Air Products and Chemicals, Inc.

Evonik Operations Gmbh

E Ink Corporation

Evonik Degussa Gmbh

E Ink Corporation & Air Products and Chemical, Inc.

E Ink Corporaiton

Shafiq Fazel

Eric Howard Klingenberg

David Darrell Miller

Lan Cao

Shiying Zheng

Sudhir Ananthachar

Jared Denis Bender

Guy Danner

Charles Howie Honeyman

Gauri Sankar Lal

Michael Ian Cook

Richard M Webber

Stephen Michael Boyce

Charles Hegedus

Robert Marjo Theodoor Rasing

Keith Douglas Campbell

Edze Jan Tijsma

Eva Chen

Wei Cao

Robert Rasing

Nergiz Bozok

Thomas T Corby

Michael Oberlander

The present invention relates to a polyurea coating composition comprising (A) a polyisocyanate; (B) a polyaspartic ester; and (C) an aspartic ester. The polyaspartic ester (B) is represented by the structure below:

Polyurea compositions from polyaspartic esters and secondary heterocyclic amines derived aspartic esters

Polycarbamide coating compositions and secondary diamine curing agents used to produce the coating compositions are disclosed. Curing agent compositions comprising: (a) the reaction product of bis(4-aminocyclohexyl) methane and ethyl ester of 2-butendioc acid; and (b) the reaction product of bis(4-amino-3-methylcyclohexyl)methane and ethyl ester of 2-butendioic acid; and (c) at least one polyol are also disclosed. One aspect of the disclosure relates to a non-aqueous coating composition comprising the disclosed amine curing agents with a polyisocyanate resin. The coating compositions are suitable for use as direct to metal coatings or top coats. Methods of producing the curing agents and the coating compositions are also disclosed.

Polycarbamide resins for metal coating applications

A method of forming a low gloss, high solids polyurea coating containing very low volatile organic compounds (VOC) in the coating composition. The low volatile content not only makes the coating environmentally friendly but allows it to be applied at variable thickness levels and over a wide variety of environmental conditions. The coating composition is comprised of an isocyanate reactive agent containing a secondary diamine, a polyisocyanate, a gloss reducing agent and a viscosity modifier. The gloss reducing agent is generally pre-mixed into an isocyanate reactive agent containing a secondary diamine and/or polyisocyanate containing the viscosity modifier before mixing the two components together to form a low gloss polyurea coating.

Low gloss, high solids polyurea coatings

Amine-epoxy curing agents are disclosed including at least one saturated heterocyclic compound having two nitrogen heteroatoms according to formula (I) and at least one saturated fused bicyclic heterocyclic compound having three nitrogen heteroatoms according to formula (II): wherein X is independently selected from a hydrogen atom, a linear or branched Cto Calkyl group and a substituted or un-substituted phenyl group, Yis a direct bond or a divalent polyethylene polyamine group having 1 to 8 nitrogen atoms or a divalent polyethylene polyamine derivative having 1 to 8 nitrogen atoms, Yis a direct bond or a divalent polyethylene polyamine group having 1 to 7 nitrogen atoms and R is independently a hydrogen atom or a group selected from C-Clinear, cyclic, and branched alkyl, alkenyl, and alkaryl groups.

Nitrogen-containing heterocyclic epoxy curing agents, compositions and methods

The present invention relates to epoxy curing agents which are obtained from the reaction of a polyalkylene polyether modified polyepoxide resin and a polyamine component. They polyamine component is a reaction product of a polyethylene polyamine having 3 to 10 nitrogen atoms, for example, diethylenetriamine (DETA), and at least one aldehyde having 1 to 8 carbon atoms, for example, formaldehyde. The epoxy curing agent may be used as part of a two component coating system in the curing of liquid or pre-dispersed curable epoxy resins.

Epoxy curing agents, compositions and uses thereof

Substantially solvent-free aqueous polyurethane dispersions and methods of making and using the same are provided. The substantially solvent-free aqueous polyurethane dispersions are provided in a substantially solvent-free system of a prepolymer made by reacting at least one polyol, at least one polyisocyanate, at least one isocyanate-reactive compound comprising one or more ionic or potential ionic groups, and at least one isocyanate chain terminating agent.

Solvent free aqueous polyurethane dispersions and methods of making and using the same

A polyurethane formed from an isocyanate, a polyether diol and a polyester diol, the polyester diol having a molecular weight less than about 2000, or comprising two polyester diol segments connected by a steric hindrance group, each of the polyester diol segments having a molecular weight less than about 2000, the molar ratio of polyether diol to polyester diol being in the range of from about 1:9 to about 9:1. The polyurethane is useful as a lamination adhesive in electro-optic displays, and in components used to form such displays.

Electro-optic display and materials for use therein

An electro-optic display comprises a layer of solid electro-optic material; a backplane comprising at least one electrode; and an adhesive layer disposed between the layer of electro-optic material and the backplane and adhesively securing the layer of electro-optic material to the backplane, the adhesive layer comprising a thermally-activated cross-linking agent comprising an epoxidized vegetable oil fatty acid or an epoxidized ester of such a fatty acid. The cross-linking agent reduces void growth when the display is subjected to temperature changes.

Electro-optic displays, and materials for use therein

A polyurethane is formed from an isocyanate and a polyester diol having a molecular weight less than about 2000, or a polyester diol comprising two polyester diol segments connected by a steric hindrance group, each of the polyester diol segments having a molecular weight less than about 2000. The polyurethane is useful as a binder in electro-optic displays, and in components used to form such displays.

Aqueous polyurethane dispersions comprising polyurethane polymer and methods for making and using same are disclosed herein. In one aspect of the present invention, aqueous polyurethane dispersions, comprising a polyurethane polymer having a weight average molecular weight ranging from 20,000 to 80,000, are prepared by controlling the weight average molecular weight of the polymer by reacting the isocyanate terminated prepolymer with at least one chain terminating agent; and/or maintaining a N/COOH molar ratio of amine in the neutralizing agent to acid functional group in the isocyanate reactive compound to from about 0.5:1 to about 1:1.

Aqueous polyurethane dispersion and method for making and using same

An electro-optic display comprises first and second substrates, and an adhesive layer and a layer of electro-optic material disposed between these substrates, the adhesive layer comprising a mixture of a polymeric adhesive material and an additive selected from a salt, a polyelectrolyte, a polymer electrolyte, a solid electrolyte, a conductive metal powder, a ferrofluid, a non-reactive solvent, a conductive organic compound, and combinations thereof. The additive enables the volume resistivity of the adhesive layer to be controlled. Also, in an encapsulated electrophoretic medium comprising capsules in a polymeric binder, the volume resistivity of the binder can be controlled in a similar manner.

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Allentown, PA, United States of America

Shafiq Fazel