Philip Morris USA Inc.

Philip Morris Inc.

Other

Philip Morris Products S.a.

Sarojini Deevi

Yezdi B Pithawalla

Rangaraj S Sundar

Seetharama C Deevi

Unnikrishnan Pillai

Kent Brian Koller

Mohammad R Hajaligol

Mohamed Samy El-Shall

Donald M Schleich

Azzedine Bensalem

Sohini PalDey

Padmanabha Reddy Ettireddy

Munmaya K Mishra

William R Sweeney

Diane L Gee

Jay A Fournier

A Clifton Lilly, Jr

Michael L Watkins

Zhaohua Luan

Shengsheng Liu

D Bruce Losee

Harry V Lanzillotti

Kenneth S Houghton

Ila Skinner

M Samy El-Shall

Arnys C Lilly, Jr

A method of making composite nanoscale particles comprising subjecting a starting material to laser energy so as to form a vapor and condensing the vapor so as to form the composite nanoscale particles, wherein said composite nanoscale particles comprise a first metal and/or a first metal oxide incorporated in nanoscale particles of an oxide of a second metal, the first metal being different than the second metal. The starting material can comprise first and second metals or compounds of the first and second metals. The composite nanoscale particles can be formed in a reaction chamber wherein a temperature gradient is provided. The atmosphere in the chamber can be an inert atmosphere comprising argon or a reactive atmosphere comprising oxygen. The composite nanoscale particles are useful for low-temperature and near-ambient temperature catalysis. The composite nanoscale particles can be incorporated in the tobacco cut filler, cigarette paper and/or cigarette filter material of a cigarette to catalyze the oxidation of carbon monoxide to carbon dioxide.

In situ synthesis of composite nanoscale particles

Cut filler compositions, cigarette paper, cigarette filters, cigarettes, methods for making cigarettes and methods for smoking cigarettes are provided, which involve the use of a catalyst capable converting carbon monoxide to carbon dioxide. The catalyst comprises nanoscale metal and/or metal oxide particles supported on high surface area support particles. The catalyst can be prepared by combining a metal precursor solution with high surface area support particles to form a mixture, or by combining a metal precursor solution with a colloidal solution to form a mixture, and then heat treating the mixture.

Catalyst to reduce carbon monoxide in the mainstream smoke of a cigarette

A metallo-organic decomposition process for the preparation of intermetallic powders and films. A liquid mixture containing a first metal precursor and a second metal is heated to a temperature in a first temperature range so as to convert the first metal precursor to a first metal followed by heating to a temperature in a second temperature range so as to form an intermetallic compound by a solid state reaction between the first and second metals. The intermetallic compound can be used as a catalyst in cut filler and/or the filter of a cigarette.

Preparation of intermetallics by metallo-organic decomposition

An oral chewable tobacco product includes a gum composition in an amount of about 30% to about 70% by weight based on the weight of the oral chewable tobacco product and tobacco powder in an amount of about 30% to about 70% by weight based on the weight of the oral chewable tobacco product. The gum composition includes at least one environmentally biodegradable polymer in an amount of about 20% to about 95% by weight based on the weight of the gum composition and at least one softener in an amount of about 5% to about 80% by weight based on the weight of the gum composition.

Oral chewable tobacco product and method of manufacture thereof

A method of making composite nanoscale particles comprising subjecting a starting material to laser energy so as to form a vapor and condensing the vapor so as to form the composite nanoscale particles, wherein said composite nanoscale particles comprise a first metal and/or a first metal oxide incorporated in nanoscale particles of an oxide of a second metal, the first metal being different than the second metal. The starting material can comprise first and second metals or compounds of the first and second metals. The composite nanoscale particles can be formed in a reaction chamber wherein a temperature gradient is provided. The atmosphere in the chamber can be an inert atmosphere comprising argon or a reactive atmosphere comprising oxygen. The composite nanoscale particles are useful for low-temperature and near-ambient temperature catalysis. The composite nanoscale particles can be incorporated in the tobacco cut filler, cigarette paper and/or cigarette filter material of a cigarette to catalyze the oxidation of carbon monoxide to carbon dixoxide.

A component of a cigarette comprises a silver-based catalyst for the conversion of carbon monoxide to carbon dioxide. The silver-based catalyst comprises particles (e.g., nanoscale or larger sized particles) of metallic silver and/or silver oxide supported in and/or on metal oxide support particles. The silver-based catalyst can be incorporated into a cigarette component such as tobacco cut filler, cigarette paper and cigarette filter material to reduce the concentration of carbon monoxide in the mainstream smoke of a cigarette during smoking. The catalyst can also be used in non-cigarette applications.

Silver and silver oxide catalysts for the oxidation of carbon monoxide in cigarette smoke

CuO&#x2014;ZnO&#x2014;CeOcatalyst and aged CuO&#x2014;ZnO catalyst catalytically active for low temperature oxidation of carbon monoxide. The catalysts are co-precipitated, filtered, washed, dried, and calcined. The catalysts can be incorporated into a component of a cigarette or can be used to reduce the concentration of carbon monoxide from a vehicle exhaust emission, a gas used in a laser, a gas used in a fuel cell and/or ambient air undergoing air filtration.

Catalysts for low temperature oxidation of carbon monoxide

A method of making palladium-containing nanoscale catalyst particles comprising subjecting a starting material to laser energy so as to form a vapor and condensing the vapor so as to form the catalyst particles. The catalyst comprises nanoscale particles of palladium and/or palladium oxide incorporated in and/or on nanoscale particles of a metal or metal oxide. The nanoscale catalyst, which can be incorporated in the tobacco cut filler, cigarette wrapper and/or cigarette filter of a cigarette, is useful for low-temperature and near-ambient temperature catalysis. The nanoscale catalyst can convert carbon monoxide and nitric oxide that are found in mainstream smoke to carbon dioxide and nitrogen, respectively. The nanoscale catalyst may also be incorporated into a hydrocarbon conversion reactor, into a vehicle exhaust emissions system, into a laser, into a fuel cell or used in an air filter or for emissions reduction in the cold starting of an automobile engine.

Palladium-containing nanoscale catalysts

A laminate including a flavorant useful for packaging cigarettes or other products such as food products. The laminate includes crosslinked polymer coatings adhered to at least two metal foils, and a volatile flavor component such as menthol is applied to one of the polymer-coated surfaces. The laminate minimizes loss of volatile and/or heat sensitive flavor components from the package during extended periods at elevated temperature which are often associated with long term storage and/or shipping.

Laminated metal foil packaging material and method of making

A method for forming a copper oxide catalyst includes forming a precipitate of copper hydroxide from a copper salt solution; forming dried particles of copper hydroxide by drying the precipitate at a temperature of less than 30&#xb0; C.; heating the copper hydroxide particles to form copper oxide; and activating the copper oxide. The copper oxide catalyst includes particles of copper oxide. Copper oxide catalyst particles can preferably include a metastable form of copper oxide. The copper oxide catalyst particles are useful for low-temperature and near-ambient temperature catalysis and/or oxidation of carbon monoxide to carbon dioxide.

Method for forming activated copper oxide catalysts

A method of making intermetallic nanoscale particles comprising iron aluminide and/or iron aluminum carbide comprising the steps of preparing a mixture of a solvent, an iron salt and LiAlH, and heating the mixture to form the intermetallic nanoscale particles. The intermetallic nanoscale particles, which can comprise intermetallic nanoscale particles of iron aluminide and/or iron aluminum carbide in an alumina matrix, are capable of reducing the amount of 1,3-butadiene in the mainstream smoke of a cigarette.

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Midlothian, VA, United States of America

Sarojini Deevi