Toyota Jidosha Kabushiki Kaisha

Nippon Soken, Inc.

Shinji Tsuji

Naoto Miyoshi

Takeru Yoshida

Mikio Murachi

Yoshiharu Miyake

Kenji Kato

Kenji Katoh

Hirohito Hirata

Mareo Kimura

Takaaki Ito

Masahiko Takeuchi

Masaru Kakinohana

Oji Kuno

Nobuo Kamiya

Tatsuji Mizuno

Kazumasa Takatori

Takao Tani

Masahiko Sugiyama

Yoshitsugu Ogura

Tetsuo Kawamura

Naohisa Oyama

Shigeki Daido

Norio Taguchi

Juji Suzuki

Koichi Yamashita

Kouichi Yamashita

Hitoshi Kato

Kodo Kawase

Takayuki Shibuya

A filterfor collecting PMs, a microwave transmitterfor emitting electromagnetic waves whose frequency is dozens of GHz-a few of THz onto the filter, a microwave receiverfor detecting an intensity of the electromagnetic waves that have transmitted through the filter, and a computing means for computing a collection amount of PMs from the intensity that has been detected with the microwave receiverare included. Since it is possible to detect the distribution of the collection amount of PMs with good accuracy, it is possible to carry out a recycling process in a state where the collection amount does not become too much, and thereby it is possible to make a reducing-agent supply amount into exhaust gases minimum at the time of the recycling process.

Collection-amount detection method for particulate matters and collection-amount detection apparatus therefor and exhaust-gas converting apparatus

A NOx occluding and reducing catalystis provided in an exhaust gas passage of an engine to occlude the NOx in the exhaust gas of a lean air-fuel ratio. The engine is provided with an injector for directly injecting the fuel into the combustion chamber, and the fuel fed by a fuel pump into a common rail with pressure is injected. The additive containing a sulfur-solidifying agent that forms a solid sulfate upon the reaction with sulfur in the fuel due to combustion, is injected into the common rail from a tank due to a pump, and is supplied into the combustion chamber through the injector together with the fuel. When the condition of the atmosphere of the NOx occluding and reducing catalyst is the one where the NOx in the exhaust gas is little absorbed, the ECU adjusts the discharge amount of the pump, and decreases the amount of the additive injected into the common rail or interrupts the injection. This decreases the consumption of the sulfur-solidifying agent.

Method of purifying exhaust gas of an internal combustion engine

The present invention is a method of solidifying sulfur component being the cause of &ldquo;SOx poisoning&rdquo; by use of a sulfur solidifier. The solidifier includes a metal element having a function of oxidizing the sulfur component and a basic metal element. And the solidifier solidifies sulfur component before exhaust gas flows into an NOx-occluding reduction-type exhaust purifying catalyst located on an exhaust path. Since the foregoing sulfur solidifier includes the above metal element and the basic metal element, it can effectively solidify the sulfur component which are the cause of the SOx poisoning, and ensure improvement in purification performance.

Method of purifying exhaust gas from internal combustion engine

A noble metal composite colloid composed of a plurality of noble metals is constructed to be loaded on a porous oxide support. The noble metals are loaded in particles which are larger than the conventional grains in the atomic state. Thus, vapor pressure decreases and volatile components, such as PtO , are suppressed from dislocation or diffusion. In addition, affinity of the noble metals with the support is improved, and are suppressed from moving on the support. Thus, nobel metal grain growth is suppressed, decreases in catalytic activity is minimized and durability is improved.

Catalyst for purifying exhaust gases, a method of producing the same, and a method of purifying exhaust gases

A catalyst for purifying an exhaust gas includes a composite oxide support and a platinum structural layer. The composite oxide support has a spinel structure expressed by M.Al O in which M is an alkaline-earth metal. The platinum structural layer is formed on a surface of the composite oxide support and includes a matrix composed mainly of an alkaline-earth metal oxide in which platinum clusters are dispersed uniformly. A composite oxide layer can be interposed between the composite oxide support and the platinum structural layer. Also disclosed is an optimum process for producing the catalyst.

Catalyst for purifying an exhaust gas and process for producing the same

A catalyst for purifying an exhaust gas includes a composite oxide including gold (Au) and having crystalline unit cells in every one of which an Au ion is disposed. Since the Au exists in a state of an ion, the catalyst exhibits a good catalytic activity. Since the Au is present in such a manner that it is surrounded by the other elements, it is inhibited from moving. As a result, the catalyst is improved in terms of the heat resistance.

Catalyst for purifying an exhaust gas

A catalyst for purifying an exhaust gas includes amorphous and homogeneous composite oxide particles, a catalytic noble metal element, and metallic oxide particles. The metallic oxide particles interpose among the composite oxide particles to connect them with each other at least. The catalyst has good heat resistance, sulfur-poisoning resistance, and durability. The catalyst is produced as follows. A slurry is prepared by mixing an organosol with a suspension, or by mixing a solution with a suspension. The slurry is deposited on a support substrate to form a coating layer thereon. The suspension includes a precursor powder, and a solvent. The precursor powder includes the composite oxide particles, and the catalytic noble metal element. The composite oxide particles include a support component, and an NO,storage element. The solvent is free from elution of the NO,storage element. The organosol includes an organic solvent, and an oxide sol. The solution includes an organic solvent, and an organometallic compound. The oxide sol and organometallic compound includes aluminum, silicon or zirconium.

Catalyst for purifying exhaust gas and process for producing the same

A catalyst support, a catalyst using the catalyst support and a process for producing the same are disclosed. For instance, the catalyst support includes a composite oxide powder produced by spraying and burning a W/O type emulsion, the W/O type emulsion including an aqueous solution dispersed in an organic solvent, the aqueous solution containing aluminum as a major component and at least one co-metallic element in addition to the aluminum. Thus, the catalyst support can be produced less expensively without using any expensive alkoxide. Further, due to the spraying and burning, the composite oxide powder is composed of porous hollow particles which have a very thin shell thickness of dozens of nanometers, and makes the catalyst support which is amorphous and exhibits a large specific surface area. Hence, the catalyst support can maintain the large specific surface area even after a high-temperature durability test. Furthermore, the composite oxide powder includes the co-metallic element which is composited in such a highly dispersed manner that the agglomerated sulfates are less likely to be produced. Therefore, the catalyst support is inhibited from being poisoned by sulfur.

Catalyst support and catalyst and process for producing the same

The present invention relates to an alloy catalyst for purifying an exhaust gas, and particularly provides an alloy catalyst excellent in nitrogen oxide purification characteristics in the lean region by improving the catalytic activity by coating first catalytic metal particles with a second metal coagulated phase, and a process for producing the same, the alloy catalyst for purifying an exhaust gas having a structure in which metal coagulated phases being applied to and supported by a metal oxide, and comprising first catalytic metal particles having an average particle size of up to 30 nm, and a second metal coagulated phase containing at least one metal, differing from the catalytic metal particles, and applying to the first catalytic metal particles at a coating ratio of at least 45%, and the process for producing an alloy catalyst for purifying an exhaust gas, comprising the steps of allowing first catalytic metal particles having an average particle size of up to 30 nm to adhere onto a metal oxide, and reduction precipitating a second metal coagulated phase containing at least one metal differing from the first catalytic metal particles thereon, and comprising at least one metal selected from the group consisting of Pt, Pd, Au, Rh, Ag and Ir.

Alloy catalyst and process for producing the same

A high heat-resistant catalyst support comprises an amorphous composite oxide which is constituted by:

Method of producing heat-resistant catalyst support

This catalyst support aims to improve heat resistant and durability by highly dispersing an NO.sub.x storage component. This catalyst support is produced by mixing a solution of a chemical compound including at least one element of alkali metals, alkaline-earth metals, and rare-earth elements with a solution of oxide sol of at least one metal of group IIIb, group IVa, and group IVb in the periodic table to prepare a mixed sol solution, forming the mixed sol solution into gel, and drying and calcining the gel. The obtained catalyst support is amorphous and attains a high specific surface area even when calcined at elevated temperatures, so that the catalyst support is superior in heat resistance.

Growing community of inventors

Okazaki, Japan

Shinji Tsuji