Petrochina Company Limited

Beijing Institute of Transfusion Medicine, Academy of Military Sciences

East China University of Science

Beijing Institute of Transfusion Medicine, Academy of Military Medical Sciences

Sihan Wang

Yali Wang

Libo Wang

Xiuhui Wang

Buwei Yu

Fuling Huang

Qian Chen

Guizhi Wang

Baojun Zhang

Xuemei Han

Shukun Sun

Deshun Zhang

Tong Liu

Yan Jiang

Ning Zhang

Yulong Wang

Xianming Xu

Hongling Chu

Yuanyuan Cao

Jianzhong Li

Gang Wang

Kecun Ma

Jiabo Qu

Yunguang Han

Enhao Sun

Hongliang Huo

Yu Wang

Lei Zhang

Yanhua Li

Wei Shi

Min Liu

Jingyuan Zhang

Han Gao

Sheng Xu

Peng Wei

Yongjun Zhang

Hongxia Chen

Hua Li

Huimin Yuan

Fengrong Wang

Weihong Guan

Huaiqi Shao

Xuetao Pei

Yongcheng Sun

Yulong Li

Jingying Zhao

Hailei Yao

Wen Yue

Shubao Wan

Zhonghua Yang

Ruhai Lin

Dongmei Niu

Wenchao Zhang

Gongchen Yan

Puke Mi

Jinhua Qian

Legang Feng

Panfeng Lu

Yuxin Gao

Ling Jiang

Lingting Fan

Guiyue Guo

Xiangmin Yu

Lihua Xing

Yingnan Ning

Dongting Kuang

Shulan Wang

Yingjie Feng

Defu He

Rui Meng

Xiwu Zhao

Shuqing Liu

Yingzi Guo

Chunfeng He

Hongbo Ren

The present invention provides a low viscosity poly-&#x3b1;-olefin lubricating oil and a synthesis method thereof. The method comprises: (1) the &#x3b1;-olefin raw material is subjected to dehydration treatment so that the water content in the raw material is &#x2264;10 ppm; (2) a reaction of the dehydration treated &#x3b1;-olefin raw material is carried out in the presence of a complex catalyst and gaseous BFto obtain a reaction product, wherein the pressure of the gaseous BFis 0.01 to 1 MPa; (3) the reaction product obtained in step (2) is sequentially subjected to flash distillation, gas stripping, centrifugation, and washing treatment to obtain an intermediate product; (4) the intermediate product obtained in step (3) is subjected to distillation under reduced pressure to separate the unreacted &#x3b1;-olefin raw material and &#x3b1;-olefin dimers, and the remaining heavy fractions are subjected to hydrogenation saturation treatment followed by fractionation and cutting-off.

Low viscosity poly-a-olefin lubricating oil and synthesis method thereof

The present disclosure provides a method and a catalyst for selective oligomerization of ethylene. The raw material for the catalyst consists of a dehydropyridine annulene-type ligand, a transition metal compound, and an organometallic compound in a molar ratio of 1:0.5-100:0.1-5000. The present disclosure also provides a method for selective oligomerization of ethylene accomplished by using the above-mentioned catalyst. The catalyst for selective oligomerization of ethylene has high catalytic activity, high selectivity for the target products 1-hexene and 1-octene, and low selectivity for 1-butene and 1-C.

Method and catalyst for selective oligomerization of ethylene

Disclosed in the present invention is new use of saturated amine compounds for use in preparing medicines to resist radiation damage and promoting regeneration and repair of radiation-damaged tissues.

Method for treating or preventing radiation damage

A catalyst for synthesizing 1-hexene from ethylene trimerization and its application are provided. Said catalyst consists of (a) the compound containing P and N, (b) electron donor, (c) Cr compound, (d) carrier and (e) accelerator. The molar ratio of (a), (b), (c), (d) and (e) is 0.5-100:0.5-100:1:0.5-10:50-5000. The catalyst is prepared by mixing the components of (a)-(e) in an ethylene trimerization apparatus in situ and ethylene is introduced into the apparatus continuously. The prepared catalyst can be used to synthesize 1-hexene from ethylene trimerization in the inert solvents. The trimerization is performed at 30-150&#xb0; C. and 0.5-10.0 MPa for 0.1-4 hours. The catalyst has high catalytic activity and high 1-hexene selectivity. During the process of ethylene trimerization, by-product polyethylene does not stick to the apparatus.

Catalyst or synthesizing 1-hexene from ethylene trimerization and application thereof

A method for synthesis of 1-decene oligomer is provided, wherein 1-decene is polymerized at 80-120&#xb0; C., 0.8-1.4 MPa in the presence of aluminum trichloride catalyst supported on gamma-alumina and n-hexane solvent where the volume ratio of 1-decene to n-hexane is 3:8-4:1. The catalyst is treated as follows: impregnating gamma-alumina carrier in 0.5-2.0 M of hydrochloric acid, sulfuric acid, nitric acid or mixtures thereof, then vacuum drying at 80-100&#xb0; C. and calcining at 400-800&#xb0; C.; dissolving 5-10 g of anhydrous aluminum trichloride in 100 ml of tetrachloromethane, trichloromethane or dichloromethane solvent; adding the obtained solution into 10-20 g of activated alumina carrier and obtaining the catalyst after vacuum drying. The conversion of 1-decene is 50 wt % or more. The oligomer has a kinematic viscosity at 40&#xb0; C. of 6.0-25 mm/s and a viscosity index of 160-262.

Method for synthesis of 1-decene oligomer

The present invention relates to a catalyst composition for ethylene oligomerization and the use thereof. Such catalyst composition includes chromium compound, ligand containing P and N, activator and accelerator; wherein the chromium compound is selected from the group consisting of acetyl acetone chromium, THF-chromium chloride and Cr(2-ethylhecanoate); general formula of the ligand containing P and N is shown as: in which R, R, Rand Rare phenyl, benzyl, or naphthyl. Ris isopropyl, butyl, cyclopropyl, cyclopentyl, cyclohexyl or fluorenyl; the activatior is methyl aluminoxane, ethyl aluminoxane, propyl aluminoxane and/or butyl aluminoxane; the accelerator is selected from the group consisting of 1,1,2,2,-tetrachloroethane, 1,1,2,2-tetrabromoethane, 1,1,2,2-tetrafluoroethane, and compounds having a formula of XRX, in which Xand Xare F, Cl, Br, I or alkoxyl, Ris alkylene or arylene group; the molar ratio of chromium compound, ligand containing P and N, activator and accelerator is 1:0.5&#x2dc;10:50&#x2dc;3000:0.5&#x2dc;10. After mixing the four components mentioned previously under nitrogen atmosphere for 10 minutes, they are incorporated to the reactor, or these four components are incorporated directly into the reactor. Then ethylene is introduced for oligomerization. Such catalyst can be used in producing 1-octene through ethylene oligomerization. It is advantageous in high catalysing activity, high 1-octene selectivity, etc. The catalytic activity is more than 1.0&#xd7;10g product&#xb7;maCr&#xb7;h, the fraction of Clinear &#x3b1;-olefin is more than 70% by mass.

Catalyst composition for ethylene oligomerization and the use thereof

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Beijing, China

Sihan Wang