Sumitomo Chemical Company, Limited

Seimei Yasui

Hiroshi Sato

Takanobu Noguchi

Minoru Hino

Michio Yamamoto

Takao Oshima

Akihiro Furuta

Makoto Hanabata

Hideto Tojima

Masakazu Sagou

Yoshinobu Matsuda

Yoshiharu Yagi

Yoshiaki Togawa

Yoshiki Toyoshima

Kunihiko Tanaka

Kazuo Hayatsu

Yukio Suzuki

Toshitsugu Kikuchi

Naoyoshi Jinno

Akira Shintani

Junzo Saito

Koiti Fujisawa

Kunio Izumi

Otsugu Hayashi

Masakazu Sagoh

Tsutomu Fujita

Osamu Hiroaki

Kazuya Hayashi

An optical disk is provided which comprises two sheets of substrates; or two sheets of substrate and a reinforcing plate or a reinforcing rim; or one sheet of substrate and a reinforcing plate; which are bonded to form an integrated body having a spacer interposed therebetween, said spacer being made of elastomeric foam having a specific gravity of not more than 1.5 and an expansion ratio of not less than 1.5 as the material of the said spacer. This optical disk has a high adaptability of the drive and exhibits a high reliability, i.e. excellent vibration restricting performance, thereby being possible to provide a stable and highly accurate information processing.

Optical foam-spacer disk assembly

A positive type photoresist composition comprising a novolak resin and O-quinone diazide compound, the novolak resin being one which is obtained by the addition condensation reaction of a phenol and formaldehyde which is performed in one stage by using as a catalyst an organic acid salt of a divalent metal which is more electropositive than hydrogen, or in two stages by using an acid catalyst in the subsequent stage, the phenol being at least one compound represented by the formula ##STR1## wherein R is hydrogen or an alkyl group of carbon number 1 to 4, the compound being such that the average carbon number in the substituent per one phenol nucelus is 0.5 to 1.5 and the ones with the substituent at the ortho- or para-position with respect to the hydroxyl group account for less than 50 mol %, is disclosed. The positive type photoresist composition of the invention has an improved resolving power, i.e., .gamma.-value.

Positive type high gamma-value photoresist composition with novolak

A positive type photoresist composition comprising an m-hydroxy-.alpha.-methylstyrene polymer and as a photo-sensitizer a quinonediazide compound is disclosed. A positive type photoresist composition comprising an m-hydroxy-.alpha.-methylstyrene polymer, a novolak resin, and as a photo-sensitizer a quinonediazide compound, is also disclosed.

Positive photoresist composition with m-hydroxy-.alpha.-methylstyrene

A process for the production of a phenolic resin modified with a liquid polybutadiene being useful as an impregnating varnish in the production of a copper-clad laminate for a printed circuit, which comprises preparing an adduct of a liquid polybutadiene having a number average molecular weight of 150 to 5,000 with an .alpha., .beta.-unsaturated dicarboxylic acid or its anhydride, subjecting the adduct to an addition reaction with one or plurality of phenols in the presence of an acid catalyst to obtain a composition and reacting the composition with formaldehyde in the presence of a basic catalyst.

Process for production of phenolic resin modified with liquid

A resin composition for electrocoating which comprises

Resin composition for electrocoating

Process for the preparation of a phenol resin modified with a liquid polybutadiene which comprises reacting a polybutadiene having a number average molecular weight of 150 to 5,000 with a phenol in the presence of an acid catalyst to obtain a composition which consists of a polybutadiene-phenol adduct and unreacted phenol, in said polybutadiene-phenol adduct, one molecule of phenol per 3 to 8 butadiene units being added to the polybutadiene, and reacting the composition of a polybutadiene-phenol adduct with a formaldehyde in the presence of a basic catalyst, said basic catalyst comprising a primary amine of the formula: R--NH.sub.2 wherein R is a hydrocarbon group having 1 to 20 carbon atoms in an amount of 0.01 to 0.5 mole per 1 mole of the phenol used for the preparation of the composition which is used alone or in combination thereof with other basic compound. Said resin composition thus prepared is useful for the preparation of a laminated sheet having excellent curing characteristics, particularly excellent electrical characteristics, punchability and flexibility.

Process for preparation of a phenolic-polybutadiene-HCHO resin

1,1,3,4,4,6-Hexamethyl-1,2,3,4-tetrahydronaphthalene (HMT), which is an intermediate for the production of acetyl HMT valuable in the art of perfumery because of its musk-like odor properties, is produced with industrial advantages by reacting p-cymene with 2,3-dimethylbutene using a catalytic amount of an anhydrous aluminum halide in the presence of at least one member selected from secondary alkyl halides, tertiary alkyl halides, propargyl halides and allyl halides; and 7-acetyl HMT is obtained by acetylation of the above-obtained HMT.

Process for preparing hexamethyltetrahydronaphthalenes

Process for the preparation of a resin composition which comprises reacting a polybutadiene having a number average molecular weight of 150 to 10,000 and 1,4-structure of at least 80% by weight with a phenol in the presence of an acid catalyst to obtain a composition which consists of a polybutadiene-phenol adduct and unreacted phenol, in said polybutadiene-phenol adduct, one molecule of phenol per 3 to 8 butadiene units being added to the polybutadiene, and reacting the polybutadiene-phenol adduct composition with a formaldehyde in the presence of a basic catalyst. Said resin composition thus prepared is useful for the preparation of a laminated sheet having excellent curing characteristics, particularly excellent electrical characteristics, punchability and flexibility.

Process for preparation of resin composition useful for laminated sheet

A resin for coatings, particularly useful as a medium for printing inks and paints, comprising a modified polymer produced by adding at least one .alpha.,.beta.-unsaturated dicarboxylic acid or anhydride thereof to at least one liquid conjugated diolefinic polymer having a number average molecular weight of 150 to 3,000, a viscosity of 2 to 5,000 cps at 30.degree. C. and at least 50% of cis-1,4 structure and subjecting the resulting adduct to diesterification with at least one alcohol having 1 to 27 carbon atoms and whereby the acid value owing to the carboxyl group or the carboxylic anhydride group of the resulting modified polymer being made not more than 10.

Esters of an adduct of diolefinic polymer and unsaturated dicarboxylic

A process for isomerization of .alpha.-olefin dimers which comprises dimerizing a lower .alpha.-olefin with a Ziegler type catalyst comprising a nickel compound and an organo-aluminum compound, and then continuing the reaction with addition of at least one compound, prior to deactivation of said catalyst, which is selected from the group consisting of the following organo-halogen compounds of the formulae (I), (II), (III) and (IV), ##STR1## wherein X.sup.1 to X.sup.11 are the same or different and are each a halogen or hydrogen atom or an alkyl group having 1 to 20 carbon atoms and at least one of them in each formula is a halogen atom, R is a hydrocarbon group having 1 to 20 carbon atoms, R.sup.1, R.sup.2 and R.sup.3 are the same or different and are each a hydrogen or halogen atom or a hydrocarbon group having 1 to 20 carbon atoms, R.sup.4 is a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms, R.sup.5 and R.sup.6 are the same or different and are each an alkyl having 1 to 20 carbon atoms or, taken together, may form a cycloalkyl group, and n is an integer of 0 to 5.

.alpha.-Olefin dimer isomerization using organo-halogens

A resin for coatings, particularly useful as a medium for printing inks and paints, comprising a modified polymer produced by adding at least one .alpha.,.beta.-unsaturated dicarboxylic acid or anhydride thereof to at least one liquid conjugated diolefinic polymer having a number average molecular weight of 150 to 3,000, a viscosity of 2 to 5,000 cps at 30.degree. C. and at least 50% of cis-1,4 structure and subjecting the resulting adduct to imidation or diamidation with at least one amine having 1 to 27 carbon atoms and whereby the total amine value of the resulting modified polymer being made not more than 3.

Resin for coatings

A process for production of a polymer emulsion comprising polymerizing at least one partially esterified, imidated or amidated product of an adduct with a compound having a polymerizable unsaturated group and a hydroxy group, epoxy group or amino group, in an aqueous system in the presence or absence of a vinyl monomer, said adduct being produced by adding an .alpha.,.beta.-unsaturated dicarboxylic acid or anhydride thereof to at least one compound selected from the group consisting of a synthetic unsaturated polymer having a number average molecular weight of 150 to 30,000 and an iodine value of 50 to 500, a natural drying oil, a natural semidrying oil and an unsaturated fatty acid which composes the natural drying or semidrying oils. The polymer emulsion shows excellent coating film properties when used for paints.

Process for production of novel polymer emulsion

A process for production of the maleic anhydride adduct of a liquid polymer having a maleic anhydride addition amount of 2 to 70% by weight, which comprises reacting a liquid polymer having a molecular weight of 150 to 5,000 and a viscosity of 2 to 50,000 cp at 30.degree. C. in the presence of at least one compound, as a gelation inhibitor, selected from the group consisting of imidazoles, thiazoles, metallic salts of mercaptothiazoles, urea derivatives, naphthylamines, nitrosamines, iron, iron compounds and specific halogen compounds, said liquid polymer being selected from the group consisting of liquid polybutadienes, liquid polyisoprenes and liquid copolymers comprising units of butadiene or isoprene and units of at least one compound selected from the group consisting of other diolefins, olefins and aromatic vinyl compounds.

Process for production of the maleic anhydride adduct of a liquid polymer

A process for dimerizing lower .alpha.-olefins using a catalyst comprising (A) at least one nickel compound selected from the group consisting of organic acid salts of nickel, inorganic acid salts of nickel and complexes of nickel, (B) a trialkyl aluminum, (C) at least one phosphorus-containing compound selected from the group consisting of tri-valent phosphorus compounds represented by the formulae: (I) PR.sup.1 R.sup.2 R.sup.3, (II) (R.sub.2.sup.1 N).sub.n PR.sub.3-n.sup.2 and (III) (R.sup.1 O).sub.n PR.sub.3-n.sup.2 (in which R.sup.1, R.sup.2 and R.sup.3 are each an alkyl, cycloalkyl, alkenyl, aryl or aralkyl group having up to 18 carbon atoms and n is an integer of 1 to 3), and (D) a halogenated phenol of the formula (IV), ##STR1## wherein X.sub.1, X.sub.2, X.sub.3, X.sub.4 and X.sub.5 are each a halogen or hydrogen atom or a hydroxyl group and at least one of them is a halogen atom.

Process for dimerizing lower alpha-olefins

Synthetic saturated oils useful as materials for lubricating oils and cosmetics and prepared by hydrogenation of low molecular weight polyisoprene having the 1,4 structure of at least 70% in the main chains and a number average molecular weight of about 290 to 3,000.

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Takarazuka, Japan

Seimei Yasui