Mobay Corporation

Bayer Corporation

Mobay Chemical Corporation

Miles Inc.

Bayer Aktiengesellschaft

Other

Sivaram Krishnan

Charles E Lundy

James B Johnson

Ronald L Price

Roger J White

Winfried G Paul

Arthur L Baron

Robert Allen Pyles

Mark W Witman

John R Sanderson

Ulrich R Grigo

Dieter Neuray

Klaus Kircher

Wolfgang Cohnen

James N Rieck

Wolfgang Ebert

James W Rosthauser

Hans-Jurgen Kress

Robson M Mafoti

Karl W Haider

James P Mason

Timothy J Pike

Russell P Carter, Jr

Ramesh M Pisipati

David M Derikart

Douglas G Powell

Daniel H Bolton

Jon M Newcome

Steven A Jorissen

Donald K Booher

Kevin F Dunay

Jeffrey M Tennant

Wolfgang Alewelt

Neil H Nodelman

Rick L Archey

Peter R Muller

Gerard E Reinert

James Y J Chung

Klaus Geisler

Jack C Chan

Richard E Keegan

Nelson R Lazear

John V Bailey

Jeff M Tennant

Michael A Gerace

Larry D Sarver

Peter H Shu

Gerald L Robbins

Edward M Anderson

Susan H Bates

William B Villee

Walter G Chwala

Michael P Jenkins

Joseph R Thomas

Pia I Santelices

Robert D Kroshefsky

Donald A Folajtar

William G Curtis

Wolfgang J Siebourg

Wolfgang Siebourg

A process for making a photochromic optical lens is disclosed. In a first embodiment of the process a multi-plied laminate, containing a ply of photochromic thermoplastic polyurethane (herein &ldquo;TPU&rdquo;) and a ply containing thermoplastic polycarbonate, is first placed in the cavity of a suitable mold. The ply that contains polycarbonate resin is placed facing the cavity. Thermoplastic polycarbonate resin is then injected into the cavity. In a second embodiment, referred to as an over-mold method, polycarbonate is first injection molded into a molding cavity to form a substrate. Photochromic TPU is, in a subsequent step, injected into the cavity to form a superstrate overlay. In both embodiments, the articles thus molded are suitable for the preparation of optical lenses.

Process for preparing a photochromic lens

The present invention resides in the surprising properties found to characterize the thermoplastic molding composition which comprise a polydiorganosiloxane block copolycarbonate and an additive amount of a partially fluorinated polyolefin. The composition of the invention has a surprisingly improved flame retardance and a high impact strength.

Flame retardant polycarbonate blends

A thermoplastic polycarbonate molding composition free from organo phosphorus compounds and having an improved resistance to discoloration caused by exposure to High Intensity Discharge (HID) light and heat is disclosed. Accordingly, the molding composition contains (co)polycarbonate resin, a dimeric benzotriazole and an ester of a 3,5-di-tert-butyl-4-hydroxyhydrocinnamic acid. In a preferred embodiment, a sheet made of (co)polycarbonate resin is rendered improved resistance to discoloration by having applied to at least one of its surfaces an adherent protective film prepared from the polycarbonate composition of the invention.

Color-stable polycarbonate composition and articles molded therefrom

A thermoplastic polycarbonate molding composition having improved resistance to gamma radiation-induced yellowing is disclosed. Particularly suitable for the manufacture of devices targeted for medical applications, the composition contains additive amounts of a first stabilizing compound conforming structurally to

Polycarbonate composition resistant to gamma radiation

A thermoplastic polycarbonate molding composition having improved resistance to gamma radiation-induced yellowing is disclosed. Particularly suitable for the manufacture of devices geared for medical applications, the composition contains an additive amount of a stabilizing compound conforming structurally to

A thermoplastic molding composition comprising polycarbonate resin and additive, positive, amounts of stabilizer and salt is disclosed. The composition is characterized by its freedom from splay and by its improved flame retardance. The stabilizer of the invention is a physical mixture of poly(alkyl methacrylate) with fluorinated polyolefin, and the salt is an alkali metal or alkaline earth metal salt of perfluoroalkane sulfonic acid, aromatic sulfimide, or aromatic sulfonic acid.

Flame retardant polycarbonate composition

The present invention relates to a novel photochromic polyurethane consisting essentially of an isocyanate reactive mixture consisting essentially of: i) from about 40 to about 85% by weight of one or more polyols having a nominal functionality of from 2 to 4 and molecular weights of from 500 to 6000 g/mole; ii) from about 15 to about 60% by weight of one or more diols or triols or mixtures thereof having a functionality of from 2 to 3 and molecular weights of from 62 to 499; b) an aliphatic polyisocyanate having a functionality ranging from about 2 to about 3; and c) a photochromic compound selected from a group consisting of spirooxazines, fulgides, fulgimides, and naphthopyrans, wherein the photochromic compound is present in an amount of 0.01 to 5 parts per hundred parts by weight of the isocyanate reactive mixture.

Photochromic polyurethanes

A thermoplastic composition featuring an improved resistance to thermally induced resin degradation is disclosed. The composition comprises (i) thermoplastic polycarbonate resin (ii) about 3 to 20 percent, relative to the total weight of (i) and (ii), of titanium dioxide, and (iii) an oligomer or polymer the structure of which features at least one pendant cyclic iminoether group per molecular chain. The amount of (iii) is that which is sufficient to improve the resistance of the composition to thermal degradation.

Melt-stable pigmented polycarbonate molding composition

A thermoplastic composition featuring an improved resistance to hydrolysis is disclosed. The composition comprises (i) thermoplastic polycarbonate resin (ii) about 0.01 to 3 percent of a compound selected from the group consisting of phosphite and phosphonite and (iii) an additive amount of an oligomer or polymer the structure of which features at least one pendant cyclic iminoether group per molecular chain. The additive amount is that which is sufficient to improve the resistance of the polycarbonate resin to hydrolysis.

Hydrolysis-stable polycarbonate molding composition

A thermoplastic molding composition having low haze values, suitable for optical applications is disclosed. The compositions contains a resinous component selected from the group consisting of (i) a homogeneous blend of polycarbonate resin and polycaprolactone and (ii) a copoly(carbonate-lactone) block or random copolymer, and melanin in an amount of 0.1 to 1.0 parts per hundred parts of weight of the resinous component.

Thermoplastic composition suitable for optical applications having low

A thermoplastic polycarbonate composition suitable for the preparation of optical storage devices, for instance optical discs, is disclosed. The composition, containing a stabilizing amount of partially fatty acid ester and as a stabilizer, a compound the structure of which contains at least one benzofuran-2-one group per molecule, features improved resistance to yellowing, reduced haze and high total light transmission values.

Polycarbonate composition useful in optical storage applications

A photochromic ophthalmic lens and a process for its preparation are disclosed. The lens comprise a substantially transparent substrate having a lenticular shape and, at least one film adhering to at least one surface of said substrate. The film contains a resinous blend of polycarbonate resin, and poycaprolactone and an effective amount of a photochromic dye selected from a group consisting of spiropyrans, spiroxazines, fulgides and fulgimides. In an additional embodiment the film contains a copoly(carbonate-lactone) block or random copolymer.

Photochromic ophthalmic lens

A transparent thermoplastic molding composition having good release properties is disclosed. The composition which contains no magnetic elements contains a polycarbonate resin and 0.01 to 0.3 percent by weight of a mold release agent. The agent is the product of a reaction of a compound represented by formula (I) ##STR1## where R.sub.1 denotes a C.sub.1-30 -alkyl group, with at least one member selected from the group consisting of ##STR2## where R.sub.2 and R.sub.3 independently denote C.sub.1-30 - alkyl or an aryl group, and ##STR3## where n is 1-7.

Polycarbonate compositions having reduced tendency to splay

A thermoplastic molding composition having improved release properties is disclosed. The composition contains a polycarbonate resin and a mold release agent which is a hydroxy ester conforming structurally to ##STR1## where R is a member selected from the group consisting of glycerol, trimethylol propyl and pentaerythritol radicals, R' denotes a C.sub.6-20 hydrocarbon radical having at least one pendant hydroxyl group, and x is 2 to 4.

Polycarbonate compositions having good mold-release properties

Growing community of inventors

Pittsburgh, PA, United States of America

Sivaram Krishnan