Teijin Limited

Shingo Emi

Susumu Norota

Yasuhiko Segawa

Tsutomu Kiriyama

Tadasi Imoto

Noritsugu Saiki

Toshitsugu Matsuki

Toshinori Azumi

Tetsuo Yamauchi

Yoshito Ikada

Shoji Kawase

Shizuo Azuma

Kiyoshi Sugie

Tomoyoshi Ono

Toshiaki Harada

Shizuka Kurisu

Yasuyuki Yamazaki

Tamio Mitamura

Shoji Mizutani

Kouzi Soga

Kyoji Suzuki

Kazuo Takamatu

Kouji Soga

Yasuhiko Sagawa

Satoshi Fukuhara

A selectively permeable hollow fiber membrane for blood dialysis consisting substantially of a cellulose derivative, which has at least a dense layer on the innermost side and a porous layer of greater void percentage on the outside, and a process for producing the selectively permeable hollow fiber membrane consisting substantially of a cellulose derivative, which comprises extruding a spinning solution containing a polymer consisting substantially of a cellulose derivative dissolved in an organic solvent, from an annular slit into a filamentous form, while simultaneously introducing a core material solution with a water content of at least 50 wt % into the extruded filamentous body, and then immersing the filamentous body into a coagulating solution after passing it through a gas.

Selectively permeable hollow fiber membrane and process for producing

Hollow fiber blood purifying membrane and process for its production

A cellulosic polymer wherein at least a part of the hydroxyl groups of the cellulosic polymer is modified as represented by the following general formula [I]: ##STR1## wherein R.sup.1 and R.sup.2 may be the same or different and each represents a hydrogen atom or a C.sub.1 to C.sub.5 alkyl group, X is a strong negative atomic group, and Y is ##STR2## wherein R.sup.3 and R.sup.4 may be the same or different and each represents a member selected from the group consisting of a hydrogen atom, a C.sub.1 to C.sub.5 alkyl group and a C.sub.3 to C.sub.6 cycloalkyl group, or ##STR3## Y is wherein R.sup.5, R.sup.6 and R.sup.7 may be the same or different and each represents a member selected from the group consisting of a hydrogen atom, a C.sub.1 to C.sub.5 alkyl group, a C.sub.3 to C.sub.6 cycloalkyl group and a C.sub.6 to C.sub.10 aryl group, and n is from 1 to 10. Using the cellulosic polymer, a blood-treating device is assembled.

Cellulosic polymer, blood-treating device, and process for producing the

A phosphazene polymer carrier is prepared that has functional groups capable of binding a biologically active substance such as an enzyme or antibody and groups which are non-reactive and hydrophilic. A bifunctional aldehyde is reacted with primary amino groups of a shaped phosphazene polymer to form side chains having aldehyde groups, an amino group-containing compound is reacted with a portion of the aldehyde groups to produce the groups that are non-reactive and hydrophilic, and aldehyde groups not reacted are capable of binding a biologically active substance. The phosphazene polymer may be crosslinked prior to reacting with the bifunctional aldehyde. In another embodiment, a protecting agent is reacted with a portion of the aldehyde groups to block the aldehyde groups, imino bonds are reduced, a compound having an amino group is reacted with aldehyde groups not blocked to form the groups which are non-reactive and hydrophilic, and the protecting agent is removed to provide aldehyde groups capable of binding a biologically active substance. The non-reactive and hydrophilic groups may also be formed by reacting primary amino groups with formaldehyde or by diazotizing primary amino groups of the polymer followed by hydrolysis to form hydroxyl groups. A biologically active substance immobilized on the polymer can be used to separate a substance that has affinity for the immobilized biologically active substance.

Immobilization of biologically active substances with a polyphosphazene

A phosphazene polymer for immobilizing biologically active substances such as enzymes is prepared that does not lower activity originally possessed by the biologically active substance and does not contain a functionality which can adsorb undesired substances. The polymer has organic radicals having a functional group capable of binding a biologically active substance and organic radicals which are non-reactive and hydrophilic. The non-reactive and hydrophilic organic radicals are preferably prepared by reacting a side chain of the polymer having a primary amino group with formaldehyde or by diazotizing the primary amino group followed by hydrolysis to form a hydroxyl group. A biologically active substance immobilized on the polymer can be used to separate a substance that has affinity for the immobilized biologically active substance.

Phosphazene polymer for immobilizing biologically active substances

An anti-fungus, deodorant fiber material comprises synthetic polymer fibers, a deodorant material in an amount of 8% by weight or more and consisting of an ethylene-ethylenically unsaturated carboxylic acid copolymer, and an anti-fungus material in an amount of 1% by weight or more and consisting of fine copper particles preferably having a size of 50 mesh or smaller, and the deodorant material and the anti-fungus material are contained together in the synthetic fibers or the deodorant material is contained in one type of synthetic fibers and the anti-fungus material is separately contained in another type of synthetic fibers.

Anti-fungus, deodorant fiber material

An assembly of fibers composed of at least two dissimilar fiber-forming polymers, characterized by the fact that

Process for producing an assembly of many fibers

Pneumatic cellular aromatic polyamide articles characterized by

Pneumatic cellular aromatic polyamide articles and process for the

A process and apparatus for producing a fibrous assembly. At least one fiber-forming polymer is extruded through a spinneret having numerous small openings. The process uses a die equipped with a spinneret having numerous closely spaced small openings and an opening ratio (.alpha.) of at least 30%. At least one fiber-forming polymer in the form of a shaped mass having a specified compression resistance is continuously stuffed into said die. Said shaped mass has a shape such that it measures more in one direction than in another. There is passed through the spinneret an electric current sufficient to give said fiber-forming polymer Joule heat required for cutting said polymer by partitioning members defining the numerous small openings of the spinneret. The cut fiber-forming polymer is taken up as fine streams. The present invention provides ultrathick aromatic polyamide fibers having an average cross-sectional area of about 0.01 mm.sup.2 to about 5 mm.sup.2 and comprising at least one fiber-forming aromatic polyamide and an inorganic or metallic fine powder or a fibrous material.

Process for producing fibrous assembly

Novel assembly of composite fibers

The present invention provides a process for producing a fibrous assembly, which comprises extruding a melt of a fiber-forming polymer through a mesh spinneret, said spinneret including many closely arranged small openings and having an opening ratio (.alpha.), represented by the following formula, of at least about 10% ##EQU1## V.sub.a is the total apparent volume of the spinneret which is taken within a unit area of its mesh portion, and V.sub.f is the total volume of partitioning members defining the small openings which is taken within a unit area of the mesh portion of the spinneret; said extrusion being carried out while generating Joule heat in the partitioning members of the spinneret and cooling the vicinity of the extrusion surface of the spinneret by supplying a cooling fluid, whereby the melt is stably converted into fine streams by the partitioning members; and taking up and solidifying the fine streams; and also provides the process wherein the extrusion surface of the spinneret is turned upward so that the normal vector of the extruding surface is reverse to the direction of gravity, and the fine streams extruded from the extrusion surface are taken up against gravity. The present invention provides a molding apparatus for production of a fibrous assembly having a mesh spinneret which has many closely arranged small openings having an opening ratio .alpha. defined by the above formula of at least 10% and the extrusion surface of the spinneret being turned upwardly such that the normal vector of the extrusion surface is reverse to the direction of gravity.

Process for producing a fibrous assembly

A composite sheet structure comprising (A) a nonwoven web composed of (a) continuous filaments of a synthetic resin and (B) a net-like web having intersecting points and being composed of (b) continuous net strands of a mixture consisting of at least two thermoplastic synthetic resins having different melting points, said web (A) and said web (B) being bonded to each other by heating; characterized in that (i) said web (A) has a basis weight of about 2 to about 30 g/m.sup.2, (ii) said web (B) has a basis weight of about 1 to 10 g/m.sup.2, an average net strand diameter of about 1 to about 100 microns, and an average mesh length of up to about 5 mm, and said net strands (b) are composed of at least two resins having melting points differing from each other by at least about 20.degree. C., of which a resin having the lowest melting point has a melting point at least about 20.degree. C. lower than that of said filaments (a) and is present in an amount of about 5 to about 95% by weight based on the weight of said resin mixture, (iii) the amount of said web (A) is about 30 to about 90% by weight based on the total weight of said webs (A) and (B), (iv) said composite sheet structure has a basis weight of about 10 to about 200 g/m.sup.2, and (v) said filaments (a) are partly embraced by said net strands (b) throughout the composite sheet structure.

Composite sheet structure

A fibrous composite comprising a coalesced assembly of (A) a sheet-like mesh structure composed of fibers of a synthetic elastomeric polymer, the individual fibers being interconnected at random in irregular spaced-apart relationship thereby forming a number of meshes of different shapes and sizes, said mesh structure having a recovery ratio after 10% stretch of at least 70% in two arbitrarily selected, mutually perpendicular directions on the plane of said mesh structure, and (B) a mat-, web- or sheet-like fibrous structure composed of short or long fibers, said fibrous structure having a recovery ratio after 10% stretch of less than 50% in at least one arbitrarily selected direction. An elastic fibrous composite of this invention is suitable as various apparel base materials and industrial materials such as filter clothes, adsorbents, and heat insulating materials.

Fibrous composite having elasticity

A novel composition comprising 100 parts by weight of an aromatic polyester, 5 to 150 parts by weight of powdery feldspar and optionally 5 to 120 parts by weight of a plate-like inorganic filler such as glass flakes and/or 1 to 100 parts by weight of a rubbery elastomer such as acrylic rubber. Up to a half of the powdery feldspar may be replaced by another pulverulent inorganic filler such as talc. The composition is useful as engineering plastics because it gives molded articles having high impact strength and heat distortion temperatures and reduced warping.

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Iwakuni, Japan

Shingo Emi