Ube Industries, Inc.

Satoshi Bandai

Masato Murakami

Michinori Suzuki

Nobuharu Hisano

Nobuhiro Tsujimoto

Yasumasa Iwamoto

Osamu Kimura

Sakae Yuasa

Toshifumi Fukunaga

Takashi Kitamura

Kazuo Ogawa

Hiroshi Ishii

Koji Maeda

Yoshihira Hosoyama

Takamasa Fujii

Katsumi Kimura

Masumi Hayashi

A polymer of ethylenically unsaturated monomer, for example, 1,3-butadiene, having a desired molecular weight and distribution thereof is produced, with a high stability, by preparing a solution of hydrogen in an inert organic solvent for the monomer in which a vapor-liquid phase equilibrium of hydrogen is attained, and then by addition-polymerizing the monomer in the hydrogen-dissolved inert organic solvent in the presence of a catalyst preferably including a metallocene complex of transition metal compound, an inert compound of a non-coordination anionic compound with a cationic compound, an organic metal (aluminum) compound and, optionally, water.

Method of producing a polymer

The present invention provides a process for the production of a conjugated diene polymer having a controlled microstructure at a high polymerization activity in the presence of a metallocene type complex of compound of transition metal of the group V of the Periodic Table. A novel catalyst is provided comprising (A) a metallocene type complex of a transition metal of the group V of the Periodic Table, (B) an ionic compound of a non-coordinating anion and a cation, (C) an organic metal compound of the groups I to III and (D) water, wherein the molar ratio of (C)/(D) is from 0.66 to 5. A novel process for the production of a conjugated diene polymer is also provided, which comprises the polymerization of a conjugated diene compound in the presence of a catalyst comprising (A) a metallocene type complex of a transition metal of the group V of the Periodic Table, (B) an ionic compound of a non-coordinating anion and a cation, (C) an organic metal compound of the groups I to III and (D) water, wherein the molar ratio of (C)/(D) is from 0.66 to 5.

Conjugated diene compound polymerization catalyst process for the preparation of conjugated diene polymer in the presence thereof and polybutadiene thus prepared

A metal wire-containing polymeric laminate tape is continuously produced by superimposing a pair of primary cross-linked, electro-insulating thermoplastic polymer tapes side by side along the longitudinal axes thereof under tension, while a plurality of metal wires are interposed, under tension, in parallel to each other, between the primary tapes along the longitudinal axes thereof; by heating the resultant precursory laminate tape up to a temperature of from 10.degree. to 120.degree. C. above the melting point of the corresponding thermoplastic polymer, which is not cross-linked; by pressing the heated precursory laminate tape by using a pair of elastic pressing rolls, whereby the primary tapes are heat-bonded together to provide a body of laminate matrix within which the metal wires are embedded; and, optionally, by cooling the resultant laminate tape.

Process for continuously producing a polymeric laminate tape having a

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Ichihara, Japan

Satoshi Bandai