Ausimont Usa, Inc.

Solvay Solexis, Inc.

Solvay Sa

Solvay Specialty Polymers Italy S.p.a.

Solvay Solexis S.p.a.

Shiow-Ching Lin

Bradley Lane Kent

Michelle Kelly

Craig Norman Kamsler

Steven John Burks

Giuseppe Marchionni

Vincenzo Arcella

Marco Avataneo

Eliana Ieva

Karol Argasinski

Ping-Tsung Huang

Eli M Pearce

Michael Coates

A composition comprising at least one vinylidene fluoride (VDF) polymer [polymer (F)]; and inorganic particles at least partially coated with at least one perfluoropolyether block copolymer [polymer (E)] comprising: A) one or more (per)fluoropolyoxyalkylene segment (chain R), comprising recurring units having at least one catenary ether bond and at least one fluorocarbon moiety, and B) one or more polyalkylene segment (chain R) comprising recurring units of formula: &#x2014;(CRR&#x2014;CRR)&#x2014;, wherein R, R, R, R, equal to or different from each other, are selected from the group consisting of H, halogens (preferably F, Cl); C-C(hydro)carbon groups, optionally containing fluorine or other heteroatoms, referably perfluoroalkyl or (per)fluorooxyalkyl. The invention also discloses a method of coating various substrates using said composition.

PVDF coating composition

Coating composition

A process for making pigmented PVDF-based powder coatings by coagulation and powder based coatings made by the process. The process involves blending a PVDF latex and a water reducible acrylic polymer and pigment dispersion, adding coagulant to precipitate solid PVDF and pigment associated by ionic interaction with acrylic polymer binder, separating solids and drying the precipitate. Also, methods for coating substrates with the powder coating and coated substrates.

Precipitation process for making polyvinylidene fluoride powder coatings and coatings made by the process

A weather resistant coating composition comprising a miscible polymer blend of highly crystalline polyvinylidene fluoride polymer and polyalkyl methacrylate, such as PVDF and PMMA. The miscible blend comprises from about 50 weight percent to about 90 weight percent polymer comprising polyvinylidene fluoride and from about 10 weight percent to about 50 weight percent polyalkyl methacrylate. The polyalkyl methacrylate having a molecular weight within the range of about 25,000 grams per mole to about 200,000 grams per mole. The crystallinity of the polyvinylidene fluoride polymer is about 20% to about 70%. The weather resistant coating has excellent and unexpected physical characteristics, including solvent resistance and gloss retention.

Polyvinylidene fluoride weather resistant coating compositions including polymethyl methacrylate

A process for making a PVDF-based powder coating compositions using a co-coagulation process and compositions comprising co-coagulated PVDF, co-coagulated PVDF-based powder coating compositions and substances coated with these compositions. Vinylidene fluoride polymer latex compositions are mixed with compatible thermoplastic polymer latex, such as acrylic polymer latex, and a coagulant is added. The coagulant precipitates the vinylidene fluoride and polymer, and the precipitant is filtered and dried forming the powder coating. The powder coating is homogenous. The coating comprises no solvents and can be applied to a number of substrates.

Process for making polyvinylidene fluoride power coatings and coating formulations

A miscible polymer blend of superior mechanical strength, hardness and abrasion or mar resistance comprising PVDF and at least one compatible aromatic polyimide. The aromatic polyimide in the miscible polymer blend acts as a nucleating agent for PVDF crystallization. The miscible polymer blend comprising PVDF and aromatic polyimide does not exhibit the negative characteristic of reduced mechanical strength encountered in PVDF and polymer alloys known in the art. The PVDF/aromatic polyimide alloy is prepared by dissolving, separately, PVDF and the aromatic polyimide in a solvent and blending the solutions to form the required composition.

Compatible blends of polyvinylidene fluoride and aromatic polyimide

A paint composition which comprises a binder component which includes a polyvinylidene fluoride polymer and a solvent component. The polyvinylidene fluoride polymer has a melt viscosity of at least 40 kPoise. Such paint compositions have low gloss and are useful as exterior weather-resistant paints for buildings where low-gloss paints are preferred.

Low-gloss paints including polyvinylidene fluoride having a high melt viscosity

A compatible blend of superior mechanical strength, hardness and abrasion or mar resistance comprising PVDF and a compatible organic polymer containing one or more imide groups. The alloy consisting of PVDF and a polymer containing imide groups is prepared by dissolving, separately, the PVDF and polymer in a solvent and blending the solutions to provide the required composition. The alloy can also be prepared by dispersing PVDF powder in a solution of polymer containing imide groups. After heating and drying, a homogeneous alloy is formed. In addition, melt extrusion of PVDF with the imide-containing polymer also generates the desired PVDF alloy.

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Lawrenceville, NJ, United States of America

Shiow-Ching Lin