Konishiroku Photo Industry Co., Ltd.

Konica Corporation

Megumi Ide

Satoshi Nakagawa

Shuji Kida

Morito Uemura

Shuichi Sugita

Kenichi Kishi

Shinji Yoshimoto

Yutaka Kaneko

Mitsuto Fujiwhara

Takaya Endo

Katsunori Katoh

Hiroshi Sugita

Kosaku Masuda

Ryosuke Satoh

Naoko Shimada

Toyoki Nishijima

Shigeto Hirabayashi

Toyoaki Masukawa

Toshifumi Iijima

Noritaka Nakayama

Nobuaki Kagawa

Norio Miura

Eiichi Sakamoto

Atsushi Tomotake

Hiroshi Shimazaki

Noboru Mizukura

Shoji Kikuchi

Toshihiko Kimura

Minoru Ishikawa

Hiroshi Menjo

Ken-ichi Kishi

Hiroshi Inoie

Motoaki Sugino

Mayumi Tsuruta

Shuzi Kida

Takako Tanaka

Yasuhiko Kawashima

A silver halide photographic light-sensitive material is disclosed. The light-sensitive material comprises a support and one or more photographic constituent layers and at least one of said layers contains a dye capable of being decolored by reacting with a color developing agent.

Silver halide photographic light-sensitive material

A silver halide photographic material comprising a pyrazolotriazole coupler represented by the following Formula I and a stabilizer represented by the following Formula VIII. ##STR1## The substituents are as defined in the specification.

Silver halide photographic sensitive material

A silver halide light-sensitive photographic material comprising a support and, provided thereon, at least one silver halide emulsion layer containing a dye-forming coupler of Formula [I]: ##STR1## wherein R.sub.1 is an alkyl group or a cycloalkyl group; R.sub.2 is an alkyl group, a cycloalkyl group, an acyl group or an aryl group; R.sub.3 is a group which is substituted to a benzene ring; n is an integer of zero or 1; R.sub.4 is an organic group containing one linkage group containing a carbonyl unit or a sulfonyl unit; J is a ##STR2## wherein R.sub.5 is a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group; and X.sub.1 is a group capable of being split off upon reaction with the oxidation product of a color developing agent.

Silver halide light-sensitive photographic material containing a novel

Silver halide color photographic light-sensitive material is disclosed, which is improved in color reproducibility and in fastness of magenta images to light, heat and humidity. The photographic material a magenta coupler represented by Formula (M-1) and a compound represented by Formula (XI) or Formula (XII). ##STR1## In formulas (XI) and (XII) X.sup.1 is an oxygen atom, a sulfur atom or an --NR.sup.10 --; X.sup.2 represents a hydroxyl sulfur atom; R.sup.6 and R.sup.7 each represent a substituent having a .sigma. p value of not more than -0.25; M represents a metal atom; and a and b each represent an integer of 0 to 3.

A silver halide color photographic light-sensitive material comprising a silver halide emulsion layer containing a cyan coupler represented by the following general formula [I]. The color photographic material is improved in sensitivity, density of cyan image, density losing of cyan image due to processing by a fatigued bleach or bleach-fix solution. ##STR1##

Silver halide color photographic light-sensitive material

A silver halide photographic light-sensitive material improved in light-fastness of dye images and in prevention of yellow-stain formation in a non-colored area after processing. The photographic material comprises a support having thereon photographic structural layers including at least one silver halide emulsion layer. At least one of the photographic component layers contains a compound represented by the following Formula [I]: ##STR1## A magenta coupler represented by the following formula [M-I] is preferably used with the above compound. ##STR2##

Silver halide photographic light-sensitive material to provide dye-image

A silver halide photographic light-sensitive material containing a 1H-pyrazolo[3,2-c]-s-triazole type magenta coupler is disclosed. The magenta coupler has an --SO.sub.2 -- group and at least one group selected from the group consisting of a --COOM group and a --SO.sub.3 M group, M being a hydrogen atom or a cation, in its molecule. The photographic material is improved in color development performance and preservability of magenta images.

Silver halide photographic light-sensitive material comprising a support having a plurality of silver halide emulsion layers which are sensitive to the same spectral region and having different speeds and at least one light-sensitive layer comprising a nondiffusible coupler, which upon reaction with an oxidized product of a color developing agent is capable of forming a nondiffusible dye, wherein the silver halide emulsion layer having the greatest speed of said plurality of silver halide emulsion layers sensitive to a particular spectral region contains a nondiffusible coupler which, upon reaction with an oxidized product of a color developing agent, is capable of producing a moveable dye, and a silver halide emulsion having a speed slower than said fastest speed layer contains a nondiffusible compound which, upon reaction with an oxidized product of a color developing agent, is capable of releasing a development inhibitor material.

There is disclosed a light-sensitive silver halide photographic material, having two or more light-sensitive silver halide emulsion layers different in color sensitivities on a support, at least two of the light-sensitive silver halide emulsion layers different in color sensitivities containing a DIR compound capable of releasing a developing inhibitor or developing inhibitor precursor through the reaction with the oxidized product of a developing agent, the developing inhibitor or developing inhibitor precursor released from the DIR compound being diffusive, wherein the following conditions A:

Developing inhibitor arrangment in light-sensitive silver halide color

A light-sensitive silver halide color photographic material, which comprises a cyan coupler for photography represented by the formula [IA] or [IB] shown below in the light-sensitive emulsion; ##STR1## wherein R.sup.1 is a group having a bulk sufficient to impart diffusion resistance to said coupler; R.sup.2 and R.sup.3 each represent a hydrogen atom or a halogen atom, at least one of R.sup.2 and R.sup.3 being a halogen atom; R.sup.2' represents an alkyl group, a cycloalkyl group, an alkenyl group or an aryl group; R.sup.3' represents a halogen atom; and Z represents a hydrogen atom or a group eliminable during the coupling reaction with the oxidized product of a color developing agent. According to the material of this invention, good spectral absorption characteristics can be exhibited and a cyan dye image can be given without dye loss even by use of a bleaching bath or bleach fixing bath which is fatigued after running.

Light-sensitive silver halide color photographic material

There is disclosed a light-sensitive silver halide photographic material having at least one light-sensitive layer constituted of a plural number of silver halide emulsions provided on a support, and a non-light-sensitive intermediate layer containing a diffusion resistant coupler capable of forming a migratable color forming dye or a compound capable of forming a flow-out type coupling product provided at least adjacent to the silver halide emulsion layer with the highest light sensitivity among the plural number of silver halide emulsion layers on its support side. The light-sensitive material according to this invention exhibits excellent photographic characteristics such as sensitivity, graininess, sharpness, storability and gradation.

Light-sensitive silver halide photographic material

There is disclosed a light-sensitive silver halide photographic material containing a compound represented by the formula (I): ##STR1## wherein G, R.sub.1, R.sub.2 and X have the same meanings as defined in the specification. The 1-naphthol coupler which is contained in the light-sensitive silver halide photographic material is high in reactivity with an oxidized product of a color forming developing agent and can efficiently impart imagewise photographic effects to light-sensitive silver halide photographic materials.

There is disclosed a novel silver halide photosensitive color photographic material comprising a coupler which consists of a coupling component (A) which is capable of causing a coupling reaction with an oxidized color developing agent and a substituent component bonded at the coupling position of said coupling component (A), which substituent component is capable of being split off on coupling reaction, the improvement characterized in that said substituent comprises a coupling component (B) which can undergo coupling reaction with an oxidized color developing agent when released from said coupling component (A) and a photographically useful component which is capable of being released on coupling reaction of said coupling component (B). The color photographic material according to the present invention provides graininess, sharpness and color reproducibility which is sufficiently competent to the requirement of further miniturization of film size by use of a coupler having novel functions.

Silver halide photosensitive color photographic material

The invention relates to silver halide photographic materials comprising a support and a light sensitive silver halide emulsion layer containing as a cyan-dye-forming coupler a compound of the formula ##STR1## wherein R.sub.1 is a halogen atom, an alkyl, alkoxy or acylamino group; R.sub.2 and R.sub.3 are individually a hydrogen atom, an alkyl or aryl group and R.sub.2 and R.sub.3 may form a heterocyclic group by the condensation thereof; n is an integer of 0-3; R.sub.4 is an alkyl, aryl, acyl or heterocyclic group; R.sub.5 is an alkyl, aryl, alkoxy, amino, acylamino, sulfonamide, carboxy, alkoxycarbonyl, carbamoyl, cyano or halogenated alkyl group; and R.sub.6 is a hydrogen atom or an alkyl, alkoxy, carboxy, carbamoyl, hydroxy, acyloxy, nitro, amino, azo, acylamino, sulfonamide or acyl group.

Silver halide photographic material

A silver halide photographic light-sensitive material which comprises at least one of those pyrazole compounds represented by the following general formula: ##STR1## wherein A is a group which can be eliminated in a photographic process condition; X is ##STR2## wherein R.sub.5 is a hydrogen atom or an alkyl, an aryl, an acyl or a sulfone group, which R.sub.5 group may combine together with R.sub.1 to form a condensed ring; R.sub.1 is a hydrogen atom or an alkyl, an aryl, an acyl, a sulfone, an alkoxy, or a heterocyclic residue; R.sub.2 is a hydrogen atom or an alkyl, an aryl, an alkoxy, an amino, an acid amide, a sulfonamide, a carboxyl, an alkoxycarbonyl, a carbamoyl, a cyano, or a halogenated alkyl group, R.sub.3 and R.sub.4 each is a hydrogen atom or an alkyl or an aryl group; and PUG is a photographically useful group which is released after elimination of the A group in a photographic processing condition and which has a hetero atom directly combined with the carbon substituted in the fourth position of the pyrazole nucleus.

Growing community of inventors

Hino, Japan

Satoshi Nakagawa