Shell Oil Comapny

Shell Internationale Research Maatschappij, B.v.

Smita Edulji

Evert Van Der Heide

Brendan Dermot Murray

Jean Paul Andre Marie Joseph Ghislain Lange

Reinhard Geyer

Dionysius Jacobus Maria De Vlieger

Hendrik Albertus Colijn

Henri Preising

Dionysius Jacobus De Vlieger

The invention provides a catalyst system comprising: a) one or more Group 1 metal phosphotungstate-containing species; and b) one or more catalytic species suitable for hydrogenation; and a process for the preparation of monoethylene glycol from starting material comprising one or more saccharides, by contacting said starting material with hydrogen in a reactor in the presence of a solvent and said catalyst system.

Catalyst system and process for the production of glycols

Implementations of the disclosed subject matter provide a process for producing ethylene glycol and propylene glycol from a sorbitol feed which may include contacting the sorbitol feed with hydrogen in a reactor in the presence of a solvent and a bi-functional catalyst system. The bi-functional catalyst system may include a first catalyst comprising a copper compound, a zinc compound, and an additional metal compound and a second catalyst comprising sodium carbonate.

Method for the production of glycols from sorbitol

The invention provides a catalyst system comprising: a) one or more silver tungstate-containing species; and b) one or more catalytic species suitable for hydrogenation, wherein the weight ratio of said one or more silver tungstate-containing species to the one or more catalytic species suitable for hydrogenation is greater than 2.5:1, on the basis of the total weight of the catalyst system; and a process for the preparation of monoethylene glycol from starting material comprising one or more saccharides, by contacting said starting material with hydrogen in a reactor at a reactor temperature in the range of from 145 to 190&#xb0; C. in the presence of a solvent and said catalyst system.

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Houston, TX, United States of America

Smita Edulji