Saudi Arabian Oil Company

Korea Advanced Institute of Science and Technology

Seokin Choi

Yuguo Wang

Rashid M Othman

Minkee Choi

Cemal Ercan

Provided here are adsorbent compositions containing polyvinyl alcohol-bonded pellets of zeolite templated carbon. Also provided here are methods of producing adsorbent compositions by forming an aqueous mixture containing a binder, water, and zeolite-templated carbon; subjecting the aqueous mixture to a drying process to remove the water and form a dry mixture of the binder and the zeolite-templated carbon, and compacting the dry mixture of the binder and the zeolite-templated carbon to form the binder-bonded pellets of the zeolite templated carbon.

Methods of making zeolite-templated carbon pellets and uses thereof

A method for the large-scale synthesis of a zeolite-templated carbon (ZTC). The method includes the steps of: introducing a bed material comprising a zeolite to a fluidized bed reactor and heating the bed material to a temperature between 550&#xb0; C. and 800&#xb0; C.; fluidizing the bed material with a fluidizing gas and maintaining the temperature of the bed material between 550&#xb0; C. and 800&#xb0; C.; introducing an organic carbon precursor while fluidizing the zeolite for a period of time such that carbon is deposited on the zeolite by chemical vapor deposition to produce a zeolite-carbon composite; and treating the zeolite-carbon composite with an acid solution such that the zeolite template is dissolved and the ZTC is obtained.

Process for the large-scale manufacture of zeolite-templated carbon

Embodiments provide a methane microporous carbon adsorbent including a thermally-treated CVD carbon having a shape in the form of a negative replica of a crystalline zeolite has a BET specific surface area, a micropore volume, a micropore to mesopore volume ratio, a stored methane value and a methane delivered value and a sequential carbon synthesis method for forming the methane microporous carbon adsorbent. Introducing an organic precursor gas for a chemical vapor deposition (CVD) period to a crystalline zeolite that is maintained at a CVD temperature forms the carbon-zeolite composite. Introducing a non-reactive gas for a thermal treatment period to the carbon-zeolite composite maintained at a thermal treatment temperature forms the thermally-treated carbon-zeolite composite. Introducing an aqueous strong mineral acid mixture to the thermally-treated carbon-zeolite composite forms the methane microporous carbon adsorbent. The crystalline zeolite includes tri-ethanolamine (TEA) and has a shape that is orthogonal with a mid-edge length in a range of 8 &#x3bc;m to 20 &#x3bc;m.

Synthesis of ordered microporous activated carbons by chemical vapor deposition

A methane microporous carbon adsorbent comprising a thermally-treated CVD carbon having a shape in the form of a negative replica of a crystalline zeolite has a BET specific surface area, a micropore volume, a micropore to mesopore volume ratio, a stored methane value and a methane delivered value and a sequential carbon synthesis method for forming the methane microporous carbon adsorbent. Introducing an organic precursor gas for a chemical vapor deposition (CVD) period to a crystalline zeolite that is maintained at a CVD temperature forms the carbon-zeolite composite. Introducing a non-reactive gas for a thermal treatment period to the carbon-zeolite composite maintained at a thermal treatment temperature forms the thermally-treated carbon-zeolite composite. Introducing an aqueous strong mineral acid mixture to the thermally-treated carbon-zeolite composite forms the methane microporous carbon adsorbent.

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Daejeon, South Korea

Seokin Choi