Sk Corporation

Korea Research Institute of Chemical Technology

Sin Cheol Kang

Sun Woong Choi

Ahn Seop Choi

Dong Hyun Cho

Sunyoung Park

Yong Ki Park

Won Choon Choi

Na Young Kang

Hwi Min Seo

Dae Jin Kim

Joo Hyeong Oh

A naphtha and methanol mixed catalytic cracking reaction process involves a simultaneous cracking reaction of naphtha and methanol using a circulating fluidized-bed reactor comprising a reactor, a stripper, and a regenerator. The naphtha is supplied from the bottom part of the reactor at a position between 0%&#x2dc;5% of the total length of the reactor, and the methanol is supplied from the bottom part of the reactor at a position between 10%&#x2dc;80% of the total length of the reactor. The catalytic cracking reaction process uses the circulating fluidized-bed reactor and can crack naphtha and methanol simultaneously by having different introduction positions for the naphtha and methanol in the reactor, which is advantageous for heat neutralization, so that energy consumption can be minimized and also the yield of light olefins can be improved by suppressing the production of light saturated hydrocarbons such as methane, ethane and propane.

Naphtha and methanol mixed catalytic cracking reaction process

A method of on-line coating a coat film on the inner wall of a reaction tube in a hydrocarbon pyrolysis reactor for preventing the formation and the deposit of coke on the inner walls. This method comprises the steps of vapor depositing a mixed solution of a metal alkoxide and a chromic compound on the inner walls concurrently with introducing a carrier at a flow rate of 1-5000 kg/hr/coil at a temperature of 600-900&#xb0; C. under a pressure of 0-3 kg/cmto form a buffer layer on the inner walls; and vapor depositing a metal alkoxide as a barrier on the buffer layer; and vapor depositing an alkali metal/alkaline earth metal compound alone or mixed with metal alkoxide as a decoking layer on the barrier. A decoking layer may further be provided on the diffusion barrier.

Method of on-line coating of a film on the inner walls of the reaction tubes in a hydrocarbon pyrolysis reactor

A method of on-line coating a coat film on the inner wall of a reaction tube in a hydrocarbon pyrolysis reactor for preventing the formation and the deposit of coke on the inner walls. This method comprises the steps of vapor depositing a mixed solution of a metal alkoxide and a chromic compound on the inner walls concurrently with introducing a carrier at a flow rate of 1-5000 kg/hr/coil at a temperature of 600-900&deg; C. under a pressure of 0-3 kg/cm to form a buffer layer on the inner walls; and vapor depositing a metal alkoxide as a barrier on the buffer layer; and vapor depositing an alkali metal/alkaline earth metal compound alone or mixed with metal alkoxide as a decoking layer on the barrier. A decoking layer may further be provided on the diffusion barrier.

Method of on-line coating film on the inner walls of the reaction tubes in a hydrocarbon pyrolysis reactor

Growing community of inventors

Seoul, South Korea

Sin Cheol Kang