Showa Denko K.k.

Showa Denko Kabushiki Kaisha

Satoshi Iwamoto

Kazuyuki Watanabe

Hisayoshi Yanagihara

Hirotoshi Takahashi

Kazuharu Itoh

There are provided a propylene-based polymer characterized in that (1) the xylene-extraction insoluble portion (XI) is 99.0 wt % or greater, (2) the isotactic pentad ratio (IP) is 98.0% or greater as measured by,C nuclear magnetic resonance spectroscopy, (3) the isotactic average chain length (N) is 500 or greater, and (4) the total amount of each of the fractions obtained by column separation of the xylene insolubles whose average chain length (N,) is 800 or greater accounts for 10 wt % or more of the entirety, and a method for its production, as well as a propylene-based polymer composition prepared by combining with this propylene-based polymer at least a nucleating agent in the range of 0.05-15 wt %. In addition, there are provided a polymerization catalyst component allowing the production of such a propylene-based polymer, and a method for its production.

Propylene-based polymer, method for its production, composition thereof, catalyst component for polymerization, and method for its production

Propylene-based polymer, method of its production, composition thereof,

A polyolefin composition, which comprises: (A) 1 to 99% by weight of a polyolefin having the following properties of (a) to (e); (a) a ratio of kinematic viscosity .eta..sub.1 at a frequency of 10.sup.-1 rad/sec to kinematic viscosity .eta..sub.2 at a frequency of 10 rad/sec at a temperature of 190.degree. C. according to a kinematic viscoelasticity determination method of 4 to 20, (b) a crystallization peak temperature Tcp according to a Differential Scanning Calorimetry of 110.degree. C. to 130.degree. C., (c) a ratio (Tmp/Tcp) of melting peak temperature Tmp to crystallization peak temperature Tcp according to a Differential Scanning Calorimetry of 1.1 to 1.5, (d) Tmp/(Tmp-Tcp)=3.0 to 9.8, and (e) a crystal structure exhibiting a-axial orientation in a diffraction pattern according to a X-ray diffraction method, and (B) 99 to 1% by weight of a propylene resin having the following properties of (f) and (g); (f) a ratio of kinematic viscosity .eta..sub.1 at a frequency of 10.sup.-1 rad/sec to kinematic viscosity .eta..sub.2 at a frequency of 10 rad/sec at a temperature of 190.degree. C. according to a kinematic viscoelasticity determination method of below 4, and (e) and no crystallization structure exhibiting a-axial orientation in a diffraction pattern according to a X-ray diffraction method.

Polyolefin composition, molded article thereof and multilayered laminate

A polyolefin composition, which comprises: (A) 1 to 99% by weight of a polyolefin in having the following properties of (a) to (e); (a) a ratio of kinematic viscosity .eta..sub.1 at a frequency of 10.sup.-1 rad/sec to kinematic viscosity .eta..sub.2 at a frequency of 10 rad/sec at a temperature of 190.degree. C. according to a kinematic viscoelasticity determination method of 4 to 20, (b) a crystallization peak temperature Tcp according to a Differential Scanning Calorimetry of 110.degree. to 130.degree. C., (c) a ratio (Tmp/Tcp) of melting peak temperature Tmp to crystallization peak temperature Tcp according to a Differential Scanning Calorimetry of 1.1 to 1.5, (d) Tmp/(Tmp-Tcp)=3.0 to 9.8, and (e) a crystal structure exhibiting a-axial orientation in a diffraction pattern according to a X-ray diffraction method, and (B) 99 to 1% by weight of a propylene resin having the following properties of (f) and (g); (f) a ratio of kinematic viscosity .eta..sub.1 at a frequency of 10.sup.-1 rad/sec to kinematic viscosity .eta..sub.2 at a frequency of 10 rad/sec at a temperature of 190.degree. C. according to a kinematic viscoelasticity determination method of below 4, and (e) and no crystallization structure exhibiting a-axial orientation in a diifraction pattern according to a X-ray diffraction method.

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Oita, Japan

Satoshi Iwamoto