California Institute of Technology

Honda Motor Co., Ltd.

University of California

Georgia Tech Research Corporation

Other

Materia, Inc.

Alionyx Energy Systems

Simon Christopher Jones

Christopher J Brooks

Robert H Grubbs

Thomas F Miller, Iii

Qingmin Xu

Victoria K Davis

Kaoru Omichi

Isabelle M Darolles

Nam Hawn Chou

Christopher M Bates

Julia A Kornfield

Ming-Hsin Wei

Nebojsa Momcilovic

Michael A Webb

Brett M Savoie

Ryan Mckenney

Mark E Davis

Hongjin Tan

Stephen A Munoz

Maksudul M Alam

Cedric M Weiss

Jeongmin Kim

Arunkumar Tiruvannamalai

Brendon McNicholas

Virendra Sarohia

Walt A De Heer

Li-Sheng Wang

Keith Billings

Seth R Marder

Joshua N Haddock

Christopher John Brooks

William Wolf

Ryan K McKenney

Alice Chang

Jennifer Marie Murphy

Sohrab Hossain

Bernard Kippelen

Michael A Giardello

Harry B Gray

Farshad J Motamedi

Clifford Lee Henderson

Joseph W Perry

Brian Edgecombe

Takashi Okada

Li-sheng Wang

Peter J Hotchkiss

Benoit Domercq

Thay A Ung

Jennifer E Curtis

Steve Munoz

Paul Viskovich

Elisa Riedo

Robert J Szoskiewicz

Vamsi K Kodali

Debin Wang

Yueming Hua

Philoseok Kim

Emmanuelle Despagnet-Ayoub

Xiaohong Zhang

Danh Ngo

Andrew Stewart

Zeiad Muntasser

Demetrio Batac

Mohamed El-Kumbari

Nanditha Nair

Thomas F Miller Iii

Thomas F Iii Miller

The present disclosure relates to fluoride ion batteries and structures of metal based electrode materials for various fluoride ion batteries. The structures of the metal based electrode materials comprise one or more shells or interfaces, enabling the electrodes to operate at room temperature with a liquid electrolyte.

Liquid-type room-temperature fluoride ion batteries

The present disclosure relates to a method of making core-shell and yolk-shell nanoparticles, and to electrodes comprising the same. The core-shell and yolk-shell nanoparticles and electrodes comprising them are suitable for use in electrochemical cells, such as fluoride shuttle batteries. The shell may protect the metal core from oxidation, including in an electrochemical cell. In some embodiments, an electrochemically active structure includes a dimensionally changeable active material forming a particle that expands or contracts upon reaction with or release of fluoride ions. One or more particles are at least partially surrounded with a fluoride-conducting encapsulant and optionally one or more voids are formed between the active material and the encapsulant using sacrificial layers or selective etching. The fluoride-conducting encapsulant may comprise one or more metals. When the electrochemically active structures are used in secondary batteries, the presence of voids can accommodate dimensional changes of the active material.

Barium-doped composite electrode materials for fluoride-ion electrochemical cells

Described herein are compositions having an eight-membered monocyclic unsaturated hydrocarbon, methods and system to separate the eight-membered monocyclic unsaturated hydrocarbon from a hydrocarbon mixture including additional nonlinear unsaturated CHm hydrocarbons with 4≤m≤8, by contacting the hydrocarbon mixture with a 10-ring pore molecular sieve having a sieving channel with a 10-ring sieving aperture with a minimum crystallographic free diameter greater than 3 Å and a ratio of the maximum crystallographic free diameter to the minimum crystallographic free diameter between 1 and 2, the molecular sieve having a T1/T2 ratio ≥20:1 wherein T1 is an element independently selected from Si and Ge, and T2 is an element independently selected from Al, B and Ga, the 10-ring pore molecular sieve further having a counterion selected from NH, Li, Na, Kand Ca.

Molecular sieves mediated unsaturated hydrocarbon separation and related compositions, materials, methods and systems

An electrochemically active structure having a core and a shell at least partially surrounding the core. Also a method of making the electrochemically active structure as described herein as well as electrochemical cells comprising the electrochemically active structure as described herein.

Electroactive materials modified with molecular thin film shell

The present disclosure relates to a method of making core-shell and yolk-shell nanoparticles, and to electrodes comprising the same. The core-shell and yolk-shell nanoparticles and electrodes comprising them are suitable for use in electrochemical cells, such as fluoride shuttle batteries. The shell may protect the metal core from oxidation, including in an electrochemical cell. In some embodiments, an electrochemically active structure includes a dimensionally changeable active material forming a particle that expands or contracts upon reaction with or release of fluoride ions. One or more particles are at least partially surrounded with a fluoride-conducting encapsulant and optionally one or more voids are formed between the active material and the encapsulant using sacrificial layers or selective etching. When the electrochemically active structures are used in secondary batteries, the presence of voids can accommodate dimensional changes of the active material.

Composite electrode materials for fluoride-ion electrochemical cells

Electrolyte solutions including at least one anhydrous fluoride salt and at least one non-aqueous solvent are presented. The fluoride salt includes an organic cation having a charge center (e.g., N, P, S, or O) that does not possess a carbon in the &#x3b2;-position or does not possess a carbon in the &#x3b2;-position having a bound hydrogen. This salt structure facilitates its ability to be made anhydrous without decomposition. Example anhydrous fluoride salts include (2,2-dimethylpropyl)trimethylammonium fluoride and bis(2,2-dimethylpropyl)dimethylammonium fluoride. Combining these fluoride salts with at least one fluorine-containing non-aqueous solvent (e.g., bis(2,2,2-trifluoroethyl)ether; (BTFE)) promotes solubility of the salt within the non-aqueous solvents. The solvent may be a mixture of at least one non-aqueous, fluorine-containing solvent and at least one other non-aqueous, fluorine or non-fluorine containing solvent (e.g., BTFE and propionitrile or dimethoxyethane). The electrolyte solutions may be employed in electrochemical cells, such as batteries, fuel cells, electrolysis systems, and capacitors.

Non-aqueous fluoride salts, solutions, and their uses

A fluoride shuttle (F-shuttle) battery and nanostructures of copper based cathode materials in the fluoride shuttle battery. The F-shuttle batteries include a liquid electrolyte, which allows the F-shuttle batteries to operate under room temperature. The minimum thickness of copper layer within the copper nanostructures is no more than 20 nm. The thickness of copper layer within the copper nanostructures is controlled and reduced to ensure the energy densities of F-shuttle batteries.

Nanostructural designs for electrode materials of fluoride ion batteries

Crosslinked polymers and related compositions and related compositions, electrochemical cells, batteries, methods and systems are described. The crosslinked polymers have at least one redox active monomeric moiety having a redox potential of 0.5 V to 3.0 V with reference to Li/Lielectrode potential under standard conditions or &#x2212;2.54 V to &#x2212;0.04 V vs. SHE and has a carbocyclic structure and at least one carbonyl group or a carboxyl group on the carbocyclic structure. The crosslinked polymers also include at least one comonomeric moiety with at least one of the at least one redox active monomeric moiety and/or the at least one comonomeric moiety has a denticity of three to six corresponding to a three to six connected network polymer, and provide stable, high capacity organic electrode materials.

Crosslinked polymers and related compositions, electrochemical cells, batteries, methods and systems

The present disclosure is directed to fluoride (F) ion batteries and F shuttle batteries comprising an anode with a solid electrolyte interphase (SEI) layer, a cathode comprising a core shell structure, and a liquid fluoride battery electrolyte. According to some aspects, the components therein enable discharge and recharge at room-temperature.

Solid electrolyte interphase (SEI) application on anode of fluoride ion/shuttle batteries

Processes and reaction mixtures including non-aqueous solvent mixtures are presented. Non-aqueous solvent mixtures including fluoride salt and non-aqueous solvent combinations are provided that possess high fluoride ion concentrations useful for a range of applications, including organic synthesis. Further non-aqueous solvent mixtures are provided including a salt possessing a non-fluoride anion and a non-aqueous solvent that, when contacted with aqueous fluoride-containing reagents, extract fluoride ions to form non-aqueous fluoride-ion solutions possessing high fluoride-ion concentrations. The salts include an organic cation that does not possess a carbon in the &#x3b2;-position or does not possess a carbon in the &#x3b2;-position having a bound hydrogen. This salt structure facilitates its ability to be made anhydrous without decomposition. Example anhydrous fluoride salts include (2,2-dimethylpropyl)trimethylammonium fluoride and bis(2,2-dimethylpropyl)dimethylammonium fluoride. The combination of these fluoride salts with at least one fluorine-containing non-aqueous solvent (e.g., bis(2,2,2-trifluoroethyl)ether; (BTFE)) promotes solubility of the salt within the non-aqueous solvents.

Organic synthesis applications of non-aqueous fluoride salt solutions

The disclosed systems and methods improve on the current landscape surrounding rewards for healthy behaviors, creates a social community around various stakeholders in the healthcare system and implements discussions around preventative medicine and healthy lifestyles. Using either a traditional network or decentralized architecture, the present system creates a community around all stakeholders and facilitates recommendations and rewards in exchange for targeted lifestyle changes, such as modifications to diet, exercise, nutrition, lifestyle, psychology, rest management, hydration, and the inclusion of vitamins and supplements. The present invention further incorporates a third party marketplace that provides incentives to patient communities for accessing information and taking active steps towards living a healthier life.

System and method for rewarding healthy behaviors and exchanging health related data

Growing community of inventors

Whittier, CA, United States of America

Simon Christopher Jones