon

Liana Annunziata

Jean Francois Carpentier

The invention relates to a monoethylenically unsaturated monomer of formula (I), and to the use thereof for producing a polymer. The invention also relates to the polymer obtained by polymerising said monomer, and to the use thereof in a composition for producing coatings.

Monoethylenically unsaturated monomers and uses thereof

1) Hydrocarbon-based copolymer comprising two end groups preceded by an ester function and chosen from a 2-oxo-1,3-dioxolan-4-yl (or cyclocarbonate), a dithiocyclocarbonate, an exo-vinylene cyclocarbonate and a 2-oxo-1,3-dioxolen-4-yl, the main chain of which comprises units (I) and (II)  in which Ris notably a methyl radical; and the number-average molecular mass Mn of which is between 400 and 100 000 g/mol. 2) Process for preparing said copolymer, comprising: (i) a step of heating a statistical bipolymer A chosen from a poly(butadiene-isoprene), a poly(butadiene-myrcene) and a poly(butadiene-farnesene); and then (ii) a step of heating the product formed, in the presence of a chain-transfer agent. 3) Use as adhesive, as a mixture with an amine compound comprising at least two amine groups.

Liquid hydrocarbon-based copolymers bearing two cyclocarbonate ester end groups

1) Hydrocarbon-based copolymer comprising two end groups preceded by an ether function and chosen from a 2-oxo-1,3-dioxolan-4-yl (or cyclocarbonate), a dithiocyclocarbonate, and a 2-oxo-1,3-dioxolen-4-yl, the main chain of which comprises units (I) and (II)  2) Process for preparing said copolymer, comprising: 3) Use as adhesive, as a mixture with an amine compound comprising at least two amine groups.

Liquid hydrocarbon copolymers having two cyclocarbonate ether end groups

Polymer of formula (1) bearing an alkoxysilane end group:  Preparation by ring-opening metathesis polymerization. Use as an adhesion promoter or a reactive plasticizer.

Hydrocarbon-based polymers bearing an alkoxysilane end group

Hydrocarbon-based polymer of formula (1) bearing alkoxysilane end groups: 

Hydrocarbon-based polymers bearing two alkoxysilane end groups

1) Hydrocarbon-based polymer of formula (I):  

Hydrocarbon-based polymers bearing dithiocyclocarbonate end groups

1) Hydrocarbon polymer having two azlactone end groups Fis formula (IIa) and Fis formula (IIb): 

Hydrocarbon polymers having two azlactone end groups

The present invention relates to the field of tailored di-, tri- and multi-block as well as gradient polyesters/polycarbonates copolymers prepared by introducing monomers simultaneously in the reaction medium in the presence of an organometallic, metal salt or organic catalyst.

One-step, one-pot process for preparing multiblock and gradient copolymer

A process for copolymerizing selectively i) ethylene carbonate with ii) one or more cyclic esters can include contacting the ethylene carbonate with the one or more cyclic esters in the presence of a catalyst. The catalyst can be a Zn-complex with a diaminophenolate ligand (NNO) or a &#x3b2;-diiminate ligand (BDI).

Method of copolymerizing ethylene carbonate with one or more cyclic esters

Poly(carbonate-urethane) or poly(ester-urethane) may be characterized in that of carbonate soft segments have molecular weights Mn ranging between 10,000 and 250,000 g/mol. The segments' length may be monitored by the ring-opening polymerization condition. The process of preparing the poly(carbonate-urethane) or poly(ester-urethane) may include immortal ring-opening polymerization of a cyclic carbonate or of a cyclic ester or diester monomers in the presence of a first catalyst system and diols or polyols. The process may include chemical modification of the hydroxyl chain-end groups into carboxylic groups in the presence of a second catalyst system. The process may include a coupling reaction with at least 2 equivalents of a second cyclic carbonate, enabling coupling with the carboxylic moiety in the presence of a third catalyst system. The process may include polyaddition of a diamine or a polyamine via ring-opening of the second cyclic carbonate, and obtention of poly(carbonate-urethane) or poly(ester-urethane).

Isocyantate-free method for preparing poly(carbonate-urethane) or poly(ester-urethane)

Process for the preparation of a hydrocarbon polymer comprising two end groups having 2-oxo-1,3-dioxolan-4-yl final parts by ring opening metathesis in the presence of a metathesis catalyst, of a chain transfer agent comprising a carbonate ring and of a compound of formula comprising at least one C-Cring having a carbon-carbon double bond. Hydrocarbon polymer capable of being obtained by this process. Process for the preparation of polyurethanes by reaction of this polymer and of a compound comprising at least one amine group, and polyurethanes thus obtained.

Hydrocarbon-based polymers comprising two end groups with 2-oxo-1,3-dioxolan-4-yl endings, preparation thereof and use thereof

This invention relates to the synthesis of polycarbonates prepared from carbonate monomers derived from the biomass in the presence of a system comprising an organometallic transfer agent and alcohol. It also relates to the polymers resulting from these cyclic compounds.

Monomers issued from renewable resources and process for polymerising them

The present invention discloses a method for preparing poly(carbonate-urethane) or poly(ester-urethane) without isocyanate.

Isocyanate-free method for preparing poly(carbonate-urethane) or poly(ester-urethane)

This invention relates to the polymerisation of five-, six- or seven-membered cyclic carbonates by ring-opening polymerisation in the presence of a system comprising a metal salt such as triflate, triflimidate, acetylacetonate or carboxylate and an alcohol.

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Vitre, France

Sophie Guillaume