Other

Rutgerswerke Aktiengesellschaft

Th. Goldschmidt Ag

M. Goldschmidt Ag

Rutgerwerke Aktiengesellschaft

Siegfried Peter

Eckhard Weidner

Herbert Beneke

Gerd Brunner

Bernd A Czech

Burghard Gruning

Zhengfeng Zhang

Eckard Weidner

Martin Drescher

Wolfgang Jaumann

Ruth Ganswindt

Jurgen Stadelhofer

Manfred Recksik

Arnold Alscher

Franz Dietrich Oeste

Rudolf Oberkobusch

Manfred Meinbreckse

Joachim R Kempfert

Ulrich M Ender

Wolfgang K&ouml;nig

Zhenfeng Zhang

Rolf Riha

Georg Hartel

Wolfgang Bruckhoff

Wolfgang Fexer

Hans-Peter Neuner

Georg Haertel

Marc Seekamp

The invention relates to a process for the preparation of fatty acid esters from fats and oils of biological origin by transesterification with monohydric alcohols in the presence of basic catalysts, the catalysts being salts of a basic organic compound and carbonic acid.

Process for the transesterification of fats and oils of biological origin by means of alcoholysis using special carbonic acid salts

The present invention relates to a process for obtaining fatty acid esters from triglycerides by means of alcoholysis. In particular, the invention relates to a process for the transesterification of fat and/or oil by alcoholysis wherein, in order to accelerate the process in the initial stage, at least one alkanol fatty acid ester is added in a quantity such that the reaction mixture produced thereby consists of one phase. A high reaction rate can thereby be maintained in the process from the beginning.

Process for the transesterification of fat and/or oil by means of alcoholysis

A method for removing free fatty acids from fats or oils of biological origin or their steam distillates by extracting the free fatty acids with a mixture of basic organic nitrogen compounds and water as an extraction medium at a temperature below the boiling point of the organic nitrogen compounds. The content of the basic organic nitrogen compounds in the extraction medium is 20-30% by weight. In this manner, the formation of a viscous soapstock which is difficult to remove is prevented. The boiling point of the basic organic nitrogen compounds used is the same as or above boiling point of water and below the boiling point of the fatty acids to be extracted in order to enable simple recovery of the extraction medium.

Process for removing free fatty acids from fats and oils of biological origin or their steam distillates

A process is described for extracting carotenes from carotene-containing materials, in particular from fats and oils of biological origin, which provides for extraction of carotene-containing material with an extractant comprising at least one member selected from the group consisting of acetonitrile, N-methylpyrrolidone, N,Ndimethylformamide, N,N-dimethylacetamide, 4-formylmorpholine, 4-acetylmorpholine, 4-methylmorpholine, 4-phenylmorpholine.

Process for extracting carotenes from carotene-containing materials

Process for the transesterification of fat and/or oil of biological origin by means of alcoholysis

The invention concerns a method for producing fatty acid esters from fatty acid triglyceride and in particular from animal or vegetable fats and oils by transesterification with a monovalent low-molecular weight alcohol in the presence of a homogeneous or heterogeneous catalyst. In accordance with the invention, the formed fatty acid ester is extracted from the reaction mixture by means of a near-critical extractant. In this way fatty acid esters are obtained at high yield and excellent purity. As the extractant preferably a low pressure gas having a reduced temperature at 20&deg; C. of about 0.7, preferably of equal to or greater than 0.7, is employed. Preferred extractants are carbon dioxide, propane, butane, dimethyl ether, ethyl acetate or mixtures thereof.

Method for producing fatty acid esters

The invention relates to a method for separating alkyl glycoside mixtures or alcohol-containing alkyl glycoside mixtures by extraction, which is characterized in that the extraction is carried out with an extraction agent, which is close to or below the critical point at a reduced temperature ranging from 0.9 to 1.2, and at pressures, which are selected so that the density of the extraction agent is at least 180 kg/m.sup.3.

Method for separating alkyl glycosides

A method for synthesizing alkyl glucosides by the acetalization of sugars, particularly glucose, with alcohols in excess and subsequent separation of the excess alcohol by extraction, the extraction being carried out with an extraction agent, which is close to the critical point at a reduced pressure in the range of 0.8 to 1.3 and preferably of 0.9 to 1.2 at pressures, which are selected so that the density of the extraction agent, which is close to the critical point, is greater than 180 kg/m.sup.3.

Method of synthesizing alkyl glucosides

Process for de-oiling crude lecithin

Described is a process for removing glycerol and/or diglycerol from glycerides and glyceride mixtures by extraction, which process is characterized in that the glyceride or glyceride mixture is dissolved in organic compounds which preferably contain carbonyl and hydroxyl groups, if desired in combination with hydrocarbons, and that glycerol is extracted from the resulting solution with the aid of water. Thereby glycerol concentrations in the material to be purified of 0.1 weight % or lower may be obtained in a simple manner.

Process for removing glycerol from glycerides

The invention relates to a process for recovering monoglycerides and optionally diglycerides and/or triglycerides as well as optionally glycerol from mixtures comprising glycerides and glycerol containing glycerides, respectively, by countercurrent extraction with a circulating extraction. As an extractant, forming a separate phase, there is used a hydrocarbon having a density of more than 180 kg/m.sup.3 and/or trifluoromethane having a density of more than 180 kg/m.sup.3.

Process for preparing pure monoglycerides, pure diglycerides and/or pure

A process for the extraction of oils from oil-containing solid vegetable material by means of compressed gases, wherein said vegetable material is extracted with a mixture consisting of a supercritical gas and a subcritical entraining agent selected from the group consisting of propane, butane, pentane, ethanol, ethyl acetate, formaldehydedimethylacetal, CHF.sub.2 Cl and mixtures thereof, wherein the conditions of pressure, temperature and composition are selected so as to form a single fluid phase in said mixture of oil, supercritical gas and subcritical entraining agent, said extraction resulting in a loaded extractant which is separated from the extracted material in a separator and converted into an oil-rich liquid phase and a gaseous oil-exhausted phase in a regenerator by temperature increase and/or pressure decrease and said oil-rich phase and said oil-exhausted phase are separated and the oil-rich phase is pressure relieved, whereupon, if desired, the entraining agent remaining in the obtained oil is recovered.

Process for the extraction of oil containing vegetable materials

COS, CS.sub.2, mercaptan, SH.sub.2, SOX and/or NOX are removed from a host gas by scrubbing using a solution of a salt of Scandium, Yttrium, an element of the Lanthanide or Actinium groups or blends thereof in water or in organic solvent.

Decontamination of gases by scrubbing

In a process for the production of carbon fibers from high boiling bituminous substances in which a purified and polymerized concentrated carbon fiber precursor is spun into fibers which are oxidized and then carbonized and optionally graphitized, the improvement comprising just before spinning a supercritical gas is dissolved in mesophase pitch at a pressure of 100 to 350 bars and a temperature up to 150.degree. K. below the melting temperature of the mesophase pitch to form a low viscosity melt, separating the latter into an isotropic phase and an anisotropic carbon fiber precursor and spinning the latter into fibers whereby the spinning temperature is lowered and the mesophase contact is increased due to the viscosity lowering activity of the supercritical gas.

Improved production of carbon fibers

A method of removing salts from coal tar and coal pitches comprising washing coal tar or coal pitch in a pressure container with water and a carbon dioxide containing gas at a temperature and pressure near the critical point of the gas in the optional presence of at least one member of the group consisting of a solvent and an entraining agent, removing the liquid or dissolved tar or pitch to obtain tar or pitch with a low salt content and removing the aqueous phase whereby all the resins remain in the tar or pitch.

Growing community of inventors

Uttenreuth-Weiher, Germany

Siegfried Peter