Dai Nippon Printing Co., Ltd.

Shohei Itami

Yoshihiro Kishimoto

Azusa Suzuki

Yasunari Iio

Kanari Aono

Provided are: a laminate film which is equipped with a vapor-deposited aluminum oxide film exhibiting high barrier performance and excellent so-called retort resistance, and also exhibits favorable adhesion between the vapor-deposited aluminum oxide film and a plastic substrate even after undergoing a hydrothermal treatment; a barrier laminate film containing the laminate film; and a barrier packaging material which uses the barrier laminate film. A laminate film exhibiting improved adhesion strength and barrier performance, wherein: a transition region prescribing adhesion strength is formed between the surface of the substrate film and the vapor-deposited film which primarily comprises the formed vapor-deposited aluminum oxide film, by subjecting the vapor-deposited aluminum oxide film of the laminate film to a time-of-flight secondary ion mass spectrometry (TOF-SIMS) method using a Cs (cesium) ion gun; the transition region contains elementally bonded AlOH, which can be modified into aluminum hydroxide which can be detected by etching using TOF-SIMS; and the rate of modification in the transition region into aluminum hydroxide, which is defined as the ratio of the modified transition region to the vapor-deposited aluminum oxide film specified by carrying out etching using TOF-SIMS, is prescribed to be 5-60%, inclusive.

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Tokyo, Japan

Shohei Itami