Fuji Electric Co., Ltd.

Fuji Electric., Ltd.

Seishi Terasaki

Youichi Tei

Teruaki Kobayashi

Shinichi Tamura

Tadashi Mimura

Yoshihiro Ueno

Shinjiro Suzuki

Fengqiang Zhu

Kenichi Ohkura

Quanqiu Zhang

Shinichi Omokawa

Kenji Kawate

An electrophotographic photoreceptor having a photosensitive layer which includes, as a resin binder, a copolymeric polyarylate resin having structural units of a Chemical Structural Formula 1, a method of producing the photoreceptor, an electrophotographic device including the electrophotographic photoreceptor, and a method of preparing the copolymeric polyarylate resin are provided. The electrophotographic photoreceptor reduces the amount of abrasion at the surface of a photoreceptor drum and lowers frictional resistance from the beginning until the end of printing, and moreover provides good images.

Electrophotographic photoreceptor including a copolymer polyarylate resin, production method therefor, electrophotographic device including the photoreceptor, and production method for the copolymer polyarylate resin

An organic electrophotographic photoconductor diminished in an image trouble due to history of a transfer process in a reversal development system is disclosed. The above organic electrophotographic photoconductor is called a separated-function laminated type organic electrophotographic photoconductor, which has an undercoat layer and a photosensitive layer laminated in this order on a conductive substrate, the photosensitive layer comprising a charge generation layer laminated on the undercoat layer and containing an organic compound, and a charge transport layer laminated on the charge generation layer and containing an organic compound. For the charge generation layer, a titanyloxyphthalocyanine compound is used as a charge generation material. The present invention uses the titanyloxyphthalocyanine compound having a clear diffraction peak at a Bragg angle (2.theta.) of 9.6.degree..+-.0.2.degree. or 27.3.degree..+-.0.2.degree. for CuK.alpha. characteristic X-ray (wavelength 1.541 .ANG.). For the charge transport layer, a specific organic compound is used as a charge transport material.

Electrophotographic photoconductor and electrophotographic device using

Phthalonitrile, an alkali metal or an alkali metal compound, and a hydrogen donor compound are heated in an organic solvent to synthesize a partially hydrogenated alkali metal phthalocyanine, which is then brought into contact with a dealkalizing agent to effect substitution with hydrogen of the partially hydrogenated alkali metal phthalocyanine to thereby obtain high-purity metal-free phthalocyanine. FX-type metal-free phthalocyanine as obtained according to the foregoing procedure may be used as a charge-generating substance to produce an electrophotographic photoconductor of high image quality which is highly sensitive to near infrared rays.

Process for preparing a metal-free phthalocyanine

An electrophotographic photoconductor, includes metal-free phthalocyanine as a charge-generating substance, wherein the X-ray diffraction spectrum of said metal-free phthalocyanine as measured using CuK.alpha. as a radiation source includes intense diffraction peaks at Bragg angles (2.theta..+-.0.2.degree.) of 7.5.degree., 9.0.degree., 16.6.degree., 17.2.degree., 21.5.degree., 22.2.degree., 23.8.degree., and 28.5.degree., and wherein the infrared absorption spectrum of said metal-free phthalocyanine includes four absorption bands with the maximum absorption intensity at a wavenumber of 716 cm.sup.-1 between a wavenumber of 700 cm.sup.-1 and a wavenumber of 760 cm.sup.-1 and a characteristic absorption band at a wavenumber of 3,291.+-.2 cm.sup.-1.

Electrophotographic photoconductor including a metal-free phthalocyanine

Metal-free phythalocyanine, process for preparing the same, and

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Kawasaki, Japan

Seishi Terasaki