University of California

Sarah H Tolbert

Bruce S Dunn

John S Wang

Torsten Brezesinski

Richard Barry Kaner

George Gruner

Reza Mohammadi

Miao Xie

Andrew T Lech

Terri Chai Lin

Eric Detsi

John Cook

Robert W Cumberland

Gregory Paul Carman

Eric Joseph Nemanick

Scott Macklin Keller

Benjamin Kalman Lesel

Jenn-Ming Yang

Alexander L Ayzner

Joshua Hockel

John J Gilman

Benjamin J Schwartz

Yves Rubin

Hsiu-Ying Chung

Jonathan B Levine

Erik K Richman

Laura Schelhas

Hyungsuk Kim

Merissa Halim

Darcy Wanger

Christopher J Tassone

Robert D Kennedy

Christopher Day

Hyungseok Kim

Chris Byung-Hwa Kang

Abby Kavner

Michelle B Weinberger

Nanoporous carbon coated lithium vanadium fluorophosphate materials and cathodes for fast charging li-ion batteries are described. Formation of the materials using polymer-templating is also described.

Nanoporous lithium vanadium fluorophosphate materials and cathodes for fast charging li-ion batteries

A mesoporous, nanocrystalline, metal oxide construct particularly suited for capacitive energy storage that has an architecture with short diffusion path lengths and large surface areas and a method for production are provided. Energy density is substantially increased without compromising the capacitive charge storage kinetics and electrode demonstrates long term cycling stability. Charge storage devices with electrodes using the construct can use three different charge storage mechanisms immersed in an electrolyte: (1) cations can be stored in a thin double layer at the electrode/electrolyte interface (non-faradaic mechanism); (2) cations can interact with the bulk of an electroactive material which then undergoes a redox reaction or phase change, as in conventional batteries (faradaic mechanism); or (3) cations can electrochemically adsorb onto the surface of a material through charge transfer processes (faradaic mechanism).

Mesoporous nanocrystalline film architecture for capacitive storage devices

A composition includes tungsten (W); at least one element selected form the group of elements consisting of boron (B), beryllium (Be) and silicon (Si); and at least one element selected from the group of elements consisting of titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), zirconium (Zr), niobium (Nb), molybdenum (Mo), ruthenium (Ru), hafnium (Hf), tantalum (Ta), rhenium (Re), osmium (Os), iridium (Ir), lithium (Li) and aluminum (Al). The composition satisfies the formula WMXwherein X is one of B, Be and Si; M is at least one of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Zr, Nb, Mo, Ru, Hf, Ta, Re, Os, Ir, Li and Al; x is at least 0.001 and less than 0.999; and y is at least 4.0. A tool is made from or coated with this composition.

Compositional variations of tungsten tetraboride with transition metals and light elements

A composition includes tungsten (W); at least one element selected from the group of elements consisting of boron (B), beryllium (Be) and silicon (Si); and at least one element selected from the group of elements consisting of titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), zirconium (Zr), niobium (Nb), molybdenum (Mo), ruthenium (Ru), hafnium (Hf), tantalum (Ta), rhenium (Re), osmium (Os), iridium (Ir), lithium (Li) and aluminum (Al). The composition satisfies the formula WMXwherein X is one of B, Be and Si; M is at least one of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Zr, Nb, Mo, Ru, Hf, Ta, Re, Os, Ir, Li and Al; x is at least 0.001 and less than 0.999; and y is at least 4.0. A tool is made from or coated with this composition.

A synthetic metal dichalcogenide having a highly defected nanocrystalline layered structure, wherein layer spacing is larger than in perfect crystals of the same material, wherein the defected structure provides access to interlayer crystals of the same material, and wherein the defected structure facilitates a pseudocapacitive charge storage mechanism. The metal dichalcogenide is receptive to intercalation of ions such as Li ions, Na ions, Mg ions, and Ca ions, and does not undergo a phase transition upon intercalation of Li ions, Na ions, Mg ions, or Ca ions. The metal dichalcogenide can be used, for example, as a component of an electrode that also includes a carbon derivative, and a binder, which are intermixed to form the electrode. The resultant composite electrode is highly porous and highly electronically conductive, and is suitable for use in devices such as symmetric capacitors, asymmetric capacitors, rocking chair batteries, and other devices.

Metal chalcogenides for pseudocapacitive applications

Selective alloy corrosion is used to synthesize a robust and ultrafine mesoporous NiFeMn-based metal/metal oxide oxygen evolving catalyst with ligament and pore sizes in the range of 10 nm and a BET surface area of 43 m/g. As an oxygen evolving catalyst, the mesoporous catalyst exhibits high stability (&#x3e;264 hours) at a high current density (500 mA/cm) with a low overpotential (360 mV) using a moderate electrolyte concentration (1 M KOH). The catalyst is made from non-precious metals and its fabrication is straight forward and directly applicable to large-scale synthesis.

Mesoporous nickel-iron-manganese-alloy based metal/metal oxide composite thick film catalysts

A nanoporous tin is disclose, along with a method of fabrication thereof, the tin having a hierarchical nanoporous and mesoporous ligament morphology that exhibits long-term cyclability, particularly when used as anode material in Li-ion. One embodiment of the present technology is a fabrication method to directly produce nanoporous tin in powder form, rather than a monolithic piece of nanoporous metal, so that the NP-Sn powder can be directly integrated into composite electrodes using commercial battery electrode processing techniques.

Nanoporous tin powder for energy applications

A magnetoelectric composite device having a free (i.e. switchable) layer of ferromagnetic nanocrystals mechanically coupled a ferroelectric single crystal substrate is presented, wherein application of an electrical field on the composite switches the magnetic state of the switchable layer from a superparamagnetic state having no overall net magnetization to a substantially single-domain ferromagnetic state.

Magnetoelectric control of superparamagnetism

Described herein are photovoltaic devices including self-assembling fullerene derivatives. In one embodiment, a photovoltaic device includes a first electrode layer, a second electrode layer, and an active layer disposed between the first electrode layer and the second electrode layer. The active layer is configured to absorb incident light to produce a first type of charge carrier that is transported to the first electrode layer and a second type of charge carrier that is transported to the second electrode layer. The active layer includes self-assembled molecules of a fullerene derivative to provide a conductive path through at least a portion of the active layer.

Photovoltaic devices including self-assembling fullerene derivatives for improved efficiencies

A lithium ion battery that incorporates an anode formed from a Group IV semiconductor material such as porous silicon is disclosed. The battery includes a cathode, and an anode comprising porous silicon. In some embodiments, the anode is present in the form of a nanowire, a film, or a powder, the porous silicon having a pore diameters within the range between 2 nm and 100 nm and an average wall thickness of within the range between 1 nm and 100 nm. The lithium ion battery further includes, in some embodiments, a non-aqueous lithium containing electrolyte. Lithium ion batteries incorporating a porous silicon anode demonstrate have high, stable lithium alloying capacity over many cycles.

Lithium ion batteries based on nanoporous silicon

Growing community of inventors

Los Angeles, CA, United States of America

Sarah H Tolbert