Mitsubishi Gas Chemical Company, Inc.

Mitsibishi Has Chemical Company, Inc.

Shinpei Iwamoto

Satoshi Okada

Shinichi Ikeda

Fumihiro Ito

Kenichiro Usuda

Takashi Kashiba

Shun Ogawa

Toshiya Takagi

Shota Arakawa

Akihiro Masuda

Kiyonori Michiba

Oxygen-absorbing resin composition comprising a polyester containing a constitutional unit (a) comprising tetralin ring structure, for example, an alkyl tetralin dicarboxylate, wherein the alkyl component has, for example, from 2 to 6 carbon atoms, and a constitutional unit (b) derived from a polyfunctional compound, selected from glycerin, trimethylol propane, pentaerythritol, trimellitic acid, trimellitic acid anhydride, pyromellitic acid, and pyromellitic acid anhydride, and a transition metal catalyst.

Oxygen-absorbing resin composition

Provided is an oxygen-absorbing multilayer body including an oxygen-absorbing layer containing an oxygen-absorbing composition and a thermoplastic resin layer containing a thermoplastic resin (b), wherein the oxygen-absorbing composition includes at least one compound having a tetralin ring represented by Formula (1), a transition metal catalyst, and a thermoplastic resin (a). 

Oxygen-absorbing multilayer body, oxygen-absorbing container, oxygen-absorbing airtight container, oxygen-absorbing push-through pack, and storage method using same

Oxygen-absorbing resin composition, not responsive to a metal detector, producing no odor after absorption of oxygen and has excellent oxygen-absorbing performance in a wide range of humidity conditions from low to high humidity. An oxygen-absorbing molded article, and a multilayer body, container, injection-molded article and medical containers also provided. The oxygen absorbing resin composition contains a polyester, comprising at least one constituent unit having a tetralin ring component compound, a transition metal catalyst, and a catalyst for producing the polyester. The oxygen-absorbing molded article of the present invention can be formed by molding the oxygen-absorbing resin composition into a film or a sheet. The multilayer body, container, injection-molded article, medical container, etc. of the present invention are obtained by using the oxygen-absorbing resin composition.

Oxygen-absorbing resin composition and oxygen-absorbing molded article using same and multilayer body, container, injection-molded article and medical container using these

An oxygen-absorbing resin composition containing a polyester compound, and a transition metal catalyst, and wherein the polyester compound is a polyester compound having a tetralin ring obtained by synthesis using a zinc compound contained in a catalyst; the zinc compound contained in a catalyst is present together with the obtained polyester compound in the oxygen-absorbing resin composition; the transition metal catalyst is different from the zinc compound contained in a catalyst; and the oxygen-absorbing resin composition is obtained by mixing the transition metal catalyst with the polyester compound present together with the zinc compound contained in a catalyst.

Oxygen-absorbing resin composition and oxygen-absorbing multilayer injection-molded article and oxygen-absorbing multilayer container using same

The present invention provides an oxygen absorbing agent composition comprising a compound (A) having two or more tetralin rings, and a transition metal catalyst.

Oxygen absorbing agent composition and oxygen absorbing agent package

An oxygen absorbent composition which comprises a polyester oligomer containing a constitutional unit derived from a tetralin ring-containing carboxylic acid and a diol, wherein the polyester oligomer has a number average molecular weight of 500 to 10000, and a transition metal catalyst comprising at least one transition metal selected from the group consisting of manganese, iron, cobalt, nickel and copper.

Oxygen absorbent composition

Provided are a novel oxygen-absorbing resin composition not responsive to a metal detector, producing no odor after absorption of oxygen and having excellent oxygen-absorbing performance, and a multilayer body, container, injection-molded article and medical container using these. Further provided are an oxygen-absorbing resin composition etc. having excellent oxygen-absorbing performance in a wide range of humidity conditions from low humidity to high humidity. The oxygen-absorbing resin composition of the present invention is an oxygen-absorbing resin composition containing a polyamide compound and a transition metal catalyst, wherein the polyamide compound has at least one constituent unit having a tetralin ring. Moreover, the multilayer body, container, injection-molded article, medical container, etc. of the present invention are obtained by using the oxygen-absorbing resin composition of the present invention.

Oxygen-absorbing resin composition, and multilayer body, container, injection-molded body, and medical container using same

An oxygen absorbing agent composition including at least one type of a compound having an indane skeleton represented by the following general formula (1) and a transition metal catalyst: 

Oxygen absorbing agent composition

Provided is a novel oxygen-absorbing resin composition having excellent oxygen-absorbing performance and suppressing odor generation after absorption of oxygen even if a material responsive to a metal detector is not used. Further provided is an oxygen-absorbing resin composition having excellent oxygen-absorbing performance in a wide range of humidity conditions from low humidity to high humidity. Such an oxygen-absorbing resin composition contains a copolymerized polyolefin compound and a transition metal catalyst, in which the copolymerized polyolefin compound contains at least one constituent unit having a tetralin ring.

Oxygen-absorbing resin composition and oxygen-absorbing multilayer body using same, and molded article and medical container using these

The provision of an oxygen absorbent composition comprising a compound (A) having two or more tetralin rings, at least one of the tetralin rings having a hydrogen bond bonded to a benzylic position thereof, and having two or more imide bonds, and a transition metal catalyst.

Oxygen absorbent composition and molded body and package using the same

The present invention provides a sterilized oxygen-absorbing resin composition obtained by performing at least: a sterilizing step of irradiating with radiation an oxygen-absorbing resin composition containing a transition metal catalyst and a thermoplastic resin (a) having a tetralin ring as a constituent unit; and a step of heating the oxygen-absorbing resin composition at a temperature equal to or higher than the glass transition temperature of the thermoplastic resin (a) and equal to or lower than 200&#xb0; C., after the sterilizing step.

Sterilized oxygen-absorbing resin composition, sterilized oxygen-absorbing multilayer container and method for producing the same

An oxygen-absorbing resin composition copolymerized polyolefin compound including a copolymerized polyolefin compound and a transition metal catalyst, wherein the copolymerized polyolefin compound is a copolymerized polyolefin compound including at least one of constitutional unit (a) selected from the group consisting of the constitutional units represented by the general formula (1), and at least one of the constitutional unit (b) having an indane ring, selected from the group consisting of the constitutional units represented by the general formulas (2) and (3).

An oxygen-absorbing resin composition comprising a polyester compound having a constitutional unit (a), which has at least one tetralin ring selected from the group consisting of the following general formulas (1) to (4) and a constitutional unit (b) comprising residue of tetrahydrophthalic anhydride derivative which is represented by the following general formula (5) and/or general formula (6). 

The present invention provides a novel oxygen absorbent composition being capable of realizing an oxygen absorbent not responding to a metal detector, being suppressed in the increase of the odor intensity after the absorption of oxygen and having an excellent oxygen absorption performance over a wide range of humidity conditions from low humidity to high humidity, and provides an oxygen absorbent package using the oxygen absorbent composition. The oxygen absorbent composition of the present invention includes at least one compound having a tetralin ring represented by the following general formula (1) and a transition metal catalyst: 

Oxygen absorbent composition and oxygen absorbent package using the same

Provided is a resin composition which is excellent in an oxygen-absorbing performance, a resin strength and a resin processability. The oxygen-absorbing resin composition is characterized by containing a polyolefin resin, a transition metal catalyst and a polyamide resin obtained by polycondensation of aromatic diamine and dicarboxylic acid, wherein an end amino group concentration of the above polyamide resin is 30 &#x3bc;eq/g or less, and a total content of the transition metal catalyst and the polyamide resin is 15 to 60% by weight based on a whole amount of the oxygen-absorbing resin composition.

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Kanagawa, Japan

Shinpei Iwamoto