Lg Chem, Ltd

Seong Yong Ahn

Se Woong Lee

Kun Ji Kim

Hyun Kyou Ha

Kyung Hyun Kim

Heung Kwon Bae

Seong Jae Shin

Soo Hwan Hwang

Byung Kook Ahn

Dae Woo Lee

Jin Hyuck Ju

Bhom Ri Kim

Kun Ji Ki

Provided is a method of producing a vinyl chloride-based polymer composite, which includes: forming particle nuclei by bulk polymerizing vinyl chloride-based monomers; producing a vinyl chloride-based polymer by bulk polymerizing vinyl chloride-based monomers in the presence of the particle nuclei; and producing a vinyl chloride-based polymer composite including the vinyl chloride-based polymer and a cellulose-based compound.

Method of producing vinyl chloride-based polymer composite

Provided is a method of preparing a vinyl chloride-based polymer composite, which includes: bulk-polymerizing vinyl chloride-based monomers to prepare a vinyl chloride-based polymer; and preparing a vinyl chloride-based polymer composite including the vinyl chloride-based polymer and polyvinylpyrrolidone.

Method of preparing vinyl chloride-based polymer composite

The present invention relates to a method for preparing a vinyl chloride-based polymer, including: bulk polymerizing a vinyl chloride-based monomer in a polymerization reactor to prepare a vinyl chloride-based polymer; and adding water and vapor to the polymerization reactor, and heating to remove an unreacted vinyl chloride-based monomer, wherein an addition amount of the water is 0.500 to 5.000 parts by weight based on 100 parts by weight of the vinyl chloride-based polymer.

Method for preparing vinyl chloride-based polymer

The present invention relates to a vinyl chloride polymer and a production method thereof. More specifically, the present invention provides a vinyl chloride polymer having a polydispersity index of 2.0 to 2.3 and a porosity of 60% or greater and a production method thereof in which a vinyl chloride polymerization seed having a conversion rate of 5-20% is first prepared through preliminary polymerization and then a vinyl chloride monomer is introduced into the vinyl chloride polymerization seed to polymerize (main polymerization) a vinyl chloride polymer.

Vinyl chloride polymer and production method thereof

The present invention relates to a method for preparing a vinyl chloride-based polymer, more specifically, to a method for preparing a vinyl chloride-based polymer through which it is possible to improve an apparent specific gravity of a vinyl chloride-based polymer to be prepared by controlling a surface tension of a polymerization mixture to 46.5 mN/m or more, and thus, to improve an extrusion amount when extruded, whereby a vinyl chloride-based polymer having excellent processing productivity can be prepared.

Method for preparing vinyl chloride-based polymer and vinyl chloride-based polymer prepared therefrom

The present disclosure provides a method of preparing a vinyl chloride-based polymer having improved processability due to excellent blendability, and the vinyl chloride-based polymer having a particle non-uniformity of 10 or more defined by Equation 1. 

Vinyl chloride-based polymer and preparation method thereof

The present invention relates to a method of preparing a vinyl chloride-based polymer composite, which comprises dispersing a vinyl chloride-based monomer in water (Step 1); polymerizing the dispersed vinyl chloride-based monomer with an initiator to prepare a polymer slurry by (Step 2); and adding a phosphite to the polymer while drying the polymer slurry, to prepare a vinyl chloride-based polymer composite (Step 3), and a vinyl chloride-based polymer composite prepared by the method and a vinyl chloride-based polymer composite composition.

Method of preparing vinyl chloride-based polymer composite, vinyl chloride-based polymer composite, and vinyl chloride-based polymer composite composition

The present invention relates to a method of preparing a vinyl chloride-based polymer, which includes inducing the nucleation of particles by adding a mercaptan-based chain transfer agent to a monomer composition including a vinyl chloride-based monomer and a preliminary polymerization initiator (preliminary polymerization); and preparing a polymer by mixing a vinyl chloride-based monomer and the particle nuclei and adding a main polymerization initiator (main polymerization). In the preparation method, a vinyl chloride-based polymer having a uniform molecular weight distribution and a desired number average molecular weight may be provided by controlling a degree of polymerization of a vinyl chloride-based polymer prepared in such a way that dispersibility is ensured by adjusting the point of time to add the mercaptan-based chain transfer agent to the point of time to reach a specific conversion rate of the preliminary polymerization.

Method of preparing vinyl chloride-based polymer

The present invention relates to a method of preparing a vinyl chloride-based polymer, which comprises bulk-polymerizing a vinyl chloride-based monomer in the presence of an initiator (Step 1); and preparing a vinyl chloride-based polymer after the bulk polymerization (Step 2), wherein a phosphite is added in the step 1, a vinyl chloride-based polymer, and a vinyl chloride-based polymer composition comprising the vinyl chloride-based polymer.

Method of preparing vinyl chloride-based polymer, vinyl chloride-based polymer, and vinyl chloride-based polymer composition

The present invention relates to a vinyl chloride-based copolymer which has good processability and thus is capable of providing molded articles having good appearance characteristics, for example, transparency, a method for preparing the same, a thermoplastic resin composition containing the same, and a thermoplastic resin molded article produced from the thermoplastic resin composition. The vinyl chloride-based copolymer includes N-vinyllactam-based polymer compound derived units and unsaturated fatty acid ester derived units at an appropriate ratio, and may have improved structure stability and good processability due to the N-vinyllactam-based polymer compound derived units and improved plasticity and processability due to the internal plasticizer action of the unsaturated fatty acid ester derived units. Therefore, the vinyl chloride-based copolymer according to the present invention may be easily applied in industries that need thereof.

Vinyl chloride-based copolymer, method for preparing the same, and thermoplastic resin composition containing the same

The present invention relates to a method of preparing a vinyl chloride-based polymer, which may prepare a vinyl chloride-based polymer with excellent surface properties by adjusting a foam level generated during a polymerization reaction to an appropriate value, a vinyl chloride-based polymer prepared thereby, and an apparatus for preparing a vinyl chloride-based polymer which may prepare the vinyl chloride-based polymer. The method of preparing a vinyl chloride-based polymer according to the present invention may prepare a vinyl chloride-based polymer with excellent surface properties, for example, fewer occurrences of fish-eyes and excellent transparency, by performing a polymerization reaction while maintaining the level of a foam generated during the polymerization reaction at an appropriate value.

Method of preparing vinyl chloride-based polymer and apparatus for preparing vinyl chloride-based polymer

Disclosed are a chloroethylene-based nanocomposite composition comprising a chloroethylene-based resin; a nanoclay comprising a coupling agent bonded thereto; and at least one polymer selected from unsaturated organic acid-based resins or polycarboxylic acid-based resins, and a method of preparing the same.

Chloroethylene-based nanocomposite composition and method of preparing the same

The present invention relates to a vinyl chloride-based polymer containing an unsaturated fatty acid ester at a specific ratio, a method for preparing the same, a thermoplastic resin composition containing the same, and a thermoplastic resin molded article produced from the composition. The vinyl chloride-based polymer may have good processability, and thus, the thermoplastic resin molded article produced from the thermoplastic resin composition containing the vinyl chloride-based polymer may have high impact strength and improved appearance characteristics.

Vinyl chloride-based polymer, method for preparing the same, and thermoplastic resin composition containing the same

The present invention relates to a method of preparing a vinyl chloride-based copolymer having excellent plasticity and processability, a vinyl chloride-based copolymer prepared thereby, a thermoplastic resin composition including the vinyl chloride-based copolymer, and a thermoplastic resin molded article prepared from the composition. Since the preparation method may improve copolymerizability with a vinyl chloride-based monomer by continuously adding or dividedly adding an unsaturated fatty acid ester mixture used as a comonomer during the time of specific polymerization conversion rate, the unreacted unsaturated fatty acid ester mixture may be reduced, and, as a result, the conversion rate of the vinyl chloride-based copolymer may be significantly improved. Thus, plasticity and processability of a vinyl chloride-based copolymer prepared by the above method may be significantly improved.

Method of preparing vinyl chloride-based copolymer and vinyl chloride-based copolymer prepared thereby

Provided are a vinyl chloride-based copolymer, as a secondary particle in which primary particles are assembled, which may exhibit excellent mechanical properties and transparency as well as excellent plasticity by having an average pore diameter of 100 nm or less and a porosity of 40 vol % or less, including 65 wt % to 97 wt % of a vinyl chloride-based monomer-derived repeating unit; and 3 wt % to 35 wt % of cis and trans isomers of an unsaturated fatty acid ester-derived repeating units, and including the repeating units respectively derived from the cis and trans isomers of the unsaturated fatty acid ester in a weight ratio of 60:40 to 99:1, and a method of preparing the same.

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Daejeon, South Korea

Seong Yong Ahn