Toyota Jidosha Kabushiki Kaisha

Cataler Corporation

Shogo Shirakawa

Masahide Miura

Isao Chinzei

Norimichi Shimano

Isao Naito

Hiroki Nihashi

Seiji Nakahigashi

Takahiro Nishio

Hiromi Togashi

Hiromasa Suzuki

Mitsuyoshi Okada

Takashi Onozuka

Souta Akiyama

Tsuyoshi Okada

Masaru Kakinohana

Sho Hoshino

Nobuyuki Takagi

Minoru Ito

Masashi Nose

Naoto Nagata

Tomomasa Aikawa

Kimiyasu Ono

Yuriko Takahashi

Fukutaroh Mori

Takumi Tojo

Takahiro Noguchi

Shogo Kawamura

Naoto Fujita

Taizo Yoshinaga

Daichi Sato

Tatsuya Miyazaki

Yosuke Toda

Yuki Kido

Yui Kamada

Shin Nakayama

Shun Sakamoto

A supported catalyst particles include oxide carrier particles and noble metal particles supported on the oxide carrier particles, wherein the mass of the noble metal particles is less than or equal to 5 mass % based on the mass of the oxide carrier particles, and the average particle size of the noble metal particles measured by transmission electron microscopy is 1.0-2.0 nm, with the standard deviation σ less than or equal to 0.8 nm.

Supported catalyst particles

Provided is an exhaust gas purification catalyst capable of reducing a noble metal amount while maintaining a catalyst performance, which comprises a substrate and at least three catalyst coating layers formed on the substrate, the first and third catalyst coating layers contain Pd as a catalyst metal and are formed in a range of a predetermined length from an upstream end surface in an exhaust gas flow direction, and the second catalyst coating layer contains Rh as a catalyst metal and is formed in a range of a predetermined length from a downstream end surface in the exhaust gas flow direction.

Exhaust gas purification catalyst

The present disclosure provides an exhaust gas purification catalyst having improved durability, which comprises a substrate and a catalyst coat layer formed on the substrate, the catalyst coat layer having a two-layer structure, wherein the catalyst coat layer includes an upstream portion on an upstream side and a downstream portion on a downstream side in an exhaust gas flow direction, and a part or all of the upstream portion is formed on a part of the downstream portion, wherein the downstream portion contains Rh fine particles, and wherein the Rh fine particles have an average particle size measured by a transmission electron microscope observation of 1.0 nm or more to 2.0 nm or less, and a standard deviation &#x3c3; of the particle size of 0.8 nm or less.

The present disclosure provides an exhaust gas purification material and an exhaust gas purification device that can efficiently remove harmful components even after being exposed to high temperature. Such exhaust gas purification material comprises metal oxide particles and noble metal particles supported on the metal oxide particles. The noble metal particles have a particle size distribution with a mean of 1.5 nm and 18 nm and a standard deviation of less than 1.6 nm.

Exhaust gas purification material and exhaust gas purification device

The present disclosure provides an exhaust gas purification catalyst having an improved Rh activation, which comprises a substrate and a catalyst coat layer formed on the substrate, the catalyst coat layer having a two-layer structure, wherein the catalyst coat layer includes an upstream portion on an upstream side and a downstream portion on a downstream side in an exhaust gas flow direction, and a part or all of the upstream portion is formed on a part of the downstream portion, wherein the upstream portion contains Rh fine particles and Pt, wherein the Rh fine particles have an average particle size measured by a transmission electron microscope observation of 1.0 nm or more to 2.0 nm or less, and a standard deviation &#x3c3; of the particle size of 0.8 nm or less, and wherein the downstream portion contains Rh.

An exhaust gas purification device includes a substrate including an upstream end and a downstream end and having a length Ls; a first containing Pd particles, extending between the upstream end and a first position, and being in contact with the substrate; a second containing Rh particles, extending between the downstream end and a second position, and being in contact with the substrate; and a third catalyst layer containing Rh particles, extending between the upstream end and a third position, and being in contact with at least the first catalyst layer, wherein an average of a Rh particle size distribution is from 1.0 to 2.0 nm, and a standard deviation of the Rh particle size distribution is 0.8 nm or less in each of the second catalyst layer and the third catalyst layer.

Exhaust gas purification device

The present disclosure relates to an exhaust gas control catalyst including a base and a catalyst coating layer having a two-layer structure on the base. The catalyst coating layer includes a lower layer on the base, and an upper layer on the lower layer. The upper layer of the catalyst coating layer contains Rh particles in which a mean particle diameter measured by observation using a transmission electron microscope is 1.0 nm or more and 2.0 nm or less and a particle-diameter standard deviation &#x3c3; is 0.8 nm or less. A length of the upper layer from an end face on a downstream side in an exhaust gas flow direction falls within a range of 70% or more and 100% or less of a total length of the base.

Exhaust gas control catalyst

The present disclosure provides an exhaust gas purification catalyst having an improved low-temperature activity, which comprises a substrate and a catalyst coat layer formed on the substrate, wherein the catalyst coat layer contains Rh fine particles and a promoter comprising a Ce&#x2014;Zr-based composite oxide and a Zr-based composite oxide not containing cerium oxide, wherein the Rh fine particles have an average particle size measured by a transmission electron microscope observation of 1.0 nm or more to 2.0 nm or less, and a standard deviation &#x3c3; of the particle size of 0.8 nm or less, and wherein the Rh fine particles are supported on each of the Ce&#x2014;Zr-based composite oxide and the Zr-based composite oxide not containing cerium oxide.

A reuse evaluation system is a system that performs an evaluation to reuse a catalyst in a state where the catalyst that purifies an exhaust gas of an engine of a vehicleis mounted on the vehicle. The reuse evaluation system includes a deterioration estimator that estimates a degree of deterioration of the catalyst based on an operating state of the vehicle, a reuse setting unit that sets a range of the degree of deterioration of the catalyst as a reuse range of the catalyst according to a usage of reuse of the catalyst, and a reuse determining unit that determines that the catalyst is reusable in the reuse usages when the degree of deterioration of the catalyst estimated by the deterioration estimator is within the reuse range set by the reuse setting unit.

Reuse evaluation system for catalyst

A method for reusing a vehicular catalyst that ensures effective reuse of a catalyst discarded when a vehicle is discarded is provided. A catalyst deterioration level of a catalytic converter is diagnosed, a catalyst that has a value of the deterioration level diagnosed to be smaller than a predetermined value is determined as a reusable catalyst, and the catalytic converter that includes the catalyst determined as the reusable catalyst is removed from a discarded vehicle. The removed catalytic converter is stored in association with a vehicle type and a manufacturing time of the discarded vehicle. When an abnormality occurs in a catalyst of a drivable vehicle corresponding to the vehicle type and the manufacturing time, a catalytic converter that includes the abnormal catalyst is replaced with the stored catalytic converter.

Method for reusing vehicular catalyst

The present disclosure provides a method for producing an exhaust gas purifying catalyst, in which fine Rh&#x2014;Pd particles exhibiting high catalytic activity are produced such that a variation in the Pd composition can be reduced. The present disclosure relates to a method for producing an exhaust gas purifying catalyst having fine composite metal particles containing Rh and Pd, comprising: preparing a starting material solution containing Rh and Pd, in which the atomic percentage of Pd to the total of Rh and Pd is 1 atomic % to 15 atomic %; and allowing the prepared starting material solution to react with a neutralizer by a super agitation reactor having a rotation number of 500 rpm or more, to generate fine composite metal particles.

Method for producing exhaust gas purifying catalyst and exhaust gas purifying catalyst

An object of the present invention is to provide an exhaust gas purification catalyst for purifying exhaust gas, in particular, fine composite-metal particles contained therein, and a method for producing the same; the exhaust gas purification catalyst according to the present invention includes fine composite-metal particles containing Rh and Pd, wherein, when the fine composite-metal particles in the exhaust gas purification catalyst are analyzed by STEM-EDX, the average ratio of the amount of Pd with respect to the total amount of Rh and Pd in the fine composite-metal particles is 1.7 atomic % or more and 24.8 atomic % or less.

Exhaust gas purification catalyst and method for producing the same

The purpose of the present invention is to provide an exhaust gas purification catalyst which can decrease a NOx reduction temperature and comprises rhodium and gold. An exhaust gas purification catalyst which carries two-element microparticles each comprising rhodium and gold, said catalyst being characterized in that the rhodium and the gold are phase-separated from each other and the content ratio of the rhodium to the gold (i.e., rhodium:gold) is (30-99.9 at. %):(70-0.1 at. %) in the two-element microparticles.

Exhaust gas purification catalyst and method for producing it

Provided are metal particles comprising an at least partial solid solution of rhodium and gold. Also provided is a method for producing metal particles comprising adding a boron-based reducing agent to a mixed solution containing a rhodium salt and a gold salt to produce the metal particles comprising an at least partial solid solution of rhodium and gold. Furthermore, provided are an exhaust gas purifying catalyst comprising the metal particles supported on a catalyst support and a method for producing the same.

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Toyota, Japan

Shogo Shirakawa