Mitsubishi Gas Chemical Company, Inc.

Shota Arakawa

Takashi Kashiba

Shun Ogawa

Kenichiro Usuda

Satoshi Okada

Takafumi Oda

Ryoji Otaki

Takeshi Hirokane

Fumihiro Ito

Shinichi Ikeda

Kentaro Ishii

Shinpei Iwamoto

Toshiya Takagi

Takumi Toida

Ryuji Hasemi

Tsuneaki Masuda

Hiroyuki Matsushita

Haruka Okazaki

Toshiya Naito

Hasemi Ryuji

A manufacturing method of a multilayer syringe barrel is provided and includes: a finish cutting a remaining gate of a nozzle portion of a multilayer syringe barrel that is injection-molded from a nozzle tip, with a cutting blade of an ultrasonic cutting apparatus including a mechanism for suppressing abnormal vibration; and irradiating a laser beam to a corner portion of the nozzle portion, the corner portion being formed during the finish cutting.

Manufacturing method of multilayer syringe barrel

Provided is a multilayer vessel excellent in gas barrier performance and transparency and its application. The multilayer vessel contains a layer (X) that contains at least one type of polyolefin resin as the major ingredient; and a layer (Y) that contains a polyamide resin (A) as the major ingredient, the polyamide resin (A) being composed of a structural unit derived from diamine, and a structural unit derived from dicarboxylic acid, 70 mol % or more of the structural unit derived from diamine being derived from metaxylylenediamine, meanwhile 30 to 60 mol % of the structural unit derived from dicarboxylic acid being derived from straight chain aliphatic α,ω-dicarboxylic acid having 4 to 20 carbon atoms, and 70 to 40 mol % being derived from isophthalic acid.

Multilayer vessel, and application thereof

An oxygen absorbing multilayer container having at least three layers of a first resin layer containing a thermoplastic resin, an oxygen absorbing layer containing an oxygen absorbing resin composition which contains a polyester compound (a) containing a constituent unit having a tetralin ring and a transition metal catalyst, and a second resin layer containing the same type of thermoplastic resin as the thermoplastic resin contained in the first resin layer, in this order, in which a cycloolefin polymer having a glass transition temperature of 50 to 110&#xb0; C. is contained as the thermoplastic resin.

Oxygen absorbing multilayer container and method for producing the same

Provided is an oxygen-absorbing multilayer body including an oxygen-absorbing layer containing an oxygen-absorbing composition and a thermoplastic resin layer containing a thermoplastic resin (b), wherein the oxygen-absorbing composition includes at least one compound having a tetralin ring represented by Formula (1), a transition metal catalyst, and a thermoplastic resin (a). 

Oxygen-absorbing multilayer body, oxygen-absorbing container, oxygen-absorbing airtight container, oxygen-absorbing push-through pack, and storage method using same

Oxygen-absorbing resin composition, not responsive to a metal detector, producing no odor after absorption of oxygen and has excellent oxygen-absorbing performance in a wide range of humidity conditions from low to high humidity. An oxygen-absorbing molded article, and a multilayer body, container, injection-molded article and medical containers also provided. The oxygen absorbing resin composition contains a polyester, comprising at least one constituent unit having a tetralin ring component compound, a transition metal catalyst, and a catalyst for producing the polyester. The oxygen-absorbing molded article of the present invention can be formed by molding the oxygen-absorbing resin composition into a film or a sheet. The multilayer body, container, injection-molded article, medical container, etc. of the present invention are obtained by using the oxygen-absorbing resin composition.

Oxygen-absorbing resin composition and oxygen-absorbing molded article using same and multilayer body, container, injection-molded article and medical container using these

Provided is an oxygen-absorbing medical multilayer container including at least three layers including a first resin layer containing a thermoplastic resin (b1), an oxygen-absorbing layer containing an oxygen-absorbing composition, and a second resin layer containing a thermoplastic resin (b2), in this order, where the oxygen-absorbing composition contains at least one compound having a tetralin ring represented by Formula (1), a transition metal catalyst, and a thermoplastic resin (a).

Oxygen-absorbing medical multilayer container and method for storing biological medicine

Provided are a novel oxygen-absorbing resin composition not responsive to a metal detector, producing no odor after absorption of oxygen and having excellent oxygen-absorbing performance, and a multilayer body, container, injection-molded article and medical container using these. Further provided are an oxygen-absorbing resin composition etc. having excellent oxygen-absorbing performance in a wide range of humidity conditions from low humidity to high humidity. The oxygen-absorbing resin composition of the present invention is an oxygen-absorbing resin composition containing a polyamide compound and a transition metal catalyst, wherein the polyamide compound has at least one constituent unit having a tetralin ring. Moreover, the multilayer body, container, injection-molded article, medical container, etc. of the present invention are obtained by using the oxygen-absorbing resin composition of the present invention.

Oxygen-absorbing resin composition, and multilayer body, container, injection-molded body, and medical container using same

A multilayer injection molded article containing a layer (X) formed of a resin composition containing a polyamide compound (A) and a resin (B), and a layer (Y) containing a resin (C) as a major component, wherein the polyamide compound (A) contains from 25 to 50% by mol of a diamine unit, which contains a particular diamine unit in an amount of 50% by mol or more; from 25 to 50% by mol of a dicarboxylic acid unit, which contains a particular dicarboxylic acid unit in an amount of 50% by mol or more; and from 0.1 to 50% by mol of a particular constitutional unit.

Multilayer injection-molded body

Provided is a novel oxygen-absorbing resin composition having excellent oxygen-absorbing performance and suppressing odor generation after absorption of oxygen even if a material responsive to a metal detector is not used. Further provided is an oxygen-absorbing resin composition having excellent oxygen-absorbing performance in a wide range of humidity conditions from low humidity to high humidity. Such an oxygen-absorbing resin composition contains a copolymerized polyolefin compound and a transition metal catalyst, in which the copolymerized polyolefin compound contains at least one constituent unit having a tetralin ring.

Oxygen-absorbing resin composition and oxygen-absorbing multilayer body using same, and molded article and medical container using these

An injection molded article containing a resin composition containing a polyamide compound (A) and a resin (B), wherein the polyamide compound (A) contains from 25 to 50% by mol of a diamine unit, which contains a particular diamine unit, in an amount of 50% by mol or more; from 25 to 50% by mol of a dicarboxylic acid unit, which contains a particular dicarboxylic acid unit, in an amount of 50% by mol or more; and from 0.1 to 50% by mol of a particular constitutional unit.

Injection-molded body

A multilayer injection molded article containing a layer (A) containing a polyamide resin (A), and a layer (B) containing a resin (B) as a major component, wherein the polyamide resin (A) contains from 25 to 50% by mol of a diamine unit, which contains a particular diamine unit in an amount of 50% by mol or more; from 25 to 50% by mol of a dicarboxylic acid unit, which contains a particular dicarboxylic acid unit in an amount of 50% by mol or more; and from 0.1 to 50% by mol of a particular constitutional unit.

A polyamide compound containing: from 25 to 50 mol % of a diamine unit, which contains an aromatic diamine unit represented by the following formula (I), in an amount of 50 mol % or more; from 25 to 50 mol % of a dicarboxylic acid unit, which contains a linear aliphatic dicarboxylic acid unit represented by the following formula (II-1) and/or an aromatic dicarboxylic acid unit represented by the following formula (II-2), in an amount in total of 50 mol % or more; and from 0.1 to 50 mol % of a constitutional unit represented by the following formula (III): wherein n represents an integer of from 2 to 18, Ar represents an arylene group, and R represents a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group.

Polyamide compound

A polyamide composition containing a polyamide compound (A) and a transition metal compound (B), wherein the polyamide compound (A) contains: from 25 to 50 mol % of a diamine unit, which contains at least one diamine unit selected from the group consisting of an aromatic diamine unit represented by the following formula (I-1), an alicyclic diamine unit represented by the following formula (I-2) and a linear aliphatic diamine unit represented by the following formula (I-3), in an amount in total of 50% by mol or more; from 25 to 50 mol % of a dicarboxylic acid unit, which contains a linear aliphatic dicarboxylic acid unit represented by the following formula (II-1) and/or an aromatic dicarboxylic acid unit represented by the following formula (II-2), in an amount in total of 50% by mol or more; and from 0.1 to 50 mol % of a constitutional unit represented by the following formula (III): wherein m represents an integer of from 2 to 18, n represents from 2 to 18, Ar represents an arylene group, and R represents a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group.

Growing community of inventors

Kanagawa, Japan

Shota Arakawa