Kanegafuchi Kagaku Kogyo Kabushiki Kaisha

Shigeru Kobayashi

Ko Kozuka

Taizo Yasumoto

Shunichiro Kurioka

Atsuo Kubota

Nobumasa Otoshi

Masaaki Yokoe

Yoshio Iki

Munehiro Nakamura

Akira Watanabe

A process for preparing modified polyolefin particles which comprises dispersing cross-linked polyolefin particles and a polymerizable vinyl monomer capable of dissolving or swelling the cross-linked polyolefin particles in an aqueous medium, impregnating the cross-linked polyolefin particles with the vinyl monomer and polymerizing the vinyl monomer. The obtained modified polyolefin particles can provide a foamed article including uniform and fine cells and having excellent toughness, accuracy of demension, cushioning property, heat resistance and smooth and soft surface.

Process for preparing modified polyolefin particles and foamed article

A method of manufacturing acrylic fibers free from delustering in boiling water, comprises the steps of forming a spinning solution by dissolving in a solvent of acetone, acetonitrile, dimethylformamide and mixtures thereof, (a) a copolymer consisting of (1) 30 - 80% acrylonitril and (2) 70 - 20% vinyl chloride or vinylidenechloride, or (b) a tripolymer consisting of (1), (2) and (3) 3.0% or less by weight of ethylenically unsaturated monomer having hydrophilic groups, and adding one or more compound selected from the group of (1) homopolymer or copolymer of glycidyl methacrylate and (2) specific organic tin compounds, and spinning said spinning solution into a first bath consisting of 60% or less said organic solvent-water and leading said yarn in a 2nd bath consisting of 61 - 85% said organic solvent-water and then in a 3rd and more bath consisting of less than 60% said organic solvent-water and drying, drawing out and annealing said yarn by ordinary methods.

Method of manufacturing acrylic fibers

Compounds having the formula ##EQU1## wherein R is alkyl group having 6 to 22 carbon atoms, M is H, Li, Na, K or NH.sub.4 and n is an integer of 2 to 4, inclusive. The compound is useful as polymerizable emulsifying agent, and enables to improve properties of produced polymer and to provide a modacrylic fiber superior in heat stability and fastness to light. The aqueous emulsion polymerization of .alpha.,.beta.-ethylenically unsaturated monomer by the use of the polymerizable anionic emulsifying agent is capable of preventing a discharge of an environmental pollutant.

Polymerizable emulsifying agent and application thereof

A method of manufacturing acrylic fibers free from delustering in boiling water, comprises the steps of forming a spinning solution by dissolving in a solvent of Aceton et al, (a) a copolymer consisting of (1) 30 - 80% acrylonitril and (2) 70 - 20% vinyl chloride or vinylidenechloride, or (b) a tripolymer consisting of (1), (2) and (3) 3.0% or less by weight of ethylenically unsaturated monomer having hydrophilic radicals, and adding one or more compound selected from the group of (1) homopolymer or copolymer of glycidyl methacrylate and (2) specific organic tin compounds, and spinning said spinning solution into a first bath consisting of 60% or less said organic solvent-water and leading said yarn in a 2nd bath consisting of 61 - 85% said organic solvent-water and then in a 3rd and more bath consisting of less than 60% said organic solvent-water and drying, drawing out and annealing said yarn by ordinary methods.

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Akashi, Japan

Shigeru Kobayashi