Sanyo Chemical Industries, Ltd.

Satoshi Tamabuchi

Keiji Tanaka

Tsuyoshi Yuki

Masashi Date

Kenjiro Tsubota

Kenji Tanaka

Shingo Mukaida

Yoshiyuki Iwasaki

Daisuke Tagawa

Hitoshi Takai

An absorbent composition is produced by drying a mixture obtained by mixing a micro-filler (B) with a hydrogel having a water absorptive resin (A) and water. The hydrogel is produced by performing polymerization to produce the resin (A) and not drying the resin (A) after the polymerization. The absorbent composition has a specific surface area at least 10% lager than that of a reference composition produced by drying the hydrogel without the micro-filler (B).

Absorbent compositions, methods for producing thereof and absorbent products

A method for producing a water absorbent resin by polymerizing a water-soluble monomer having a polymerizable unsaturated group (A) and a crosslinking agent (B) as the essential components by radical polymerization in the presence of water or, polymerizing a water-soluble monomer having an unsaturated group (A) and a crosslinking agent (B) by radical-graft copolymerization with a water-soluble polymer (C) as the backbone polymer in the presence of water, wherein a water-based solid material capable of being endothermally fused or dissolved into water (D) is added when initiating the polymerization, with at least a part of the water-based solid material (D) in a solid state. By the method of the present invention, a water absorbent resin having a high molecular weight and a high absorption capacity with little water-soluble component can be obtained with ease.

Method for preparing water absorbent resin

A method for producing a water absorbent resin comprising the step of radically polymerizing a water-soluble radically polymerizable monomer having an acid group or a group of the salt thereof and optionally a polysaccharide in the presence of water using a crosslinking agent (C), wherein 0.0001 to 1 weight % of a thiol compound (D) having a radically polymerizable double bond, based on the above mentioned water-soluble radically polymerizable monomer (A), is used as the copolymerizing component to provide a water absorbent resin having a high absorbency and a good gel stability after absorbing body fluid, and a water absorbent comprising the water absorbent resin produced thereby.

Method for producing water absorbent resin and water absorbent

A method for preparing water-absorbent resins (D) by radically polymerizing a water soluble monomer (A), or a water-soluble monomer (A) and a polysaccharide (B) in the presence of a crosslinking agent (C) and water, wherein the polymerization is conducted under the existence of a thiol compound (E). Water-absorbent resins obtained in the method of the present invention provide high absorption while providing safety with very little amount of a water-soluble component.

Water-absorbing resin compositions obtained by adding a water-soluble thiol compound in the process of drying or pulverizing a hydrogel of a water-absorbing resin which is obtained by polymerizing a water-soluble monomer having a polymerizable unsaturated group optionally with a polysaccharide, in the presence of a crosslinking agent and water. Composition of the present invention are highly efficient in water absorption and safe for having extremely low amounts of residual monomer and water-soluble component.

Growing community of inventors

Osaka-fu, Japan

Satoshi Tamabuchi