Snamprogetti S.p.a.

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Snamprogetti

Brevetti E Licenze

Sebastiano Cesca

Aldo Priola

Giuseppe Ferraris

Sergio Arrighetti

Alberto Greco

Guglielmo Bertolini

Mario Bruzzone

Aldo Brancaccio

Giuseppe Ghetti

Eugenio Vajna

Arnaldo Roggero

Fiorenzo Renzi

Giampaolo Giuliani

Gianpaolo Giuliani

Giampaolo Guiliani

There is disclosed the coating of a metallic substrate with a cross-linked polymeric film by contacting the substrate with an aqueous composition containing:

Process and a composition for coating a metallic substrate with a

A process for preparing hydrocarbonaceous resins from C.sub.5 fractions is disclosed in which the starting hydrocarbonaceous fraction is enriched with cis-piperylene. A catalyst system is also disclosed for the formation of the resins by polymerization and the simplest catalyst is an aluminum halide. In other embodiments, the aluminum halide is used together with a second component such as a hydrocarbyl halide and/or a halide of a metal selected from Sn, Si, B, Ti, Pb, Sb, As and others. Resins having improved physico-chemical properties are obtained.

Hydrocarbonaceous resins, method for their preparation and means therefor

An alpha-olefin such as ethylene is polymerized in the presence of a catalyst system consisting of (1) an alkyl-halide, alkyl-derivative or hydride of a metal belonging to one of the first three groups of the periodic system and (2) the combination product of a transition metal chloride and titanium trichloride, supported on a previously chlorinated material such as chlorinated .alpha.-alumina having a high superficial area.

Process for the polymerization of alpha-olefins, catalyst employed in

An alpha-olefin such as ethylene is polymerized in the presence of a catalyst system consisting of (1) an alkyl-halide, alkyl-derivative or hydride of a metal belonging to one of the first three groups of the periodic system and (2) the combination product of a transition metal chloride and titanium trichloride, supported on a previously chlorinated material such as chlorinated .gamma.-alumina having a high superficial area.

Oligomers are obtained from straight-chain alpha olefins by contacting these with a catalytic system of the binary type, which is composed of an organic metallic compound of aluminum and a haloid acid. Subsequent hydrogenation of the oligomers is carried out in order to remove possible residual unsaturations.

Method for producing oligomers from straight-chain alpha olefins,

An alpha-olefin such as ethylene is polymerized in the presence of a catalyst system consisting of (1) an alkyl-halide, alkyl-derivative or hydride of a metal belonging to one of the first three groups of the periodic system and (a) the combination product of a transition metal chloride and titanium trichloride said transition metal chloride being derived from the reaction of a transition metal carbonyl and titanium tetrachloride.

Alpha olefin polymerization catalyst comprising an alkyl halide and a

Novel thermoplastic materials can be obtained in which besides the resin formed by polymerizing alkenylaromatic with or without acrylic and vinylic monomers, there is also a branched interpolymer the main carbon atom chain of which has a saturated elastomeric nature, whereas the chains which make up the branch-offs have a plastic character. Side-chains on the saturated rubber, which have the same composition as the non-grafted resin, favors the even dispersion of the rubber in the resin matrix so that the physical and mechanical properties of the resin are considerably improved: an improved resistance to ageing is also achieved. A styrene-acrylonitrile resin grafted on a saturated ethylene-propylene copolymer is but an example. The preparation process is carried out in solution: critical conditions, additives, adjuvants, initiators and promoters are indicated and exemplified. Irradiation with ultraviolet rays may be of help.

Method for the preparation of novel thermoplastic materials, and

Improved shock-resistant resins are obtained by graft-copolymerizing a monomer selected from among alkenyl aromatics, vinylics, acrylics, their halogenated derivatives or admixtures of same, with maleic anhydride and/or an imide derivative of such anhydride and with a terpolymer composed by ethylene, a higher homolog of ethylene and a polyene having at least one system of conjugated double bonds.

Shock-resistant resin and method for their preparation

A method is described whereby olefin terpolymers, consisting of ethylene, an alpha olefin and a polyene having in the molecule, in addition to the double bond participating in the formation of the macromolecule, at least one conjugated double bond system, are stabilized against oxidative aging without destroying their characteristic high vulcanization rate by reacting them with a dienophilic agent represented by one of the following formulae: ##STR1## wherein R and R.sub.6 may be an alkyl, alkenyl, cycloalkyl, aryl or aralkyl radical having up to 8 carbon atoms, R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 may be hydrogen or akyl, aryl, cycloalkyl or aralkyl radicals having up to 8 carbon atoms, the R.sub.1 -R.sub.2 and R -R pairs may be divalent radicals forming condensed rings.

Process for producing stabilized olefin terpolymers and stabilized

This invention relates to the preparation of linear alpha-olefin oligomers and more particularly to the catalyst system which consists of a two component mixture comprising an aluminium halide and a compound capable of reacting with said aluminium halide and selected among

Process for the preparation of linear alpha-olefin oligomers, subsequent

A process is described whereby homopolymers and copolymers of isobutylene are prepared by effecting the polymerization at a temperature in the range of -100.degree. to 30.degree. C in the presence of a catalyst system including:

Process for the production of polymers and copolymers of isobutylene

A method is described whereby olefin terpolymers, consisting of ethylene, an alpha olefin and a polyene having in the molecule, in addition to the double bond participating in the formation of the macromolecule, at least one conjugated double bond system, are stabilized against oxidative aging without destroying their characteristic high vulcanization rate by reacting them with a dienophilic agent represented by one of the following formulae: ##STR1## wherein R and R.sub.6 may be an alkyl, alkenyl, cycloalkyl, aryl or aralkyl radical having up to 8 carbon atoms, R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 may be hydrogen or alkyl, aryl, cycloalkyl or aralkyl radicals having up to 8 carbon atoms, the R.sub.1 -R.sub.2 and R -R pairs may be divalent radicals forming condensed rings.

Ethylene is polymerized through the use of an improved catalyst system consisting of a carrier such as neodymium oxide having a high superficial area, an aluminum compound such as triisobutylaluminum and the combination product of titanium trichloride and an isostructural chloride of another transition metal prepared by impregnating the carrier with a solution of a carbonyl derivative of the other transition metal, refluxing the impregnated carrier with titanium tetrachloride until that carbonyl derivative is converted to the chloride of the other transition metal, and then removing the excess of titanium tetrachloride.

A class of soluble polymers of high molecular weight is disclosed whose members are: copolymers of polycyclic polyenes containing two conjugated double bonds which are members of the group consisting of a) polycyclic polyenes having an endomethylenic system orthocondensed with another hydrocarbon ring wherein the two common carbon atoms form a part of a conjugated diene system whose double bonds are located inside the non-endomethylenic ring, b) polyenes presenting an alkylidene group conjugated with a double bond of a ring which forms a part of an endocyclic system, and c) orthocondensed polycyclic polyenes substituted with an alkylidene type ring whose double bond is conjugated with a double bond of one of the cycles; and homopolymers of at least one of said polycyclic polyenes with at least one other conjugated diene. They may be prepared by reacting the selected monomers in the presence of a cationic catalyst selected from the halides of metals of the second to eighth groups of the periodic system and the alkyl derivatives thereof, which may be complexed with water, alcohols, acids, ethers or alkylhalides.

High molecular weight soluble polymers starting from polycyclic polyenes

The invention relates to the preparation of oligomers starting from linear alpha-olefins and to the subsequent hydrogenation thereof to saturated oligomers products, and more particularly to the catalyst system used in the oligomer preparation reaction, the catalyst system consisting of a first component selected amongst the halogenated organo-metal aluminium components, and a second component capable of reacting with the first one and chosen amongst halogens or interhalogenic compounds and metal halides; thus higher yields of oligomers, as well as an easier performance and a control of the reaction are achieved. In turn the hydrogenation step is carried out in the presence of a known hydrogenation catalyst, at a temperature of 150 to 300.degree. C and under a pressure of from 20 to 150 atmospheres.

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San Donato Milanese, Italy

Sebastiano Cesca