Korea Kumho Petrochemical Co., Ltd.

Seung Hwon Lee

Gwang Hoon Kwag

Young Chan Jang

A Ju Kim

Pil Sung Kim

Hoochae Kim

Hyung Kyu Choi

Hwieon Park

Hyun Jin Kim

Shin Han

Seung Hwa Lee

Sam Min Kim

The present invention relates to a process of preparing 1,4-trans polybutadiene grafted with an aromatic organosulfur compound, the process comprising (a) preparing 1,4-trans polybutadiene by polymerizing 1,3-butadiene or butadiene derivatives in a nonpolar solvent in the presence of a particular catalyst, and (b) preparing the 1,4-trans polybutadiene grafted with an aromatic organosulfur compound by reacting the trans polybutadiene with an aromatic organosulfur compound. The organosulfur molecule in the molecular chain minimizes ultra high molecular weight fraction and narrows the molecular weight distribution, thereby enabling this polymer to show improved processability and tensile properties.

Grafted and functionalized high 1,4-trans polybutadiene with aromatic organosulfur compound

The present invention relates to a preparation method of aromatic organosulfur functionalized 1,4-cis polybutadiene comprising: polymerizing 1,3-butadiene or butadiene derivative in the presence of a specific catalyst in a nonpolar solvent to prepare 1,4-cis polybutadiene; and reacting the resultant polybutadiene with an aromatic organosulfur compound. Such prepared aromatic organosulfur functionalized 1,4-cis polybutadiene is without ultrahigh molecular weight region and, thus, has narrow molecular weight distribution.

Aromatic organosulfur functionalized 1,4-cis polybutadiene

Provided are a molecular weight controllable, high 1,4-trans polybutadiene catalyst system, and more particularly, a four-component catalyst for preparing 1,4-trans polybutadiene with high yield, the catalyst comprising a cobalt compound, an organoaluminum compound, a phenol-based compound, and a phosphorus-based compound used to prepare 1,4-trans polybutadiene by polymerizing butadiene or a butadiene derivative, and capable of controlling the molecular weight of 1,4-trans polybutadiene by regulating the amount of the phosphorus-based compound. In particular, 1,4-trans polybutadiene may be efficiently applied to tires, belts, or the like since it has excellent tensile strength, tear strength, and cut & chip properties with increasing processability.

Molecular weight controllable, high 1,4-trans polybutadiene catalyst system

Disclosed is a novel high 1,4-cis polybutadiene-polyurethane copolymer and a preparation method thereof. The present invention provides a high 1,4-cis polybutadiene-polyurethane copolymer represented by the following formula 1 and having an average molecular weight of at least 100,000, and a method for preparing the high 1,4-cis polybutadiene-polyurethane copolymer that includes polymerizing 1,3-butadiene or butadiene derivatives with a catalyst comprising a rare earth compound, a halogen-containing compound and an organoaluminum compound in the presence of a non-polar solvent, to prepare a polybutadiene having a high 1,4-cis content of at least 95%; and then introducing a polyurethane group to the polybutadiene. The high 1,4-cis polybutadiene-polyurethane copolymer thus obtained exhibits low cold flow and high affinity to silica or carbon black in admixture as well as excellent in elasticity and abrasion resistance:  where l, m, n and o represent the number of repeating unit, 1 is 94 to 99%, m is 0 to 5%, n is 0 to 5%, l+m+n=100%, l/(m+n) is 15 to 100, o is 1 to 100%; and A and Y are C-Calkyl or aryl, respectively.

High 1,4-cis polybutadiene-polyurethane copolymer and preparation method thereof

The present invention relates to a method for preparing a high 1,4-cis polybutadiene having a controlled cold flow and, more particularly, to a novel method for preparing a high 1,4-cis polybutadiene having a controlled cold flow that involves initiating polymerization of a 1,3-butadiene in the presence of a non-polar solvent using, as a polymerization catalyst, a complex prepared by mixing a neodymium compound with or without a conjugated diene compound, a halogenated organoaluminum compound or a halogenated organic compound, and an organoaluminum compound irrespective of the addition order of the catalyst; and adding an organoborane compound as a cold flow controller of 1,4-cis polybutadiene after a predetermined time of the polymerization. Accordingly, a high 1,4-cis polybutadiene having an efficiently controlled cold flow can be prepared without causing a significant increase in the Mooney viscosity (molecular weight), an odor (bad smell), and a reduction in 1,4-cis content and polymerization yield.

Method for preparing high 1,4-cis polybutadiene having controlled cold flow

The invention is related to a novel compound represented by NdHA wherein A is a carboxylate, and to a diene polymerization catalyst using the novel compound. NdHA has monomeric structure and does not contain water, bases and salts. NdHA is mixed with a halogen compound and an organic metal compound to prepare a catalyst system. The catalyst system in the polymerization of 1,3-butadiene (BD) or isoprene produces high cis polydiene with a high activity (100 g BD/4.0&times;10 mole Nd) and without gel formation. The polydiene thus obtained is useful for tires and golf balls and as a polystyrene modifier.

Monomeric neodymium carboxylate and its use in polymerization of conjugated diene

This invention relates to a process for preparation of high 1,4-cis polybutadiene and more particularly, to the process for preparing polybutadiene by polymerizing 1,3-butadiene monomer in the presence of a catalyst prepared by aging a mixture of a neodymium salt compound, a nickel salt compound, an organoaluminium compound and a borontrifluoride complex compound in the presence or absence of a conjugated diene compound. With much remarked catalytic activity, polybutadiene with a very high 1,4-cis content can be prepared in a high yield using a small amount of catalyst.

Process for preparation of high 1,4-CIS polybutadiene

This invention relates to a process for preparing polybutadiene with high 1,4-cis content (over 97%) and high conversion (over 90%) in such a manner that 1,3-butadiene is polymerized using an aging catalyst, which has high homogeneity due to its excellent solubility in non-polar solvents, resulting in producing polybutadiene having low gel content and low solution viscosity. The aging catalyst is a mixture of a neodymium compound, an organoaluminum compound and a borontrifluoride complex, which is represented by the formula I or the formula II, in the presence or absence of a small portion of conjugated diene compound: Formula I is represented by

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Daejeon, South Korea

Seung Hwon Lee