Nanjing University

Jiangsu Yongtai Environmental Science and Technology Co. Ltd.

Shujuan Zhang

Bingcai Pan

Weiming Zhang

Lu Lv

Xiaomeng Wang

Jing Wang

Xin Wang

Lei Yang

Yonghai Gan

Mengshu Wang

Xitong Liu

Jiyuan Jin

Yanying Chen

Bingdang Wu

Minghui Li

Wentao Zhang

Xiaojie Song

Zhihao Hang

The present disclosure provides a polyzirconium coagulant obtained by performing a controllable hydrolytic polymerization reaction on a simple zirconium salt. The polyzirconium coagulant has a good coagulation performance when removing turbidity, organic matter, phosphate, and fluoride from water body. The coagulation effluent has a low concentration of residual metal and a mild change of pH. At the same dose, compared with a simple zirconium salt and polymerized zirconium chloride with a low polymerization degree, the polyzirconium coagulant prepared by the present disclosure has a wider workable pH and dose range. Besides, compared with other metal salt coagulants, the coagulant prepared by the present disclosure has a better decontamination performance. In addition, by using the polyzirconium coagulant prepared by the present disclosure, the floc has a large size and is rapid to settle. The residual zirconium concentration is low, and pollutant removal efficiency is high.

Polyzirconium coagulant and application thereof

Disclosed is application of acetylacetone in inhibiting the growth of cyanobacteria, that is, acetylacetone is added in water disturbed with cyanobacteria, and the dosage of acetylacetone is not less than 7 mg/L to inhibit the growth of cyanobacteria. Acetylacetone inhibits the growth of cyanobacteria by inhibiting photosynthesis, has a better algicidal effect than common algaecides, is harmless to common bacteria such asandand is environmentally friendly and easy to popularize and apply.

Application of acetylacetone in inhibiting growth of cyanobacteria

The present invention provides a TiO-based coagulant and use thereof. The TiO-based coagulant is obtained by the following steps: uniformly mixing acetylacetone and ethanol and dropwise adding titanium tetrachloride to obtain a solution A; mixing deionized water and ethanol to obtain a solution B; dropwise adding solution B to solution A; stirring to obtain a sol, and then aging the sol to constant weight to obtain the TiO-based coagulant. The TiO-based coagulant can be used for treating waste water and algae-laden water. The TiO-based coagulant exhibits good coagulation effects and high stability, solves the problem of too low effluent pH caused by strong inorganic titanate acidity and is favorable to the subsequent treatment of waste water.

TiObase coagulant and its application

A method for regulating the structure and properties of the composite nanoabsorbent is provided. This method uses nanoporous chloromethylated polystyrene-divinylbenzene beads as the support material and adopts in situ precipitation method to load dissociative functional nanoparticles thereon; the composite nanoabsorbent of different absorption capacity and absorption speed can be prepared through regulating the pore structure, which is realized herein by means of starting crosslinking reactions through heating chloromethylated beads under existence of the swelling agent and the catalyst; through changing the proportions of different components in the reaction system, modes of heating and time of reaction, the polymer support with different pore structures can be prepared. This invention can successfully regulate the distribution and size of inorganic nanoparticles; the composite nanomaterials prepared by the resin of different degrees of crosslinking present different structures and properties, and the specific structure and properties can be selected in order to meet practical requirements.

Method for regulating the structure and properties of the composite nanoabsorbent

A highly active supported bimetallic nanocatalyst and its preparation method is disclosed. During the preparation, using an ion exchange or adsorption resin bearing basic functional groups as the support of the said catalyst, successively introducing the first metal precursor FeCland the second metal precursor (PdCl, NiClor CuCl) onto the resin through ion exchange process; then under the protection of nitrogen gas, simultaneously reducing the two metals with either NaBHor KBH; washing the resulting material with deoxygenated water and drying it, and the said catalyst is therefore obtained. The supported bimetallic material is characteristic of independent distribution of the two metals within the support. The independently distributed structure of the two metals enhances the catalytic efficiency of the second metal and the catalytic stability.

Supported bimetallic nanocomposite catalyst and the preparation method thereof

A method for treatment of dye wastewater by using ultraviolet-acetylacetone oxidation process is provided. This method belongs to the field of dye wastewater treatment, comprising the following steps: A) adding acetylacetone into dye-containing water, stirring and mixing them completely; B) putting the liquid obtained in step A) under ultraviolet irradiation till it is effectively decolorized. Provided is a new method for decolorizing high-concentrated dye wastewater on the basis of ultraviolet-induced oxidation process of phydroxyl radicals. This method can realize complete decolorization of the dye wastewater. During the oxidation process, the dye in the wastewater acts as the photosensitizer and can accelerate the decolorization process as the reaction progresses. The method can also improve BOD5/COD ratio from lower than 0.1 to higher than 0.3, which means that this method can be used not only for high-efficient decolorization of dye wastewater, but also as a preliminary step of microorganism treatment.

Method for treatment of dyeing wastewater by using UV/acetylacetone oxidation process

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Nanjing, China

Shujuan Zhang